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Vol. 26 No. 20 (2014)

Copyright (c) 2014 Chunhua Ge, Lihua Li, Rui Zhang, Rui Wang, Xiangdong Zhang*

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Amidation of Aromatic Amine and Benzoic Acid Under Boric Acid Catalysis

https://doi.org/10.14233/ajchem.2014.16900
Chunhua Ge
College of Chemistry, Liaoning University, Shenyang, Liaoning 110036, P.R. China *Corresponding author: E-mail: xdzhang@lnu.edu.cn; chhge70@gmail.com
Lihua Li
College of Chemistry, Liaoning University, Shenyang, Liaoning 110036, P.R. China *Corresponding author: E-mail: xdzhang@lnu.edu.cn; chhge70@gmail.com
Rui Zhang
College of Chemistry, Liaoning University, Shenyang, Liaoning 110036, P.R. China *Corresponding author: E-mail: xdzhang@lnu.edu.cn; chhge70@gmail.com
Rui Wang
College of Chemistry, Liaoning University, Shenyang, Liaoning 110036, P.R. China *Corresponding author: E-mail: xdzhang@lnu.edu.cn; chhge70@gmail.com
Xiangdong Zhang*
College of Chemistry, Liaoning University, Shenyang, Liaoning 110036, P.R. China *Corresponding author: E-mail: xdzhang@lnu.edu.cn; chhge70@gmail.com

Corresponding Author(s) : Chunhua Ge

Asian Journal of Chemistry, Vol. 26 No. 20 (2014)

Abstract

Synthesis of amides from the condensation reactions between aromatic amines and benzoic acids in the presence of boric acid is described. Aromatic amines include aniline 1,3-phenylenediamine and 1,4-phenylenediamine. Results indicate that the dehydrative amide procedure can be catalyzed by boric acid under mild conditions. The reaction is simple and the catalyst is readily available.

Keywords

Boric acid Catalysis Amidation Aromatic amine Aromatic acid.
Ge, C., Li, L., Zhang, R., Wang, R., & Zhang*, X. (2014). Amidation of Aromatic Amine and Benzoic Acid Under Boric Acid Catalysis. Asian Journal of Chemistry, 26(20), 6805–6807. https://doi.org/10.14233/ajchem.2014.16900
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