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Vol. 28 No. 9 (2016): Vol 28 Issue 9

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Correlation Between Boiling Temperature and Viscosity Arrhenius Activation Energy in N,N-Dimethylformamide + 2-Propanol Mixtures at 303.15 to 323.15 K

https://doi.org/10.14233/ajchem.2016.19858
H. Salhi
Université de Tunis El Manar, Laboratoire de Biophysique et Technologies Médicales, LR13ES07, Institut Supérieur des Technologies Médicales de Tunis, 9 Avenue Dr. Zouhaier Essafi, 1006 Tunis, Tunisia
N.A. Al-Omair
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, SaudiArabia
A.A. Al-Arfaj
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, SaudiArabia
M.A. Alkhaldi
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, SaudiArabia
N.O. Alzamel
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, SaudiArabia
K.Y. Alqahtani
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, SaudiArabia
N. Ouerfelli
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, SaudiArabia

Corresponding Author(s) : N.A. Al-Omair

nalomair@uod.edu.sa

Asian Journal of Chemistry, Vol. 28 No. 9 (2016): Vol 28 Issue 9

Abstract

Excess properties determined from literature of experimental density and viscosity values in N,N-dimethylformamide + 2-propanol mixtures over the temperature range from 303.15 to 323.15 K can conduct to test some correlation equations as well as their corresponding derivative properties. Investigation on the enthalpy of activation of viscous flow (ΔH*) and the Arrhenius activation energy (Ea) shows very close values. Here we can define new thermodynamic functions such as the molar partial activation energies Ea1 and Ea2 for N,N-dimethylformamide and 2-propanol, respectively and which can reveal their individual contribution separately. Causal correlation between the two viscosity Arrhenius parameters in the whole compositions range shows existence of distinct interaction behaviours delimited by particular compositions in N,N-dimethylformamide. The correlation between viscosity Arrhenius parameters shows the interesting new concept of Arrhenius temperature which is closely in relation to the temperature of vapourization in the vapour-liquid equilibrium and the limiting corresponding partial molar thermodynamic functions can permit to predict reliable values of the boiling temperature of pure liquid components.

Keywords

Viscosity Binary liquid mixture Boiling temperature Arrhenius activation energy Arrhenius temperature
Salhi, H., Al-Omair, N., Al-Arfaj, A., Alkhaldi, M., Alzamel, N., Alqahtani, K., & Ouerfelli, N. (2016). Correlation Between Boiling Temperature and Viscosity Arrhenius Activation Energy in N,N-Dimethylformamide + 2-Propanol Mixtures at 303.15 to 323.15 K. Asian Journal of Chemistry, 28(9), 1972–1984. https://doi.org/10.14233/ajchem.2016.19858
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