Bismuth Ions Selective Fluorescent Chemosensor Based on Rhodamine-B

Lianwei Yu; Jianfei Tian; Fuli Tian

doi:10.14233/ajchem.2016.19264

Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

Issue Published : November 3, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Bismuth Ions Selective Fluorescent Chemosensor Based on Rhodamine-B

https://doi.org/10.14233/ajchem.2016.19264

Lianwei Yu

College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P.R. China

Jianfei Tian

College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P.R. China

Fuli Tian

College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P.R. China

Corresponding Author(s) : Fuli Tian

ftian@imu.edu.cn; 2803546043@qq.com

Asian Journal of Chemistry, Vol. 28 No. 2 (2016): Vol 28 Issue 2
Article Published : November 3, 2015

Abstract

A new rhodamine-based compound (L1) has been synthesized and applied as an “off-on” chemosensor for Bi³⁺. The complexation behaviour of chemosensor with different metal ions including Bi³⁺ ions in EtOH/H₂O (4:1, v/v) was studied on UV-visible absorption spectra and fluorescent spectra. Results showed that the chemosensor (L1) is highly selective for Bi³⁺ over other cations such as Hg²⁺, Fe²⁺, Mn²⁺ and Ca²⁺. This selectivity can be attributed to the photoinduced electron transfer mechanism (PET) of the sensor in the presence of Bi³⁺. The complex solution (L1-Bi³⁺) exhibited reversibility with EDTA.

Keywords

Rhodamine-B Fluorescent chemosensor Bismuth ions

Yu, L., Tian, J., & Tian, F. (2015). Bismuth Ions Selective Fluorescent Chemosensor Based on Rhodamine-B. Asian Journal of Chemistry, 28(2), 287–290. https://doi.org/10.14233/ajchem.2016.19264

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References

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Z.-X. Han, B.-S. Zhu, T.-L. Wu, Q.-Q. Yang, Y.-L. Xue, Z. Zhang and X.-Y. Wu, Chin. Chem. Lett., 25, 73 (2014); doi:10.1016/j.cclet.2013.10.027.

T. Yu, J. Meng, Y. Zhao, H. Zhang, X. Han and D. Fan, Spectrochim. Acta A Mol. Biomol. Spectrosc., 78, 396 (2011); doi:10.1016/j.saa.2010.10.027.

M. Hranjec, E. Horak, M. Tireli, G. Pavlović and G. Karminski-Zamola, Dyes Pigments, 95, 644 (2012); doi:10.1016/j.dyepig.2012.05.024.

M.X. Wang, X.M. Meng, M.Z. Zhu and Q.X. Guo, Chin. Chem. Lett., 19, 977 (2008); doi:10.1016/j.cclet.2008.05.010.

Q. Liu, G.-P. Li, D.-J. Zhu, L. Xue and H. Jiang, Chin. Chem. Lett., 24, 479 (2013); doi:10.1016/j.cclet.2013.04.002.

V.K. Gupta, A.K. Singh and L.K. Kumawat, Sens. Actuators B, 204, 507 (2014); doi:10.1016/j.snb.2014.07.128.

L. Zhu, C.Y. Gu, Y. He and G. Wang, J. Lumin., 153, 439 (2014); doi:10.1016/j.jlumin.2014.03.067.

Y. Liu, E.-B. Yang, R. Han, D. Zhang, Y. Ye and Y.-F. Zhao, Chin. Chem. Lett., 25, 1065 (2014); doi:10.1016/j.cclet.2014.04.033.

Y.-Y. Wu, Y. Chen, W.-H. Mu, X.-J. Lv and W.-F. Fu, J. Photochem. Photobiol. Chem., 272, 73 (2013); doi:10.1016/j.jphotochem.2013.08.015.

H.G. Lee, J.H. Lee, S.P. Jang, I.H. Hwang, S.-J. Kim, Y. Kim, C. Kim and R.G. Harrison, Inorg. Chim. Acta, 394, 542 (2013); doi:10.1016/j.ica.2012.09.009.

C. Gao, X. Jin, X. Yan, P. An, Y. Zhang, L. Liu, H. Tian, W. Liu, X. Yao and Y. Tang, Sens. Actuators B, 176, 775 (2013); doi:10.1016/j.snb.2012.09.052.

C.-Y. Li, C.-X. Zou, Y.-F. Li, J.-L. Tang and C. Weng, Dyes Pigments, 104, 110 (2014); doi:10.1016/j.dyepig.2014.01.003.

X.-H. Yang, S. Li, Z.-S. Tang, X.-D. Yu, T. Huang and Y. Gao, Chin. Chem. Lett., 26, 129 (2015); doi:10.1016/j.cclet.2014.09.025.

Issue

Vol. 28 No. 2 (2016): Vol 28 Issue 2

Bismuth Ions Selective Fluorescent Chemosensor Based on Rhodamine-B

Corresponding Author(s) : Fuli Tian

Abstract

Keywords

Full Article

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