Kinetic Study of Interaction of ortho-Aminophenol with Fe(III) Schiff Base Complex in Aqueous Surfactant Medium

Pradyut Sarma

doi:10.14233/ajchem.2015.17826

Issue

Vol. 27 No. 1 (2015): Vol 27 Issue 1

Issue Published : December 27, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Kinetic Study of Interaction of ortho-Aminophenol with Fe(III) Schiff Base Complex in Aqueous Surfactant Medium

https://doi.org/10.14233/ajchem.2015.17826

Pradyut Sarma

Department of Chemistry, Arya Vidyapeeth College, Guwahati-781 016 India

Corresponding Author(s) : Pradyut Sarma

gu_123456@yahoo.com

Asian Journal of Chemistry, Vol. 27 No. 1 (2015): Vol 27 Issue 1
Article Published : December 29, 2014

Abstract

The interaction of phenolate substrate like ortho-aminophenol with [Fe(salen)]Cl has been studied in aqueous surfactant medium. The oxygenation reaction of o-aminophenol bound [Fe(salen)]⁺ adduct has found to be pseudo first order. The rate constant of the oxygenation reaction has characterized in cationic, anionic and neutral surfactant medium. These rate constant values are quite encouraging. Enzyme kinetics of the oxygenation reaction has been thoroughly examined. k_cat/K_m value of the reaction in different surfactant medium are ranges from 7.1 × 10³ to 7.9 × 10³ M^-1s^-1 and these values support the efficiency of the enzyme. Therefore the reaction has provided a better option as model of dioxygenase enzyme.

Keywords

ortho-Aminophenol Schiff base Surfactant Oxygenation reaction Enzyme kinetics

Sarma, P. (2014). Kinetic Study of Interaction of ortho-Aminophenol with Fe(III) Schiff Base Complex in Aqueous Surfactant Medium. Asian Journal of Chemistry, 27(1), 325–328. https://doi.org/10.14233/ajchem.2015.17826

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References

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References

G. Lin, G. Reid and T.H. Bugg, J. Am. Chem. Soc., 123, 5030 (2001); doi:10.1021/ja004280u.

L. Que Jr. and M. Reynolds, Met. Ions Biol. Syst., 37, 505 (2000).

M. Costas, M.P. Mehn, M.P. Jensen and L. Que, Chem. Rev., 104, 939 (2004); doi:10.1021/cr020628n.

M.M. Taqui Khan, N.H. Khan, R.I. Kureshy, A.B. Boricha and Z.A. Shaikh, Inorg. Chim. Acta, 170, 213 (1990); doi:10.1016/S0020-1693(00)80478-8.

5 L. Que, R.C. Kolanczyk and L.S. White, J. Am. Chem. Soc., 109, 5373 (1987); doi:10.1021/ja00252a012.

J.C. Moutet and A. Ourari, Electrochim. Acta, 42, 2525 (1997); doi:10.1016/S0013-4686(96)00443-4.

M. Higuchi, Y. Hitomi, H. Minami, T. Tanaka and T. Funabiki, Inorg. Chem., 44, 8810 (2005); doi:10.1021/ic051173y.

R. Mayilmurugan, E. Suresh and M. Palaniandavar, Inorg. Chem., 46, 6038 (2007); doi:10.1021/ic700646m.

L. Casella, M. Gullotti, A. Pintar, L. Messori, A. Rockenbauer and M. Gyor, Inorg. Chem., 26, 1031 (1987); doi:10.1021/ic00254a014.

M. Merkel, F.K. Müller and B. Krebs, Inorg. Chim. Acta, 337, 308 (2002); doi:10.1016/S0020-1693(02)01082-4.

M.J. Sever and J.J. Wilker, Dalton Trans., 1061 (2004); doi:10.1039/b315811j.

D.K. Das, C. Bhattaray and O.K. Medhi, J. Chem. Soc., Dalton Trans., 4713 (1997); doi:10.1039/a703701e.

T. Dhanalakshmi, M. Bhuvaneshwari and M. Palaniandavar, J. Inorg. Biochem., 100, 1527 (2006); doi:10.1016/j.jinorgbio.2006.05.004.

T. Kurahashi, K. Oda, M. Sugimoto, T. Ogura and H. Fujii, Inorg. Chem., 45, 7709 (2006); doi:10.1021/ic060650p.

P. Sarma and O. K. Medhi, J. Surface Sci. Technol., 27, 135 (2011).

M. Higuchi, Y. Hitomi, H. Minami, T. Tanaka and T. Funabiki, Inorg. Chem., 44, 8810 (2005); doi:10.1021/ic051173y.

D.A. Baldwin, H.M. Marques and J.M. Pratt, J. Inorg. Biochem., 27, 245 (1986); doi:10.1016/0162-0134(86)80065-4.

M. Velusamy, M. Palaniandavar, R.S. Gopalan and G.U. Kulkarni, Inorg. Chem., 42, 8283 (2003); doi:10.1021/ic020569w.

D.K. Das and O.K. Medhi, J. Chem. Soc., Dalton Trans., 1693 (1998); doi:10.1039/a708732b.

L. Que, R.C. Kolanczyk and L.S. White, J. Am. Chem. Soc., 109, 5373 (1987); doi:10.1021/ja00252a012.

P. Mialane, L. Tchertanov, F. Banse, J. Sainton and J.-J. Girerd, Inorg. Chem., 39, 2440 (2000); doi:10.1021/ic981236v.

P. Sarma and O.K. Medhi, Int. J. Chem. Res., 2, 135 (2011).

M. Pascaly, M. Duda, F. Schweppe, K. Zurlinden, F.K. Muller and B. Krebs, J. Chem. Soc., Dalton Trans., 828 (2001); doi:10.1039/B008511L.

R. Viswanathan, M. Palaniandavar, T. Balasubramanian and T.P. Muthiah, Inorg. Chem., 37, 2943 (1998); doi:10.1021/ic970708n.

Issue

Vol. 27 No. 1 (2015): Vol 27 Issue 1

Kinetic Study of Interaction of ortho-Aminophenol with Fe(III) Schiff Base Complex in Aqueous Surfactant Medium

Corresponding Author(s) : Pradyut Sarma

Abstract

Keywords

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