Synthesis, Characterization, Magnetic Properties and Catalytic Performance of Iron Orthoborate

Engin Meydan; Ömer Faruk Öztürk

doi:10.14233/ajchem.2016.19681

Issue

Vol. 28 No. 6 (2016): Vol 28 Issue 6

Issue Published : February 29, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Characterization, Magnetic Properties and Catalytic Performance of Iron Orthoborate

https://doi.org/10.14233/ajchem.2016.19681

Engin Meydan

Department of Chemistry, Faculty of Art & Sciences, Çanakkale Onsekiz Mart University, Çanakkale, Turkey

Ömer Faruk Öztürk

Department of Chemistry, Faculty of Art & Sciences, Çanakkale Onsekiz Mart University, Çanakkale, Turkey

Corresponding Author(s) : Ömer Faruk Öztürk

ofozturk@comu.edu.tr

Asian Journal of Chemistry, Vol. 28 No. 6 (2016): Vol 28 Issue 6
Article Published : February 29, 2016

Abstract

The structural properties of iron orthoborate samples prepared by different synthetic approaches were comparatively investigated. The structural properties of the product were characterized by powder XRD, FT-IR, UV-Vis-NIR and SEM methods and the thermal stability was analyzed by the TGA/DTA technique. The room temperature magnetic properties of the product were investigated using the vibrating sample magnetometer technique. Fe₂(SO₄)₃·H₂O was used as iron source and H₃BO₃ and B₂O₃ were used as boron sources. High temperature solid state synthesis method was used and the experiments were performed at Fe:B = 1:2, 1:3 and 1:4 mole ratios. High purity (99 %) iron orthoborate (Fe₃BO₆) was obtained from iron(III) sulfate and boric acid at 1:3 ratio. The product was observed to crystallize into orthorhombic crystal structure (Norbergite type) and cell parameters were determined as a = 10.046(2) Å, b = 8.532(2) Å and c = 4.467(1) Å values from ICDD data base. The use of Fe₃BO₆ in the catalytic reaction for the oxidation of benzyl alcohol under solvent-free conditions was tested without employing any oxidant. Benzaldehyde, dibenzyl ether and benzyl benzoate were observed to be the three main products.

Keywords

Iron borate High temperature synthesis Solid state reactions Magnetic properties Benzyl alcohol oxidation

Meydan, E., & Öztürk, Ömer F. (2016). Synthesis, Characterization, Magnetic Properties and Catalytic Performance of Iron Orthoborate. Asian Journal of Chemistry, 28(6), 1325–1329. https://doi.org/10.14233/ajchem.2016.19681

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References

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D.A. Keszler, Curr. Opin. Solid State Mater. Sci., 4, 155 (1999); doi:10.1016/S1359-0286(99)00011-X.

J.L.C. Rowsell, N.J. Taylor and L.F. Nazar, J. Solid State Chem., 174, 189 (2003); doi:10.1016/S0022-4596(03)00217-2.

I.V. Kityk, A. Majchrowski, E. Michalski, D. Kasprowicz, M. Drozdowski, J. Kisielewski, T. Lukasiewicz and B. Sahraoui, J. Phys. Chem. B, 110, 9090 (2006); doi:10.1021/jp060079f.

E.M. Levin, R.S. Roth and J.B. Martin, Am. Mineral., 46, 1030 (1961).

R.W.G. Wyckoff, Crystal Structures, Interscience Publishers, New York, edn 2, vol. 2, p. 147 (1963).

H. Schmidt, Acta Crystallogr., 17, 1080 (1964); doi:10.1107/S0365110X64002778.

J.D. Lee, Concise Inorganic Chemistry, Chapman & Hall, London, edn 4, p. 265 (1991).

J.L.C. Rowsell and L.F. Nazar, J. Mater. Chem., 11, 3228 (2001); doi:10.1039/b100707f.

C.E. Housecroft and A.G. Sharpe, Inorganic Chemistry, Pearson Education Limited, England, edn 2, p. 38 (2005).

J.L.C. Rowsell, J. Gaubicher and L.F. Nazar, J. Power Sources, 97-98, 254 (2001); doi:10.1016/S0378-7753(01)00532-8.

X. Shi, C. Chang, J. Xiang, Y. Xiao, L. Yuan and J. Sun, J. Solid State Chem., 181, 2231 (2008); doi:10.1016/j.jssc.2008.05.025.

D.C. Freitas, M.A. Continentino, R.B. Guimaraes, J.C. Fernandes, J. Ellena and L. Ghivelder, Phys. Rev. B, 77, 184422 (2008); doi:10.1103/PhysRevB.77.184422.

K. Kumari, S. Ram and R.K. Kotnala, Mater. Chem. Phys., 129, 1020 (2011); doi:10.1016/j.matchemphys.2011.05.051.

R. Shirley, The CRYSFIRE System for Automatic Powder Indexing: User’s Manual, The Lattice Press, England, p. 349 (2000).

F.J. Keller, W.E. Gettys and M.J. Skove, Physics, McGraw-Hill Publication, New York, edn 2, p. 284 (1993).

J.E. Huheey, E.A. Keiter and R.L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, HarperCollins College Publishers: New York, edn 4, p. 68 (1993).

S. Lemanceau, G. Bertrand-Chadeyron, R. Mahiou, M. El-Ghozzi, J.C. Cousseins, P. Conflant and R.N. Vannier, J. Solid State Chem., 148, 229 (1999); doi:10.1006/jssc.1999.8437.

Y. Zhang, L. Chen, K. Liang and T. Xu, J. Alloys Compd., 333, 72 (2002); doi:10.1016/S0925-8388(01)01689-9.

A. Baykal, M. Kizilyalli, G. Gözel and R. Kniep, Cryst. Res. Technol., 35, 247 (2000); doi:10.1002/1521-4079(200003)35:3<247::AID-CRAT247>3.0.CO;2-9.

V.D. Buchelnikov and S.I. Bosko, J. Magn. Magn. Mater., 258–259, 497 (2003); doi:10.1016/S0304-8853(02)01070-3.

Issue

Vol. 28 No. 6 (2016): Vol 28 Issue 6

Synthesis, Characterization, Magnetic Properties and Catalytic Performance of Iron Orthoborate

Corresponding Author(s) : Ömer Faruk Öztürk

Abstract

Keywords

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