12-Tungstophosphoric Acid/Silica Catalyst for Oxidation of Benzothiophene

Aldes Lesbani; Arianti Marpaung; Najma Annuria Fithri; Risfidian Mohadi

doi:10.14233/ajchem.2016.19435

Issue

Vol. 28 No. 3 (2016): Vol 28 Issue 3

Issue Published : December 5, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

12-Tungstophosphoric Acid/Silica Catalyst for Oxidation of Benzothiophene

https://doi.org/10.14233/ajchem.2016.19435

Aldes Lesbani

Department of Chemistry, Faculty of Mathematic and Natural Sciences, Sriwijaya University, Kampus UNSRI Inderalaya, Jl. Palembang Prabumulih Km32 Ogan Ilir 30662, South Sumatera, Indonesia

Arianti Marpaung

Department of Chemistry, Faculty of Mathematic and Natural Sciences, Sriwijaya University, Kampus UNSRI Inderalaya, Jl. Palembang Prabumulih Km32 Ogan Ilir 30662, South Sumatera, Indonesia

Najma Annuria Fithri

Department of Pharmacy, Faculty of Mathematic and Natural Sciences, Sriwijaya University, Kampus UNSRI Inderalaya, Jl. Palembang Prabumulih Km32 Ogan Ilir 30662, South Sumatera, Indonesia

Risfidian Mohadi

Department of Chemistry, Faculty of Mathematic and Natural Sciences, Sriwijaya University, Kampus UNSRI Inderalaya, Jl. Palembang Prabumulih Km32 Ogan Ilir 30662, South Sumatera, Indonesia

Corresponding Author(s) : Aldes Lesbani

aldeslesbani@yahoo.com

Asian Journal of Chemistry, Vol. 28 No. 3 (2016): Vol 28 Issue 3
Article Published : December 5, 2015

Abstract

12-Tungstophosphoric acid H₃[a-PW₁₂O₄₀] was impregnated with silica to form 12-tungstophosphoric acid/silica catalyst. Structural properties of catalyst were characterized using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and nitrogen adsorption desorption. The results showed that silica was impregnated into H₃[a-PW₁₂O₄₀] with increasing surface area properties. The catalytic activity under mild condition from H₃[a-PW₁₂O₄₀] after impregnation with silica slightly increased compared to original catalyst. The structure of catalyst after reaction was stable, which indicate the possibility of reusing the catalyst.

Keywords

12-Tungstophosphoric acid Silica Benzothiophene Oxidation

Lesbani, A., Marpaung, A., Fithri, N. A., & Mohadi, R. (2015). 12-Tungstophosphoric Acid/Silica Catalyst for Oxidation of Benzothiophene. Asian Journal of Chemistry, 28(3), 617–621. https://doi.org/10.14233/ajchem.2016.19435

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References

Y. Shiraishi, Y. Taki, T. Hirai and I. Komasawa, Ind. Eng. Chem. Res., 40, 1213 (2001); doi:10.1021/ie000547m.
J. Xu, H. Li, S. Wang, F. Luo, Y. Liu, X. Wang and Z. Jiang, Chemosphere, 111, 631 (2014); doi:10.1016/j.chemosphere.2014.05.033.
Z. Long, C. Yang, G. Zeng, L. Peng, C. Dai and H. He, Fuel, 130, 19 (2014); doi:10.1016/j.fuel.2014.04.005.
J.L. García-Gutiérrez, G.C. Laredo, P. García-Gutiérrez and F. Jimenez-Cruz, Fuel, 138, 118 (2014); doi:10.1016/j.fuel.2014.07.049.
M. Chamack, A.R. Mahjoub and H. Aghayan, Chem. Eng. J., 255, 686 (2014); doi:10.1016/j.cej.2014.06.054.
G. Zhang, F. Yu and R. Wang, Petroleum Coal, 51, 196 (2009).
W. Trakarnpruk and K. Rujiraworawut, Fuel Process. Technol., 90, 411 (2009); doi:10.1016/j.fuproc.2008.11.002.
A. Lesbani and R. Mohadi, Bull. Chem. React.Eng. Catal., 9, 136 (2014); doi:10.9767/bcrec.9.2.6074.136-141.
A. Lesbani, F. Fitriliana and R. Mohadi, Indo. J. Chem, 15, 1 (2015).
Y. Wang and A. Gaffney, Catal. Today, 156, 1 (2010); doi:10.1016/j.cattod.2010.07.002.
H.Y. Lü, W.Z. Ren, W.P. Liao, W. Chen, Y. Li and Z.H. Suo, Appl. Catal. B, 138-139, 79 (2013); doi:10.1016/j.apcatb.2013.02.034.
S. Ribeiro, A.D.S. Barbosa, A.C. Gomes, M. Pillinger, I.S. Gonçalves, L. Cunha-Silva and S.S. Balula, Fuel Process. Technol., 116, 350 (2013); doi:10.1016/j.fuproc.2013.07.011.
A. Lesbani, A. Marpaung, M. Verawaty, H.R. Amalia and R.Mohadi, J. Pure Appl. Chem. Res., 4, 5 (2015).
A. Lesbani, A. Agnes, R.O. Saragih, M. Verawaty, R. Mohadi and H. Zulkifli, Bull. Chem. React. Eng. Catal., 10, 185 (2015); doi:10.9767/bcrec.10.2.7734.185-191.
B.K. Min, A.K. Santra and D.W. Goodman, Catal. Today, 85, 113 (2003); doi:10.1016/S0920-5861(03)00380-8.
J.C. Bailar Jr., E.M. Jones, H.S. Booth and M. Grennert, Inorg. Synth., 1, 35 (1939); doi:10.1002/9780470132326.ch13.
A.D. Newman, D.R. Brown, P. Siril, A.F. Lee and K. Wilson, Phys. Chem. Chem. Phys., 8, 2893 (2006); doi:10.1039/b603979k.
F.L. Yu, Y.Y. Wang, C.Y. Liu, C.X. Xie and S.T. Yu, Chem. Eng. J., 255, 372 (2014); doi:10.1016/j.cej.2014.06.087.
A.M. Fattahi, M.R. Omidkhah, A.Z. Moghaddam and A. Akbari, Petroleum Coal, 56, 442 (2014).
S. Uchida, S. Hikichi, T. Akatsuka, T. Tanaka, R. Kawamoto, A. Lesbani, Y. Nakagawa, K. Uehara and N. Mizuno, Chem. Mater., 19, 4694 (2007); doi:10.1021/cm071565y.
C.P. Pradeep, D.-L. Long and L. Cronin, Dalton Trans., 39, 9443 (2010); doi:10.1039/c0dt00325e.

References

Y. Shiraishi, Y. Taki, T. Hirai and I. Komasawa, Ind. Eng. Chem. Res., 40, 1213 (2001); doi:10.1021/ie000547m.

J. Xu, H. Li, S. Wang, F. Luo, Y. Liu, X. Wang and Z. Jiang, Chemosphere, 111, 631 (2014); doi:10.1016/j.chemosphere.2014.05.033.

Z. Long, C. Yang, G. Zeng, L. Peng, C. Dai and H. He, Fuel, 130, 19 (2014); doi:10.1016/j.fuel.2014.04.005.

J.L. García-Gutiérrez, G.C. Laredo, P. García-Gutiérrez and F. Jimenez-Cruz, Fuel, 138, 118 (2014); doi:10.1016/j.fuel.2014.07.049.

M. Chamack, A.R. Mahjoub and H. Aghayan, Chem. Eng. J., 255, 686 (2014); doi:10.1016/j.cej.2014.06.054.

G. Zhang, F. Yu and R. Wang, Petroleum Coal, 51, 196 (2009).

W. Trakarnpruk and K. Rujiraworawut, Fuel Process. Technol., 90, 411 (2009); doi:10.1016/j.fuproc.2008.11.002.

A. Lesbani and R. Mohadi, Bull. Chem. React.Eng. Catal., 9, 136 (2014); doi:10.9767/bcrec.9.2.6074.136-141.

A. Lesbani, F. Fitriliana and R. Mohadi, Indo. J. Chem, 15, 1 (2015).

Y. Wang and A. Gaffney, Catal. Today, 156, 1 (2010); doi:10.1016/j.cattod.2010.07.002.

H.Y. Lü, W.Z. Ren, W.P. Liao, W. Chen, Y. Li and Z.H. Suo, Appl. Catal. B, 138-139, 79 (2013); doi:10.1016/j.apcatb.2013.02.034.

S. Ribeiro, A.D.S. Barbosa, A.C. Gomes, M. Pillinger, I.S. Gonçalves, L. Cunha-Silva and S.S. Balula, Fuel Process. Technol., 116, 350 (2013); doi:10.1016/j.fuproc.2013.07.011.

A. Lesbani, A. Marpaung, M. Verawaty, H.R. Amalia and R.Mohadi, J. Pure Appl. Chem. Res., 4, 5 (2015).

A. Lesbani, A. Agnes, R.O. Saragih, M. Verawaty, R. Mohadi and H. Zulkifli, Bull. Chem. React. Eng. Catal., 10, 185 (2015); doi:10.9767/bcrec.10.2.7734.185-191.

B.K. Min, A.K. Santra and D.W. Goodman, Catal. Today, 85, 113 (2003); doi:10.1016/S0920-5861(03)00380-8.

J.C. Bailar Jr., E.M. Jones, H.S. Booth and M. Grennert, Inorg. Synth., 1, 35 (1939); doi:10.1002/9780470132326.ch13.

A.D. Newman, D.R. Brown, P. Siril, A.F. Lee and K. Wilson, Phys. Chem. Chem. Phys., 8, 2893 (2006); doi:10.1039/b603979k.

F.L. Yu, Y.Y. Wang, C.Y. Liu, C.X. Xie and S.T. Yu, Chem. Eng. J., 255, 372 (2014); doi:10.1016/j.cej.2014.06.087.

A.M. Fattahi, M.R. Omidkhah, A.Z. Moghaddam and A. Akbari, Petroleum Coal, 56, 442 (2014).

S. Uchida, S. Hikichi, T. Akatsuka, T. Tanaka, R. Kawamoto, A. Lesbani, Y. Nakagawa, K. Uehara and N. Mizuno, Chem. Mater., 19, 4694 (2007); doi:10.1021/cm071565y.

C.P. Pradeep, D.-L. Long and L. Cronin, Dalton Trans., 39, 9443 (2010); doi:10.1039/c0dt00325e.

Issue

Vol. 28 No. 3 (2016): Vol 28 Issue 3

12-Tungstophosphoric Acid/Silica Catalyst for Oxidation of Benzothiophene

Corresponding Author(s) : Aldes Lesbani

Abstract

Keywords

Full Article

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