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Vol. 28 No. 9 (2016): Vol 28 Issue 9

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Novel Ionic Liquid Modified Mesomorphorous Materials for Preconcentration of Polysaccharides

https://doi.org/10.14233/ajchem.2016.19836
Yu Ri Lee
Department of Chemistry and Chemical Engineering Inha University, 253 Yonghyun-Dong, Nam-gu, Incheon 402-701, Republic of Korea
Yu Jin Lee
Department of Chemistry and Chemical Engineering Inha University, 253 Yonghyun-Dong, Nam-gu, Incheon 402-701, Republic of Korea
Wanwan Ma
Department of Chemistry and Chemical Engineering Inha University, 253 Yonghyun-Dong, Nam-gu, Incheon 402-701, Republic of Korea
Xiaoqin Wang
Department of Chemistry and Chemical Engineering Inha University, 253 Yonghyun-Dong, Nam-gu, Incheon 402-701, Republic of Korea
Kyung Ho Row
Department of Chemistry and Chemical Engineering Inha University, 253 Yonghyun-Dong, Nam-gu, Incheon 402-701, Republic of Korea

Corresponding Author(s) : Kyung Ho Row

rowkho@inha.ac.kr

Asian Journal of Chemistry, Vol. 28 No. 9 (2016): Vol 28 Issue 9

Abstract

Number 41 silica materials (MCM-41) as mesoporous mobil catalytic materials are attractive for applications to the adsorption and isolation of natural products. In this paper, a new type of MCM-41 material was synthesized by surface modification with an ionic liquid. The new materials were characterized used Fourier-transform infrared spectroscopy and thermogravimetric analysis. High performance size-exclusion chromatography with modified MCM-41 as the stationary phase was used to separate alginate and fucoidan to evaluate the adsorption performance on polysaccharides. The amino-MCM-41 material showed preferable adsorption potency to the polysaccharides. Under the optimal adsorption conditions, namely pH 7.0 and a time 0.5 h and 1 h for alginate and fucoidan, respectively, 68.50 mg g–1 alginate and 43.07 mg g–1 fucoidan were extracted.

Keywords

Polysaccharide Ionic liquid Mesoporous mobil catalytic materials of number Modification Alginic acid Fucoidan
Lee, Y. R., Lee, Y. J., Ma, W., Wang, X., & Row, K. H. (2016). Novel Ionic Liquid Modified Mesomorphorous Materials for Preconcentration of Polysaccharides. Asian Journal of Chemistry, 28(9), 1949–1954. https://doi.org/10.14233/ajchem.2016.19836
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