Spectroscopic Investigation of Zinc Sulphamate &minus; A Novel Non-Linear Optical Crystal

D. Jaishree; G. Kanchana; R. Kesavasamy

doi:10.14233/ajchem.2015.16854

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Vol. 27 No. 1 (2015): Vol 27 Issue 1

Issue Published : December 27, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Spectroscopic Investigation of Zinc Sulphamate − A Novel Non-Linear Optical Crystal

https://doi.org/10.14233/ajchem.2015.16854

D. Jaishree

Department of Physics, Sri Ramakrishna Institute of Technology, Coimbatore-641 010, India

G. Kanchana

Department of Physics, Government Arts College, Coimbatore-641 018, India

R. Kesavasamy

Department of Physics, Sri Ramakrishna Engineering College, Coimbatore-641 022, India

Corresponding Author(s) : D. Jaishree

jaishree.damu@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 1 (2015): Vol 27 Issue 1
Article Published : December 29, 2014

Abstract

Single crystals of zinc sulphamate were grown by slow evaporation solution growth technique at room temperature. Formation of the new crystal has been confirmed by powder and single crystal X-ray diffraction. The chemical composition of the crystal was revealed by energy dispersive X-ray analysis. The presence of functional groups in the crystal lattice has been qualitatively determined by FT-IR and FT-Raman analyses. The optical transmission spectroscopy (UV-visible) clearly evidences the suitability of this material for optical application. The non-linear optical characteristics of this material was explored by the second harmonic generation conversion efficiency.

Keywords

Non-linear optics Optical devices Materials

Jaishree, D., Kanchana, G., & Kesavasamy, R. (2014). Spectroscopic Investigation of Zinc Sulphamate − A Novel Non-Linear Optical Crystal. Asian Journal of Chemistry, 27(1), 192–194. https://doi.org/10.14233/ajchem.2015.16854

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References

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References

V.G. Dmitriev, G.G. Gurzadyan and D.N. Nilogosyan, Handbook of Non-Linear Optical Crystals, Springer Verlag, New York (1999).

M.S. Wong, C. Bosshard, F. Pan and P. Gunter, Adv. Mater., 8, 677 (1996); doi:10.1002/adma.19960080818.

R.F. Belt, G. Gashurov and Y.S. Liu, Laser Focus, 21, 110 (1985).

R. Scalark, Photon. Spectra, 22, 135 (1988).

R.J. Gamino, Bull. Mater. Res. Soc., 15, 357 (1990).

P. Hemalatha, V. Veeravazhuthi and A. Chandramohan, J. Cryst. Growth, 311, 4317 (2009); doi:10.1016/j.jcrysgro.2009.05.037.

P. Kerkoc and J. Hulliger, J. Cryst. Growth, 99, 1023 (1990); doi:10.1016/S0022-0248(08)80074-7.

F.A. Kanda and A.J. King, J. Am. Chem. Soc., 73, 2315 (1951); doi:10.1021/ja01149a119.

T. Yoshimori and T. Tanaka, Anal. Chim. Acta, 66, 85 (1973); doi:10.1016/S0003-2670(01)80204-X.

R. Valluvan, K. Selvaraju and S. Kumararaman, Mater. Chem. Phys., 97, 81 (2006); doi:10.1016/j.matchemphys.2005.07.063.

M. Lenin, N. Balamurugan and P. Ramasamy, Cryst. Res. Technol., 42, 39 (2007); doi:10.1002/crat.200610767.

P. Muthusubramanian and A.S. Raj, J. Mol. Struct., 84, 25 (1982); doi:10.1016/0022-2860(82)85107-7.

N. Vijayan, R. Ramesh Babu, R. Gopalakrishnan, P. Ramasamy and W.T.A. Harrison, J. Cryst. Growth, 262, 490 (2004); doi:10.1016/j.jcrysgro.2003.08.082.