Modified Poly(p-phenylene benzoxazole) with Improved Thermal Property

Fenggui Chen

doi:10.14233/ajchem.2016.19834

Issue

Vol. 28 No. 8 (2016): Vol 28 Issue 8

Issue Published : April 30, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Modified Poly(p-phenylene benzoxazole) with Improved Thermal Property

https://doi.org/10.14233/ajchem.2016.19834

Fenggui Chen

College of Chemistry and Chemical Engineering, Yangtze Normal University, Fuling, Chongqing 408003, P.R. China; Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, P.R. China

Corresponding Author(s) : Fenggui Chen

cfg@cigit.ac.cn

Asian Journal of Chemistry, Vol. 28 No. 8 (2016): Vol 28 Issue 8
Article Published : April 30, 2016

Abstract

Poly(p-phenylene benzoxazole) (PBO) with superior thermal property were widely used in many key areas. With the development of PBO application, higher thermal stability is required. In this contribution, modified PBO, containing different content of pyridine in the macromolecular chains, were prepared via direct polycondensation of salt monomer mixtures in poly(phosphoric acid). The salt monomer mixtures were synthesized by salification of 1,3-diamino-4,6-dihydroxybenzene dihydrochloride (DAR), terephthalic acid (TPA), 2,6-pyridinedicarboxylic acid (PDA) and 2,3,5,6-tetraaminopyridine (TAP). The obtained copolymers were characterized by Fourier transform infrared, elementary analysis, X-ray diffraction and thermogravimetric analysis. It can be found that PBO based copolymers modified with low dosage of PDA and TAP exhibit improved thermal property, whose thermal decomposition temperature with 10 % weight loss can reach 620 °C in air atmosphere.

Keywords

Copolymer 4,6-Diaminoresorcinol Modified poly(p-phenylene benzoxazole) Thermal stability

Chen, F. (2016). Modified Poly(p-phenylene benzoxazole) with Improved Thermal Property. Asian Journal of Chemistry, 28(8), 1802–1806. https://doi.org/10.14233/ajchem.2016.19834

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References

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X.D. Hu, S.E. Jenkins, B.G. Min, M.B. Polk and S. Kumar, Macromol. Mater. Eng., 288, 823 (2003); doi:10.1002/mame.200300013.

H.G. Chae and S. Kumar, J. Appl. Polym. Sci., 100, 791 (2006); doi:10.1002/app.22680.

Y.-H. So, Prog. Polym. Sci., 25, 137 (2000); doi:10.1016/S0079-6700(99)00038-6.

C.C. Yang, Y. Tian, C.Y. Chen, A.K.Y. Jen and W.C. Chen, Macromol. Rapid Commun., 28, 894 (2007); doi:10.1002/marc.200600869.

J. Chin, A. Forster, C. Clerici, L. Sung, M. Oudina and K. Rice, Polym. Degrad. Stab., 92, 1234 (2007); doi:10.1016/j.polymdegradstab.2007.03.030.

M. Hasegawa, N. Suyama, N. Shimoyama, H. Aoki, T. Nunokawa and T. Kimura, Polym. Int., 60, 1240 (2011); doi:10.1002/pi.3069.

B. Song, Q. Fu, L. Ying, X. Liu, Q. Zhuang and Z. Han, J. Appl. Polym. Sci., 124, 1050 (2012); doi:10.1002/app.35178.

X.H. Xu, X.Y. Liu, Q.X. Zhuang and Z.W. Han, J. Appl. Polym. Sci., 116, 455 (2010); doi:10.1002/app.31485.

Y. Oishi, A. Konnno, J. Oravec and K. Mori, J. Photopolym. Sci. Technol., 19, 669 (2006); doi:10.2494/photopolymer.19.669.

X.H. Xu, X.Y. Liu, Q.X. Zhuang and Z.W. Han, J. Macromol. Sci. A, 47, 977 (2010); doi:10.1080/10601325.2010.506112.

S. Kumar, T.D. Dang, F.E. Arnold, A.R. Bhattacharyya, B.G. Min, X. Zhang, R.A. Vaia, C. Park, W.W. Adams, R.H. Hauge, R.E. Smalley, S. Ramesh and P.A. Willis, Macromolecules, 35, 9039 (2002); doi:10.1021/ma0205055.

J.M. Jiang, H.J. Zhu, G. Li, J.H. Jin and S.L. Yang, J. Appl. Polym. Sci., 109, 3133 (2008); doi:10.1002/app.28249.

W. Huang, S.J. Li, C.P. Du, M.R. Xie, Y.Q. Zhang and J. Yin, Eur. Polym. J., 45, 3187 (2009); doi:10.1016/j.eurpolymj.2009.08.002.

M. Ueda, H. Sugita and M. Sato, J. Polym. Sci. Pol. Chem., 24, 1019 (1986); doi:10.1002/pola.1986.080240517.

J.F. Wolfe, B.H. Loo and F.E. Arnold, Macromolecules, 14, 915 (1981); doi:10.1021/ma50005a005.

J.F. Wolfe and F.E. Arnold, Macromolecules, 14, 909 (1981); doi:10.1021/ma50005a004.

Y.H. So, J.P. Heeschen, B. Bell, P. Bonk, M. Briggs and R. DeCaire, Macromolecules, 31, 5229 (1998); doi:10.1021/ma980467i.

E.W. Choe and S.N. Kim, Macromolecules, 14, 920 (1981); doi:10.1021/ma50005a006.

H. Lin, Y.D. Huang and F. Wang, Iran. Polym. J., 17, 853 (2008).

F.G. Chen and Y.J. Xu, Asian J. Chem., 27, 2072 (2015); doi:10.14233/ajchem.2015.17738.

J. Kawachi, H. Matsubara, Y. Nakahara and Y. Watanabe, Process for Producing 4,6-Diaminoresorcinols, US Patent 5892118 (1999).

D.J. Sikkema, Polymer, 39, 5981 (1998); doi:10.1016/S0032-3861(97)10289-0.

S. Mohan, N. Sundaraganesan and J. Mink, Spectrochim. Acta A, 47A, 1111 (1991); doi:10.1016/0584-8539(91)80042-H.

Issue

Vol. 28 No. 8 (2016): Vol 28 Issue 8

Modified Poly(p-phenylene benzoxazole) with Improved Thermal Property

Corresponding Author(s) : Fenggui Chen

Abstract

Keywords

Full Article

Download Citation

References

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