Highly Selective Quinoline-Based Fluorescent Probe for Copper(II) Ions

L.J. Wang; X.X. Yan; F.L. Tian

doi:10.14233/ajchem.2016.19266

Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

Issue Published : November 3, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Highly Selective Quinoline-Based Fluorescent Probe for Copper(II) Ions

https://doi.org/10.14233/ajchem.2016.19266

L.J. Wang

No. 235, Daxue West Road, Inner Mongolia University, Hohhot, P.R. China

X.X. Yan

No. 235, Daxue West Road, Inner Mongolia University, Hohhot, P.R. China

F.L. Tian

College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot, P.R. China

Corresponding Author(s) : F.L. Tian

ftian@imu.edu.cn; 553205582@qq.com

Asian Journal of Chemistry, Vol. 28 No. 2 (2016): Vol 28 Issue 2
Article Published : November 3, 2015

Abstract

A novel fluorescent probe based on 8-hydroxy-2-methyl quinoline has been designed and synthesized to detect Cu²⁺ ions. The probe showed a fluorescence turn-off response for Cu²⁺ over other metal ions such as Na⁺, K⁺, Mg²⁺, Ca²⁺, Ba²⁺, Ag⁺, Cd²⁺, Zn²⁺, Co²⁺, Fe²⁺ and Pb²⁺ in CH₃CN/H₂O solution (v/v, 4:1, pH = 7.68) with specific selectivity and high sensitivity. The fluorescence emission of the probe was immediately quenched after addition of Cu²⁺ in CH₃CN/H₂O solution (v/v, 4:1, pH = 7.68) due to photoinduced electron transfer mechanism. The binding ratio between the probe and Cu²⁺ ions was determined to be 2:1.

Keywords

Quinoline Fluorescence Copper(II) ions

Wang, L., Yan, X., & Tian, F. (2015). Highly Selective Quinoline-Based Fluorescent Probe for Copper(II) Ions. Asian Journal of Chemistry, 28(2), 291–294. https://doi.org/10.14233/ajchem.2016.19266

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Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

Highly Selective Quinoline-Based Fluorescent Probe for Copper(II) Ions

Corresponding Author(s) : F.L. Tian

Abstract

Keywords

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