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Vol. 28 No. 7 (2016): Vol 28 Issue 7

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Synthesis, Spectral, X-Ray Diffraction and Antibacterial Studies of Oxovanadium(IV) and Dioxouranium(VI) Complexes of N-(1-Morpholinobenzyl)semicarbazide

https://doi.org/10.14233/ajchem.2016.19786
M. Viswanathan
Department of Chemistry, Amrita School of Arts and Sciences, Amritapuri Campus, Amrita Vishwa Vidyapeetham University, P.O. Clappana, Kollam-690 525, India

Corresponding Author(s) : M. Viswanathan

viswanathanm@am.amrita.edu; drmviswanath@gmail.com

Asian Journal of Chemistry, Vol. 28 No. 7 (2016): Vol 28 Issue 7

Abstract

Oxovanadium(IV) and dioxouranium(VI) complexes of a Mannich base derived from morpholine, benzaldehyde and semicarbazide hydrochloride have been synthesized and characterized. The probable structures of these complexes were elucidated by elemental analysis, molar mass, molar conductance, spectral and X-ray diffraction studies. The formulae exhibited by complexes are: [VO(MBS)2]·2H2O and [UO2(MBS)2(H2O)2], where MBS = N-(1-morpholinobenzyl)semicarbazide. The biological activities of ligand and metal chelates against S. aureus, K. pneumoniae, P. vulgaris and E. coli were also investigated. The metal chelates have higher activity than that of free Mannich base, N-(1-morpholinobenzyl)semicarbazide.

Keywords

Oxovanadium Dioxouranium N-(1-Morpholinobenzyl)semicarbazide Antibacterial study
Viswanathan, M. (2016). Synthesis, Spectral, X-Ray Diffraction and Antibacterial Studies of Oxovanadium(IV) and Dioxouranium(VI) Complexes of N-(1-Morpholinobenzyl)semicarbazide. Asian Journal of Chemistry, 28(7), 1621–1623. https://doi.org/10.14233/ajchem.2016.19786
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