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Vol. 28 No. 10 (2016): Vol 28 Issue 10

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Synthesis, Electronic Absorption, Fluorescence and Live Time Spectroscopic Study of Some New 3,7-Disubstituted Coumarin Derivatives as New Fluorescent Probes

https://doi.org/10.14233/ajchem.2016.19975
F.M.A. Altalbawy1
1Department of Measurements and Environmental Applications, National Institute of Laser Enhanced Sciences (NILES), Cairo University, P.O. Box 12613, Giza, Egypt 2Department of Chemistry, Faculty of Science, Cairo University, P.O.Box 12613, Giza, Egypt *Corresponding author: Fax: +2 3 5729499; Tel: +2 100 5627258; E-mail: f_altalbawy@yahoo.com
M.H. Abdelkader1
1Department of Measurements and Environmental Applications, National Institute of Laser Enhanced Sciences (NILES), Cairo University, P.O. Box 12613, Giza, Egypt 2Department of Chemistry, Faculty of Science, Cairo University, P.O.Box 12613, Giza, Egypt *Corresponding author: Fax: +2 3 5729499; Tel: +2 100 5627258; E-mail: f_altalbawy@yahoo.com
E.S.S. Darwish2
1Department of Measurements and Environmental Applications, National Institute of Laser Enhanced Sciences (NILES), Cairo University, P.O. Box 12613, Giza, Egypt 2Department of Chemistry, Faculty of Science, Cairo University, P.O.Box 12613, Giza, Egypt *Corresponding author: Fax: +2 3 5729499; Tel: +2 100 5627258; E-mail: f_altalbawy@yahoo.com
M.H. Elnagdi2
1Department of Measurements and Environmental Applications, National Institute of Laser Enhanced Sciences (NILES), Cairo University, P.O. Box 12613, Giza, Egypt 2Department of Chemistry, Faculty of Science, Cairo University, P.O.Box 12613, Giza, Egypt *Corresponding author: Fax: +2 3 5729499; Tel: +2 100 5627258; E-mail: f_altalbawy@yahoo.com

Asian Journal of Chemistry, Vol. 28 No. 10 (2016): Vol 28 Issue 10

Abstract

The synthesis of several novel 3-heterocyclic substituent-7-methoxycoumarin derivatives were carried out starting from 3-acetyl-7-hydroxy-2H-chromen-2-one (3), which reacted with DMF-DMA affords enaminone 4 which transformed into pyranone 8, pyridine derivative 12a,b, 23, 24, triaroylbenzene 22 and fuaranone 17 with treatment with hippuric acid (5), acetyl acetone (12a), ethyl acetoacetate (12b), acetic acid and ammonium acetate, 3-acetyl-7- hydroxy-2H-chromen-2-one (3), acetic acid and 1,4-naphthoquinone (15) respectively. The UV-visible, fluorescence and live time spectra for compounds were determined. Most of them displayed high fluorescence quantum yields ranging from 0.70 to 0.99 and life times in the nanosecond range, which can make these new 3-heterocyclic substituent-7-methoxycoumarin compounds very useful as new fluorescent probes.

Keywords

Fluorescence Lifetimes Coumarin Enaminone Pyridine Fuaranone.
Altalbawy1, F., Abdelkader1, M., Darwish2, E., & Elnagdi2, M. (2016). Synthesis, Electronic Absorption, Fluorescence and Live Time Spectroscopic Study of Some New 3,7-Disubstituted Coumarin Derivatives as New Fluorescent Probes. Asian Journal of Chemistry, 28(10), 2303–2310. https://doi.org/10.14233/ajchem.2016.19975
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