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Synthesis, Characterization and Thermal Stability of Polymers Containing 2,2-Bisferrocenylpropane Group
Corresponding Author(s) : Bin Dong
Asian Journal of Chemistry,
Vol. 27 No. 1 (2015): Vol 27 Issue 1
Abstract
The copolymers of 6-vinyl bisferrocenylpropane with vinylbenzene, methyl acrylate and methyl methacrylate, respectively, were obtained from ferrocene and acetone via a series of reactions. The monomer and polymers were characterized by elemental analyses, IR spectra and 1H NMR. The thermal stabilities of the polymers were studied through DTA-TG. The results show that the copolymer of 6-vinyl bisferrocenylpropane with vinylbenzene decompose in higher temperature than the copolymer of 6-vinyl bisferrocenylpropane with methyl acrylate or methyl methacrylate, indicating that the introduction of the phenyl group to the polymer can improve the thermal stability of the polymer. The decomposing temperature of the copolymer of 6-vinyl bisferrocenylpropane with methyl methacrylate is a little higher than the copolymer of 6-vinyl bisferrocenylpropane with methyl acrylate, indicating that the introduction of the methyl group to the polymer can slightly improve the thermal stability of the polymer.
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References
F.S. Arimoto and A.C. Haven Jr., J. Am. Chem. Soc., 77, 6295 (1955); doi:10.1021/ja01628a068.
R. Horikoshi and T. Mochida, Eur. J. Inorg. Chem., 34, 5355 (2010); doi:10.1002/ejic.201000525.
G. Lisa, D.A. Wilson, D. Scutaru, N. Tudorachi and N. Hurduc, Thermochim. Acta, 507-508, 49 (2010); doi:10.1016/j.tca.2010.04.030.
T. Chen, L. Wang, G. Jiang, J. Wang, X. Dong, X. Wang, J. Zhou, C. Wang and W. Wang, J. Phys. Chem. B, 109, 4624 (2005); doi:10.1021/jp0461246.
J. Raez, J.P. Tomba, I. Manners and M.A. Winnik, J. Am. Chem. Soc., 125, 9546 (2003); doi:10.1021/ja030251i.
H. Deng, W. Shen and Z. Gao, Sens. Actuators B, 168, 238 (2012); doi:10.1016/j.snb.2012.04.014.
T. Chen, L. Wang, G. Jiang, J. Wang, X. Wang, J. Zhou, W. Wang and H. Gao, Polymer, 46, 7585 (2005); doi:10.1016/j.polymer.2005.06.017.
B. Dong, X.L. Wang, Y. Fu and D.F. Li, J. Funct. Mater., S2, 197 (2012).
G. Wen and F. Li, Acta Sci. Nat. Univ. Nei Mongol, 18, 110 (1987).
F. Li and Z. Li, Acta Sci. Nat. Univ. Nei Mongol, 18, 539 (1987).
Z.R. Lin, Organometallic Chemistry, Chengdu University of Science and Technology Press, Chengdu, China (1987).