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Copyright (c) 2014 Pinghua Chen1, Xuezhen Zhou1, Dongping Li1, Jing Li1, Yanzhu Liu1, Yongxiu Li1
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorption of Methylene Blue on Nano Composite MWCNTs/ZrO2: Equilibrium, Dynamic and Surface Data
Corresponding Author(s) : Pinghua Chen1
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
A directly ball milling method for quick synthesis of multiwall carbon nanotubes (MWCNTs)/ZrO2 composite was developed in this study. The adsorption ability of the composite was determined taking methylene blue as model contaminant. Results show the adsorption ability of material could be improved by almost 1.5 times by this simple method. The composite was characterized by TEM, EDS, XRD, Zeta-potential and surface area. The equilibrium adsorption isotherms, kinetic and thermodynamic properties, adsorption mechanism of the related adsorption process were investigated. Results show the adsorption reaction is a spontaneous, endothermic and physisorption process. Based on the low cost and simple peparing method, the nano composite is considered to be a promising adsorbent to treat water pollution in large scale.
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T. Liu, Y. Li, Q. Du, J. Sun, Y. Jiao, G. Yang, Z. Wang, Y. Xia, W. Zhang, K. Wang, H. Zhu and D. Wu, Colloids Surf. B, 90, 197 (2012).
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H.O. Seo, C.W. Sim, K.D. Kim, Y.D. Kim and D.C. Lim, Chem. Eng. J., 183, 381 (2012).
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D. Ozdes, C. Duran, H.B. Senturk, H. Avan and B. Bicer, Desalin. Water Treat., 52, 208 (2014).
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S. Addo Ntim and S. Mitra, J. Colloid Interf. Sci., 375, 154 (2012).
M. Trojanowicz, Trends Anal. Chem., 25, 480 (2006).
M.H. Bocanegra-Bernal, J. Echeberria, J. Ollo, A. Garcia-Reyes, C. Domínguez-Rios, A. Reyes-Rojas and A. Aguilar-Elguezabal, Carbon, 49, 1599 (2011).
H.J. Choi and D.H. Bae, Mater. Sci. Eng. A, 528, 2412 (2011).
M. Fattahi, N. Nabhani, E. Rashidkhani, Y. Fattahi, S. Akhavan and N. Arabian, Micron, 54-55, 28 (2013).
M. Mazaheri, D. Mari, Z.R. Hesabi, R. Schaller and G. Fantozzi, Compos. Sci. Technol., 71, 939 (2011).
E. Zapata-Solvas, D. Gómez-García and A. Domínguez-Rodríguez, J. Eur. Ceram. Soc., 32, 3001 (2012).
F. Ferrero, J. Environ. Sci. (China), 22, 467 (2010).
N. Garmendia, I. Santacruz, R. Moreno and I. Obieta, J. Mater. Sci. Mater. Med., 21, 1445 (2010).
M. Dogan, H. Abak and M. Alkan, J. Hazard. Mater., 164, 172 (2009).
X.D. Hao, J. Wei, Q.L. Zhang and D.T. Wang, Technol. Water Treatment, 39, 23 (2013).
Z. Barhon, A. Albizane, M. Azzi, N. Saffaj and J. Bennazha, J. Appl. Sci. Res. 5, 893-904 (2009).
D.P. Das, N. Baliarsingh and K.M. Parida, J. Mol. Catal. Chem., 261, 254 (2007).
A.A. Farghali, M. Bahgat, W.M.A. El Rouby and M.H. Khedr, J. Solution Chem., 41, 2209 (2012).
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M.W. Pannu, G.A. O'Connor and G.S. Toor, Environ. Chem., 31, 646 (2012).
E. Rubín, P. Rodríguez, R. Herrero and M.E. Sastre de Vicente, J. Chem. Eng. Data, 55, 5707 (2010).
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918).
H. Freundlich, J. Phys. Chem., 57, 385 (1906).
K. Hall, L. Eagleton, A. Acrivos and T. Vermeulen, Ind. Eng. Chem. Fundam., 5, 212 (1966).
F. Haghseresht and G. Lu, Energy Fuels, 12, 1100 (1998).
H. Tel, Y. Altas, M. Eral, S. Sert, B. Cetinkaya and S. Inan, Chem. Eng. J., 161, 151 (2010).
M.S. Sajab, C.H. Chia, S. Zakaria, S.M. Jani, M.K. Ayob, K.L. Chee, P.S. Khiew and W.S. Chiu, Bioresour. Technol., 102, 7237 (2011).
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