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Copyright (c) 2014 Huacheng Wu, Jiangying Wang*, Jingji Zhang, Lejian Wang, Xuanrui Jia, Mingming He, Chongyuan Wang
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis of Glutathione Modified CdSe Quantum Dots and Its Application in Determination of Trace Hg2+ Ions
Corresponding Author(s) : Huacheng Wu
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
The water-soluble glutathione (GSH) modified CdSe quantum dots (QDs) were prepared. Results show that the optimum NaBH4:Se:(Cd2+): glutathione molar ratio is obtained to be 3:1:3:9. Meanwhile, the glutathione modified CdSe quantum dots synthesized by the optimum process have a single face centered cubic phase. It is found that the fluorescence quenching occurred as Hg2+ ions interact with glutathione modified CdSe quantum dots. Hg2+ ions can be determined in the concentration range of 0.3-15 μg/L, which is proposed to determine the trace quantities of Hg2+ ions as fluorescence probe.
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D.E. Nixon, M.F. Burritt and T.P. Moyer, Spectrochim. Acta B, 54, 1141 (1999).
Y. Han, Y. Li, W. Si, D. Wei, Z. Yao, X. Zheng, B. Du and Q. Wei, Spectrochim. Acta A, 79, 1546 (2011).
Y. Bonfil, M. Brand and E. Kirowa-Eisner, Anal. Chim. Acta, 424, 65 (2000).
H.A. Mckenzie and L.E. Smythe, Elsevier, New York (1998).
M.J. Bruchez Jr., M. Moronne, P. Gin, S. Weiss and A.P. Alivisatos, Science, 281, 2013 (1998).
H. Kuang, Y. Zhao, W. Ma, L.G. Xu, L.B. Wang and C.L. Xu, TrAC Trends Anal. Chem., 30, 1620 (2011).
B. Chen, Y. Yu, Z.T. Zhou and P. Zhong, Chem. Lett., 33, 1608 (2004).
A.M. Smith and S. Nie, Nat. Biotechnol., 27, 732 (2009).
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Y. Chen, Z. Chen, Y. He, H. Lin, P. Sheng, C. Liu, S. Luo and Q. Cai, Nanotechnology, 21, 125502 (2010).
H.L. Tao, X.F. Liao, M.Z. Xu, S.H. Li, F.X. Zhong and Z.S. Yi, J. Lumin., 146, 376 (2014).
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