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Vol. 28 No. 7 (2016): Vol 28 Issue 7

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Development of Heterogeneous Ni-Ni Complex/HPA-RNi Catalyst for Hydrogenation of Benzene

https://doi.org/10.14233/ajchem.2016.19684
Sunder Lal
Department of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal-462 003, India
Deeptiraj Pant
Department of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal-462 003, India

Corresponding Author(s) : Sunder Lal

sunderlalin@gmail.com

Asian Journal of Chemistry, Vol. 28 No. 7 (2016): Vol 28 Issue 7

Abstract

Raney nickel (RNi) was modified by (NH4)3PMo12O40 heteropoly acid (HPA) to give supported HPA-RNi through exchange of ammonium ion. A homo binuclear Ni-Ni complex was synthesized to form Ni-Ni complex/HPA-RNi heterogeneous catalyst, which was used for liquid phase benzene hydrogenation. The complex and the catalyst are well characterized and the heterogeneous catalyst thus prepared was found to be highly active at lower hydrogen pressures of 2.8-3.5 MPa and at moderate temperatures of 393-473 K. The catalyst was 100 % selective towards the formation of cyclohexane. The reaction rates of benzene reduction were considerably higher (1.4-5.0 times) compared to standard hydrogenation catalysts and comparable to those of noble metal catalysts reported in the literature. The catalyst was found to be thermally and chemically stable at higher temperatures and have shown that the hydrogenation of 100 h did not affect the nature of the catalyst.

Keywords

Benzene Complex catalyst Mo-heteropoly acid Hydrogenation Raney nickel support
Lal, S., & Pant, D. (2016). Development of Heterogeneous Ni-Ni Complex/HPA-RNi Catalyst for Hydrogenation of Benzene. Asian Journal of Chemistry, 28(7), 1447–1452. https://doi.org/10.14233/ajchem.2016.19684
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