Removal of 4-Nitrophenol from Aqueous Solution by Organo-Montmorillonites Modified with Ionic Liquids

Gülay Baysal

doi:10.14233/ajchem.2016.19542

Issue

Vol. 28 No. 4 (2016): Vol 28 Issue 4

Issue Published : December 30, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Removal of 4-Nitrophenol from Aqueous Solution by Organo-Montmorillonites Modified with Ionic Liquids

https://doi.org/10.14233/ajchem.2016.19542

Gülay Baysal

Food Engineering, Engineering Faculty, Istanbul Aydin University, Istanbul 34295, Turkey

Corresponding Author(s) : Gülay Baysal

gulaybaysal@aydin.edu.tr

Asian Journal of Chemistry, Vol. 28 No. 4 (2016): Vol 28 Issue 4
Article Published : December 30, 2015

Abstract

In this study, the removal capacity of organo-montmorillonite for a hydrophobic organic pollutant such as 4-nitrophenol was evaluated. Commercially available unmodified clay was treated under different conditions with aqueous solutions of three ionic liquids viz., 1-butyl 3-methyl imidazolium tetrafluoroborate, 1-butyl 4-methyl pyridinium tetrafluoroborate and 1-methyl 3-octyl imidazolium tetrafluoroborate. The modified materials were characterized by FTIR and WXRD analysis. The Langmuir and Freundlich were tested to fit the adsorption isotherms. The results indicate that montmorillonite modified by ionic liquids can be used as adsorbent for p-nitrophenol because of its high adsorption capacity and low cost. This study can be useful for cleaning water or analytical purposes.

Keywords

Ionic liquids Organo-montmorillonite Adsorption kinetics Adsorption isotherms 4-Nitrophenol

Baysal, G. (2015). Removal of 4-Nitrophenol from Aqueous Solution by Organo-Montmorillonites Modified with Ionic Liquids. Asian Journal of Chemistry, 28(4), 871–876. https://doi.org/10.14233/ajchem.2016.19542

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References

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References

I.D. Sand, R.L. Piner, J.W. Gilmer and J.T. Owens, Organoclays as Processing Aids for Plasticized Thermoplastics, U.S. Eastman Chemical Company, USA, p. 8 (2003).

R.L. Frost, Q. Zhou, H. He and Y. Xi, Spectrochim. Acta A, 69, 239 (2008); doi:10.1016/j.saa.2007.02.023.

Q. Zhou, H.P. He, J.X. Zhu, W. Shen, R.L. Frost and P. Yuan, J. Hazard. Mater., 154, 1025 (2008); doi:10.1016/j.jhazmat.2007.11.009.

J.H. Kim, W.S. Shin, Y.H. Kim, S.J. Choi, Y.W. Jeon and D.I. Song, Water Sci. Technol., 47, 59 (2003).

Y. Park, G.A. Ayoko and R.L. Frost, J. Colloid Interf. Sci., 360, 440 (2011); doi:10.1016/j.jcis.2011.04.085.

H. Zheng, K. Jiang, T. Abe and Z. Ogumi, Carbon, 203, 44 (2006).

G. Baysal, H. Aydin, S. Koytepe and T. Seckin¸, Thermochim. Acta, 566, 305 (2013); doi:10.1016/j.tca.2013.04.036.

H. Erdemi, Ü. Akbey and H.W. Meyer, Solid State Ion., 181, 1586 (2010); doi:10.1016/j.ssi.2010.08.018.

V.V. Namboodiri and R.S. Varma, Tetrahedron Lett., 43, 5381 (2002); doi:10.1016/S0040-4039(02)01075-4.

H. Ohno and M.Yoshizawa, Solid State Ion., 154-155, 303 (2002); doi:10.1016/S0167-2738(02)00526-X.

R. Kanzaki, T. Mitsugi, S. Fukuda, K. Fujii, M. Takeuchi, Y. Soejima, T. Takamuku, T. Yamaguchi, Y. Umebayashi and S. Ishiguro, J. Mol. Liq., 147, 77 (2009); doi:10.1016/j.molliq.2008.10.003.

M. Shamsipur, A.A.M. Beigi, M. Teymouri, S.M. Pourmortazavi and M. Irandoust, J. Mol. Liq., 157, 43 (2010); doi:10.1016/j.molliq.2010.08.005.

N.E. Heimer, R.E. Del Sesto, Z. Meng, J.S. Wilkes and W.R. Carper, J. Mol. Liq., 124, 84 (2006); doi:10.1016/j.molliq.2005.08.004.

A. Chagnes, H. Allouchi, B. Carre and D. Lemordant, Solid State Ion., 176, 1419 (2005); doi:10.1016/j.ssi.2005.03.005.

G. Varank, A. Demir, K. Yetilmezsoy, S. Top, E. Sekman and M.S. Bilgili, Indian J. Chem. Technol., 19, 7 (2012).

J. Li, D. Kuang, Y. Feng, F. Zhang, Z. Xu and M. Liu, J. Hazard. Mater., 201-202, 250 (2012); doi:10.1016/j.jhazmat.2011.11.076.

A. Tor, Y. Cengeloglu and M. Ersoz, Desalination, 242, 19 (2009); doi:10.1016/j.desal.2008.03.028.

N.H. Kim, S.V. Malhotra and M. Xanthos, Micropor. Mesopor. Mater., 96, 29 (2006); doi:10.1016/j.micromeso.2006.06.017.

F. Zermane, O. Bouras, M. Baudu and J.P. Basly, J. Colloid Interf. Sci., 350, 315 (2010); doi:10.1016/j.jcis.2010.06.040.

N.Z. Al-Mutairi, Desalination, 250, 892 (2010); doi:10.1016/j.desal.2008.10.035.

H. Aydin and G. Baysal, Desalination, 196, 248 (2006); doi:10.1016/j.desal.2005.11.025.

L.B. de Paiva, A.R. Morales and F.R. Valenzuela Díaz, Appl. Clay Sci., 42, 8 (2008); doi:10.1016/j.clay.2008.02.006.

L. Wei, H. Zhu, X. Mao and F. Gan, Sep. Purif. Technol., 77, 18 (2011); doi:10.1016/j.seppur.2010.11.007.

M. Sathishkumar, A. Binupriya, D. Kavitha and S. Yun, Bioresour. Technol., 98, 866 (2007); doi:10.1016/j.biortech.2006.03.002.

R. Liu, R.L. Frost, W.N. Martens and Y. Yuan, J. Colloid Interf. Sci., 327, 287 (2008); doi:10.1016/j.jcis.2008.08.049.

X. Xin, J. Wang, H.Q. Yu, B. Du, Q. Wei and L.G. Yan, Environ. Technol., 32, 447 (2011); doi:10.1080/09593330.2010.502187.

M. Zahoor and M. Mahramanlioglu, Sep. Sci. Technol., 46, 1482 (2011); doi:10.1080/01496395.2011.561269.

Issue

Vol. 28 No. 4 (2016): Vol 28 Issue 4

Removal of 4-Nitrophenol from Aqueous Solution by Organo-Montmorillonites Modified with Ionic Liquids

Corresponding Author(s) : Gülay Baysal

Abstract

Keywords

Full Article

Download Citation

References

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