Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Eco-Friendly Chemical Routes for Transformation of Terpenoids in Green Solvents to Effective Additive Materials by using Ruthenium Complexes

https://doi.org/10.14233/ajchem.2015.18888
Abdullah Sulaiman Al-Ayed
Chemistry Department, College of Science and Arts, Qassim University, Al-Rass, P.O. Box 53, Buraidah 51477, Saudi Arabia Corresponding author: Fax: +966 63339351; Tel: +966 505 142736; E-mail: asaaied@qu.edu.sa

Corresponding Author(s) : Abdullah Sulaiman Al-Ayed

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10

Abstract

New terpenoids were prepared by ruthenium catalyzed cross-metathesis of terpenes (1a-c) with methyl acrylate (2) under environmental friendly conditions in glycerol. The new terpenoids compounds were fully characterized by FT-IR, 1H, 13C spectra and by HRMS analysis. Furthermore, the synthesis of some diazecin-3-ones is described via reaction of compound 4 with hydrazine hydrate or phenyl hydrazine in glycerol at reflux. The new compounds 5 were characterized by FT-IR, HRMS analysis and NMR spectral data.

Keywords

Terpenoids Ruthenium Cross-metathesis Diazecin-3-ones.
Sulaiman Al-Ayed, A. (2015). Eco-Friendly Chemical Routes for Transformation of Terpenoids in Green Solvents to Effective Additive Materials by using Ruthenium Complexes. Asian Journal of Chemistry, 27(10), 3619–3624. https://doi.org/10.14233/ajchem.2015.18888
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
Author biographies is not available.
Download
Statistic
Read Counter : 0