Triton-B Mediated Efficient Synthesis of Thioxoimidazolidine-4,5-diones

Ram Kishore1; M. Kamboj1; M. Shukla2; Devdutt Chaturvedi3

doi:10.14233/ajchem.2020.22252

Issue

Vol. 32 No. 1 (2020): Vol 32 Issue 1

Issue Published : 18 September 2019

Triton-B Mediated Efficient Synthesis of Thioxoimidazolidine-4,5-diones

https://doi.org/10.14233/ajchem.2020.22252

Ram Kishore1

1Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Uttar Pradesh, Lucknow Campus, Lucknow-226028, India 2Department of Chemistry, Babu Banarasi Das National Institute of Technology, Lucknow-227105, India 3Department of Chemistry, School of Physical Sciences, Mahatma Gandhi Central University, Motihari-845401, India *Corresponding author: E-mail: devduttchaturvedi@gmail.com

M. Kamboj1

M. Shukla2

Devdutt Chaturvedi3

Corresponding Author(s) : Ram Kishore1

Asian Journal of Chemistry, Vol. 32 No. 1 (2020): Vol 32 Issue 1
Article Published : 19 November 2019

Abstract

A simple, mild and efficient protocol for the synthesis of thioxoimidazolidine-4,5-diones (1-15) from substituted thiourea employing Triton-B/CS₂ system has been discussed. The protocol described is an easy, efficient, nature-friendly method using cheap, easily available, less toxic reagents at room temperature. The synthesis involves the reaction between substituted thiourea in toluene and oxalyl chloride at room temperature using phase transfer catalyst Triton-B/CS₂ system.

Keywords

Thioxoimidazolidine-4 5-diones Substituted thiourea Oxalyl chloride Toluene Triton-B Carbon disulfide.

(1)

Kishore1, R.; Kamboj1, M.; Shukla2, M.; Chaturvedi3, D. Triton-B Mediated Efficient Synthesis of Thioxoimidazolidine-4,5-Diones. ajc 2019, 32, 183-186.