HPLC Determination and Comparative Analysis of Persistent Organic Compounds in Different Environmental Matrices

Nikhat Khan; Maham Ali; Ghazala Yaqub; Zubi Sadiq

doi:10.14233/ajchem.2016.19313

Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

Issue Published : November 3, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

HPLC Determination and Comparative Analysis of Persistent Organic Compounds in Different Environmental Matrices

https://doi.org/10.14233/ajchem.2016.19313

Nikhat Khan

Department of Environmental Sciences, Kinnaird College for Women, Lahore-54000, Pakistan

Maham Ali

Department of Environmental Sciences, Kinnaird College for Women, Lahore-54000, Pakistan

Ghazala Yaqub

Department of Environmental Sciences, Kinnaird College for Women, Lahore-54000, Pakistan

Zubi Sadiq

Department of Chemistry, Lahore College for Women University, Lahore-54000, Pakistan

Corresponding Author(s) : Ghazala Yaqub

ghazala_yaqub@yahoo.com

Asian Journal of Chemistry, Vol. 28 No. 2 (2016): Vol 28 Issue 2
Article Published : November 3, 2015

Abstract

The application of easy, low-cost and effective sample preparation approach for the determination of different categories of persistent organic compounds, fruit, vegetable, soil and water samples was conducted. After extraction of environmental matrices, targeted persistent residues of lufenron, imidacloprid, dimethomorph, paraquat, glyphosate, bifenthrin and difenoconazole were determined by the method validation of high performance liquid chromatography in the collected samples from the agricultural areas of Lahore and Rahim Yaar Khan, Pakistan. All fruits and vegetables were found to be contaminated with persistent organic compounds with the values exceeding maximum residue limits (MRLs) of Codex Alimentarius Commission. Present study is a contribution in scientific research that gives the comparative analysis of persistent organic compounds under various environmental conditions.

Keywords

Persistent organic compounds High performance liquid chromatography Maximum residue limits

Khan, N., Ali, M., Yaqub, G., & Sadiq, Z. (2015). HPLC Determination and Comparative Analysis of Persistent Organic Compounds in Different Environmental Matrices. Asian Journal of Chemistry, 28(2), 339–342. https://doi.org/10.14233/ajchem.2016.19313

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References

S. Manahan, Environmental Chemistry, Lewis Publishers/CRC Press LLC, London, edn 7 (2000).
J. Buccini and H. Fiedler, The Development of a Global Treaty on Persistent Organic Pollutants (POPs), The Hand Book of Environmental Chemistry, Persistent Organic Pollutants, Springer-Verlag, Berlin/Heidelberg, edn 3 (2003).
M.H. Wong, A.O.W. Leung, J.K.Y. Chan and M.P.K. Choi, Chemosphere, 60, 740 (2005); doi:10.1016/j.chemosphere.2005.04.028.
F. Mason and N. Barak, Chemosphere, 21, 695 (1990); doi:10.1016/0045-6535(90)90036-S.
G. Zhao, Y. Xu, G. Han and B. Ling, Environ. Geochem. Health, 28, 341 (2006); doi:10.1007/s10653-005-9003-3.
M.S. El-Shahawi, A. Hamza, A.S. Bashammakh and W.T. Al-Saggaf, Talanta, 80, 1587 (2010); doi:10.1016/j.talanta.2009.09.055.
Z. Parveen, M. Khuhro and N. Rafiq, Bull. Environ. Contam. Toxicol., 74, 170 (2005); doi:10.1007/s00128-004-0564-0.
Z. Knezević and M.Serdar, Food Contr., 20, 419 (2009); doi:10.1016/j.foodcont.2008.07.014.
F.A. Mansoor-ul-Hassan, M. Sagheer, M.F. Iqbal and M. Tariq, Pak. Entomol., 27, 53 (2005).
F.J. Arrebola, J.L. Martínez Vidal, M. Mateu-Sánchez and F.J. Álvarez-Castellón, Anal. Chim. Acta, 484, 167 (2003); doi:10.1016/S0003-2670(03)00332-5.
M. Möder, P. Popp, R. Eisert and J. Pawliszyn, Fresenius J. Anal. Chem., 363, 680 (1999); doi:10.1007/s002160051271.
C. Ngan, U. Cheah, W.W. Abdullah, K. Lim and B. Ismail, Water Air Soil Pollut. Focus, 5, 125 (2005); doi:10.1007/s11267-005-7408-8.
T.K. Choudhury, K.O. Gerhardt and T.P. Mawhinney, Environ. Sci. Technol., 30, 3259 (1996); doi:10.1021/es960040w.
K. Jinno, T. Muramatsu, Y. Saito, Y. Kiso, S. Magdic and J. Pawliszyn, J. Chromatogr. A, 754, 137 (1996); doi:10.1016/S0021-9673(96)00212-9.
D. Clark, T. McElligott and E.W. Hurst, Br. J. Ind. Med., 23, 126 (1966).
A. Calderbank, Reviews of Environmental Contamination and Toxicology, Springer, pp. 71-103 (1989).
R. Frank, B.D. Ripley, H.E. Braun, B.S. Clegg, R. Johnston and T.J. O'Neill, Arch. Environ. Contam. Toxicol., 16, 1 (1987); doi:10.1007/BF01055354.
C. Wesseling, B.V.W. de Joode, C. Ruepert, C. León, P. Monge, H. Hermosillo and L.J. Partanen, Int. J. Occup. Environ. Health, 7, 275 (2001); doi:10.1179/oeh.2001.7.4.275.
S. Baskaran, R.S. Kookana and R. Naidu, Pestic. Sci., 55, 1222 (1999); doi:10.1002/(SICI)1096-9063(199912)55:12<1222::AID-PS83>3.0.CO;2-7.
J.M. Hougard, S.P. Duchon, M. Zaim and P. Guillet, J. Med. Entomol., 39, 526 (2002); doi:10.1603/0022-2585-39.3.526.
I. Mukherjee, R. Singh and J. Govil, Bull. Environ. Contam. Toxicol., 84, 294 (2010); doi:10.1007/s00128-010-9940-0.
S. Swart, M. Wingfield, W. Swart and G. Schutte, Ann. Appl. Biol., 133, 17 (1998); doi:10.1111/j.1744-7348.1998.tb05798.x.
X. Dong, L.Q. Ma, Y. Zhu, Y. Li and B. Gu, Environ. Sci. Technol., 47, 12156 (2013); doi:10.1021/es4017816.
L. Samsøe-Petersen, E.H. Larsen, P.B. Larsen and P. Bruun, Environ. Sci. Technol., 36, 3057 (2002); doi:10.1021/es015691t.
T. Anwar, I. Ahmad and S. Tahir, J. Pak. Bot., 43, 1133 (2011).
S.A. Baig, N.A. Akhtera, M. Ashfaq and M.R. Asi, Am.-Eurasian J. Agric. Environ. Sci., 6, 513 (2009).
S. Hussain, T. Masud and K. Ahad, Pakistan J. Nutr., 1, 41 (2002); doi:10.3923/pjn.2002.41.42.
B.A. Khan, A. Farid, M.R. Asi, H. Shah and A.K. Badshah, Food Chem., 114, 286 (2009); doi:10.1016/j.foodchem.2008.08.092.
M.S. Khan, M.M. Shah, Q. Mahmood, A. Hassan and K. Akbar, J. Chem. Soc. Pak., 33, 816 (2011).
Y. Latif, S. Sherazi and M. Bhanger, Ecotoxicol. Environ. Saf., 74, 2299 (2011); doi:10.1016/j.ecoenv.2011.07.030.
S.Z. Masud and N. Hasan, in ed.: M. Richardson, Pesticides Residues in Foodstuffs in Pakistan: Organochlorine, Organophosphorus and Pyrethroid Insecticides in Fruits and Vegetables, In: Environmental Toxicology Assessment, Taylor and Francis, London, pp. 269-279 (1995).
M.U. Tahir, S.I. Naik, S. Rehman and M. Shahzad, Biomedica, 25, 171 (2009).
S. Tahir and T. Anwar, Bull. Environ. Contam. Toxicol., 89, 1138 (2012); doi:10.1007/s00128-012-0857-7.

References

S. Manahan, Environmental Chemistry, Lewis Publishers/CRC Press LLC, London, edn 7 (2000).

J. Buccini and H. Fiedler, The Development of a Global Treaty on Persistent Organic Pollutants (POPs), The Hand Book of Environmental Chemistry, Persistent Organic Pollutants, Springer-Verlag, Berlin/Heidelberg, edn 3 (2003).

M.H. Wong, A.O.W. Leung, J.K.Y. Chan and M.P.K. Choi, Chemosphere, 60, 740 (2005); doi:10.1016/j.chemosphere.2005.04.028.

F. Mason and N. Barak, Chemosphere, 21, 695 (1990); doi:10.1016/0045-6535(90)90036-S.

G. Zhao, Y. Xu, G. Han and B. Ling, Environ. Geochem. Health, 28, 341 (2006); doi:10.1007/s10653-005-9003-3.

M.S. El-Shahawi, A. Hamza, A.S. Bashammakh and W.T. Al-Saggaf, Talanta, 80, 1587 (2010); doi:10.1016/j.talanta.2009.09.055.

Z. Parveen, M. Khuhro and N. Rafiq, Bull. Environ. Contam. Toxicol., 74, 170 (2005); doi:10.1007/s00128-004-0564-0.

Z. Knezević and M.Serdar, Food Contr., 20, 419 (2009); doi:10.1016/j.foodcont.2008.07.014.

F.A. Mansoor-ul-Hassan, M. Sagheer, M.F. Iqbal and M. Tariq, Pak. Entomol., 27, 53 (2005).

F.J. Arrebola, J.L. Martínez Vidal, M. Mateu-Sánchez and F.J. Álvarez-Castellón, Anal. Chim. Acta, 484, 167 (2003); doi:10.1016/S0003-2670(03)00332-5.

M. Möder, P. Popp, R. Eisert and J. Pawliszyn, Fresenius J. Anal. Chem., 363, 680 (1999); doi:10.1007/s002160051271.

C. Ngan, U. Cheah, W.W. Abdullah, K. Lim and B. Ismail, Water Air Soil Pollut. Focus, 5, 125 (2005); doi:10.1007/s11267-005-7408-8.

T.K. Choudhury, K.O. Gerhardt and T.P. Mawhinney, Environ. Sci. Technol., 30, 3259 (1996); doi:10.1021/es960040w.

K. Jinno, T. Muramatsu, Y. Saito, Y. Kiso, S. Magdic and J. Pawliszyn, J. Chromatogr. A, 754, 137 (1996); doi:10.1016/S0021-9673(96)00212-9.

D. Clark, T. McElligott and E.W. Hurst, Br. J. Ind. Med., 23, 126 (1966).

A. Calderbank, Reviews of Environmental Contamination and Toxicology, Springer, pp. 71-103 (1989).

R. Frank, B.D. Ripley, H.E. Braun, B.S. Clegg, R. Johnston and T.J. O'Neill, Arch. Environ. Contam. Toxicol., 16, 1 (1987); doi:10.1007/BF01055354.

C. Wesseling, B.V.W. de Joode, C. Ruepert, C. León, P. Monge, H. Hermosillo and L.J. Partanen, Int. J. Occup. Environ. Health, 7, 275 (2001); doi:10.1179/oeh.2001.7.4.275.

S. Baskaran, R.S. Kookana and R. Naidu, Pestic. Sci., 55, 1222 (1999); doi:10.1002/(SICI)1096-9063(199912)55:12<1222::AID-PS83>3.0.CO;2-7.

J.M. Hougard, S.P. Duchon, M. Zaim and P. Guillet, J. Med. Entomol., 39, 526 (2002); doi:10.1603/0022-2585-39.3.526.

I. Mukherjee, R. Singh and J. Govil, Bull. Environ. Contam. Toxicol., 84, 294 (2010); doi:10.1007/s00128-010-9940-0.

S. Swart, M. Wingfield, W. Swart and G. Schutte, Ann. Appl. Biol., 133, 17 (1998); doi:10.1111/j.1744-7348.1998.tb05798.x.

X. Dong, L.Q. Ma, Y. Zhu, Y. Li and B. Gu, Environ. Sci. Technol., 47, 12156 (2013); doi:10.1021/es4017816.

L. Samsøe-Petersen, E.H. Larsen, P.B. Larsen and P. Bruun, Environ. Sci. Technol., 36, 3057 (2002); doi:10.1021/es015691t.

T. Anwar, I. Ahmad and S. Tahir, J. Pak. Bot., 43, 1133 (2011).

S.A. Baig, N.A. Akhtera, M. Ashfaq and M.R. Asi, Am.-Eurasian J. Agric. Environ. Sci., 6, 513 (2009).

S. Hussain, T. Masud and K. Ahad, Pakistan J. Nutr., 1, 41 (2002); doi:10.3923/pjn.2002.41.42.

B.A. Khan, A. Farid, M.R. Asi, H. Shah and A.K. Badshah, Food Chem., 114, 286 (2009); doi:10.1016/j.foodchem.2008.08.092.

M.S. Khan, M.M. Shah, Q. Mahmood, A. Hassan and K. Akbar, J. Chem. Soc. Pak., 33, 816 (2011).

Y. Latif, S. Sherazi and M. Bhanger, Ecotoxicol. Environ. Saf., 74, 2299 (2011); doi:10.1016/j.ecoenv.2011.07.030.

S.Z. Masud and N. Hasan, in ed.: M. Richardson, Pesticides Residues in Foodstuffs in Pakistan: Organochlorine, Organophosphorus and Pyrethroid Insecticides in Fruits and Vegetables, In: Environmental Toxicology Assessment, Taylor and Francis, London, pp. 269-279 (1995).

M.U. Tahir, S.I. Naik, S. Rehman and M. Shahzad, Biomedica, 25, 171 (2009).

S. Tahir and T. Anwar, Bull. Environ. Contam. Toxicol., 89, 1138 (2012); doi:10.1007/s00128-012-0857-7.

Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

HPLC Determination and Comparative Analysis of Persistent Organic Compounds in Different Environmental Matrices

Corresponding Author(s) : Ghazala Yaqub

Abstract

Keywords

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