Evaluation of Ionic Liquid-Modified Mesoporous Silica Particles for Separation of Polysaccharides

H. Zhang; Y.R. Lee; K.H. Row

doi:10.14233/ajchem.2016.19314

Issue

Vol. 28 No. 1 (2016): Vol 28 Issue 1

Issue Published : October 5, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Evaluation of Ionic Liquid-Modified Mesoporous Silica Particles for Separation of Polysaccharides

https://doi.org/10.14233/ajchem.2016.19314

H. Zhang

Department of Chemistry and Chemical Engineering, Inha University, 253 Yonghyun-Dong, Nam-Ku, Incheon 402-751, Republic of Korea

Y.R. Lee

Department of Chemistry and Chemical Engineering, Inha University, 253 Yonghyun-Dong, Nam-Ku, Incheon 402-751, Republic of Korea

K.H. Row

Department of Chemistry and Chemical Engineering, Inha University, 253 Yonghyun-Dong, Nam-Ku, Incheon 402-751, Republic of Korea

Corresponding Author(s) : K.H. Row

rowkho@inha.ac.kr

Asian Journal of Chemistry, Vol. 28 No. 1 (2016): Vol 28 Issue 1
Article Published : October 6, 2015

Abstract

A group of ionic liquid-modified mesoporous silica particles was synthesized and characterized. A suitable sorbent with a suitable imidazole group and anion was selected according to its adsorption behaviour to the two polysaccharides on various synthesized particles. To confirm the conditions for the optimal adsorption capacity of the proposed sorbent, the standard/sorbent ratio, time and pH were investigated. The adsorption behaviour of these polysaccharides allowed the purification and separation of one compound from another and might find applications in extraction from natural plants in further studies.

Keywords

Ionic liquid Mesoporous silica particles Alginate Fucoidan HPLC

Zhang, H., Lee, Y., & Row, K. (2015). Evaluation of Ionic Liquid-Modified Mesoporous Silica Particles for Separation of Polysaccharides. Asian Journal of Chemistry, 28(1), 170–174. https://doi.org/10.14233/ajchem.2016.19314

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References

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References

V. García-Ríos, E. Ríos-Leal, D. Robledo and Y. Freile-Pelegrin, Phycol. Res, 60, 305 (2012); doi:10.1111/j.1440-1835.2012.00661.x.

A.B. Kay, Br. Med. Bull., 56, 843 (2000); doi:10.1258/0007142001903481.

M. Ueno, Y. Tamura, N. Toda, M. Yoshinaga, S. Terakado, K. Otsuka, A. Numabe, Y. Kawabata, I. Murota, N. Sato and Y. Uehara, Clin. Exp. Hypertens., 34, 305 (2012); doi:10.3109/10641963.2011.577484.

M. Fujihara, N. Iizima, I. Yamamoto and T. Nagumo, Carbohydr. Res., 125, 97 (1984); doi:10.1016/0008-6215(84)85145-9.

F. Gu, B. Amsden and R. Neufeld, J. Control. Rel., 96, 463 (2004); doi:10.1016/j.jconrel.2004.02.021.

A. Jimenez-Escrig and F.J. Sanchez-Muniz, Nutr. Res., 20, 585 (2000); doi:10.1016/S0271-5317(00)00149-4.

T. Eluvakkal, S.R. Sivakumar and K. Arunkumar, Int. J. Bot., 6, 176 (2010); doi:10.3923/ijb.2010.176.181.

B. Li, F. Lu, X. Wei and R. Zhao, Molecules, 13, 1671 (2008); doi:10.3390/molecules13081671.

L.-E. Rioux, S.L. Turgeon and M. Beaulieu, Carbohydr. Polym., 69, 530 (2007); doi:10.1016/j.carbpol.2007.01.009.

A.M. Liu, K. Hidajat, S. Kawi and D. Zhao, Chem. Commun., 13, 1145 (2000); doi:10.1039/b002661l.

Y.R. Ma, L.M. Qi, J.M. Ma, Y.Q. Wu, O. Liu and H.M. Cheng, Colloids Surf. A, 229, 1 (2003); doi:10.1016/j.colsurfa.2003.08.010.

Y. Han, S.S. Lee and J.Y. Ying, Chem. Mater., 19, 2292 (2007); doi:10.1021/cm063050x.

J.S. Lettow, Y.J. Han, P. Schmidt-Winkel, P. Yang, D. Zhao, G.D. Stucky and J.Y. Ying, Langmuir, 16, 8291 (2000); doi:10.1021/la000660h.

P. Schmidt-Winkel, W.W. Lukens, D. Zhao, P. Yang, B.F. Chmelka and G.D. Stucky, J. Am. Chem. Soc., 121, 254 (1999); doi:10.1021/ja983218i.

P. Schmidt-Winkel, W.W. Lukens, P. Yang, D.I. Margolese, J.S. Lettow, J.Y. Ying and G.D. Stucky, Chem. Mater., 12, 686 (2000); doi:10.1021/cm991097v.

A. Loaiza-Gil, P. Rodríguez, W. Velasquez, D. Gómez, B. Fontal, M. Reyes and T. Suárez, Rev. Latin Am. Met. Mater., 22, 47 (2002).

M. Tian, W. Bi and K.H. Row, J. Sep. Sci., 34, 3151 (2011); doi:10.1002/jssc.201100546.

W. Bi and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 33, 1459 (2010); doi:10.1080/10826076.2010.503805.

J.S. Wilkes, J.A. Levisky, R.A. Wilson and C.L. Hussey, Inorg. Chem., 21, 1263 (1982); doi:10.1021/ic00133a078.

P. Bonhote, A.-P. Dias, N. Papageorgiou, K. Kalyanasundaram and M. Grätzel, Inorg. Chem., 35, 1168 (1996); doi:10.1021/ic951325x.

T. Welton, Chem. Rev., 99, 2071 (1999); doi:10.1021/cr980032t.

J.D. Holbrey and K.R. Seddon, J. Chem. Soc., Dalton Trans., 2133 (1999); doi:10.1039/a902818h.

J.G. Huddleston, A.E. Visser, W.M. Reichert, H.D. Willauer, G.A. Broker and R.D. Rogers, Green Chem., 3, 156 (2001); doi:10.1039/b103275p.

Issue

Vol. 28 No. 1 (2016): Vol 28 Issue 1

Evaluation of Ionic Liquid-Modified Mesoporous Silica Particles for Separation of Polysaccharides

Corresponding Author(s) : K.H. Row

Abstract

Keywords

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