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Vol. 28 No. 9 (2016): Vol 28 Issue 9

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Non-linear Optical Response of Triphenylamine Dyes with D-A-π-A Structure

https://doi.org/10.14233/ajchem.2016.19856
Asif Mahmood
Department of Chemistry, University of Sargodha, Sargodha 40100, Pakistan
Abdallah Mohamed Elgorban
Botany and Microbiology Department, College of Science, King Saud University, P.O. Box: 2445, Riyadh 11451, Saudi Arabia
Usman Ali Rana
Sustainable Energy Technologies (SET) Center, College of Engineering, PO-Box 800, King Saud University, Riyadh 11421, Saudi Arabia
Mudassir Hussain Tahir
Department of Chemistry, University of Sargodha, Sargodha 40100, Pakistan

Corresponding Author(s) : Asif Mahmood

asifmahmood023@gmail.com

Asian Journal of Chemistry, Vol. 28 No. 9 (2016): Vol 28 Issue 9

Abstract

In this study, we have designed new triphenylamine dyes with D-A-π-A structure and calculated their electro-optical and non-linear properties. Computational techniques were used to study the effect of additional acceptor in π-conjugated systems on absorption spectra and non-linear properties. All the dyes show absorbance in visible region. During theoretical examination polarizability (α), hyperpolarizability (β) and electronic transitions were calculated. Results indicated that the selection of appropriate lengths of conjugated bridges in dye is very important to design high efficiency dyes. This theoretical frame work would be useful to design other organic dyes.

Keywords

Organic dyes Polarizability Hyperpolarizability DFT
Mahmood, A., Elgorban, A. M., Rana, U. A., & Tahir, M. H. (2016). Non-linear Optical Response of Triphenylamine Dyes with D-A-π-A Structure. Asian Journal of Chemistry, 28(9), 1985–1988. https://doi.org/10.14233/ajchem.2016.19856
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