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Thermophysical Properties of Binary Mixtures of Cyclopentanone and Isomeric Forms of n-Butyl Alcohol at 303.15 K
Asian Journal of Chemistry,
Vol. 28 No. 10 (2016): Vol 28 Issue 10
Abstract
The density and speed of sound of binary mixtures of cyclopentanone and isomeric forms of n-butyl alcohols (butan-1-ol, butan-2-ol, 2-methylpropan-1-ol, 2-methylpropan-2-ol) were measured over the entire composition range at 303.15 K. From the experimental data, the various thermophysical properties such as excess molar volume (VE) and deviation in isentropic compressibility (Dks) were calculated and then fitted to Redlich-Kister polynomial equation. The results are discussed in terms of non-specific interactions present in the above mentioned binary mixtures.
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- B. Saini, A. Gupta, R. Sharma and R.K. Bamezai, Phys. Chem. Liq., 52, 262 (2014); doi:10.1080/00319104.2013.812020.
- B. Saini, B. Rani and R.K. Bamezai, Russ. J. Phys. Chem., 88, 47 (2014); doi:10.1134/S0036024414010270.
- B. Saini, R. Sharma, R.C. Thakur and R.K. Bamezai, Asian J. Chem., 28, 1599 (2016); doi:10.14233/ajchem.2016.19767.
- R.C. Thakur, R. Sharma, A. Kumar, S. Kumar and M.L. Parmar, Orient. J. Chem., 30, 2037 (2014); doi:10.13005/ojc/300469.
- R.C. Thakur, R. Sharma, M. Meenakshi and A. Kumar, Orient. J. Chem., 31, 363 (2015); doi:10.13005/ojc/310143.
- J.N. Nayak, M.I. Aralaguppi and T.M. Aminabhavi, J. Chem. Eng. Data, 48, 628 (2003); doi:10.1021/je0201828.
- B. Ranjith Kumar, P.M. Krishna, S.A. Banu, K.A. Jyothi, T. Savitha Jyostna and N. Satyanarayana, Phys. Chem. Liq., 48, 79 (2010); doi:10.1080/00319100802688030.
- B. Sinha, Phys. Chem. Liq., 48, 183 (2010); doi:10.1080/00319100802706691.
- K. Patwari, R.K. Bachu, S. Boodida and S. Nallani, J. Chem. Eng. Data, 54, 1069 (2009); doi:10.1021/je800653d.
- N.G. Tsierkezos and M.M. Palaiologou, Phys. Chem. Liq., 47, 447 (2009); doi:10.1080/00319100802104855.
- G.P. Dubey and M. Sharma, Phys. Chem. Liq., 46, 610 (2008); doi:10.1080/00319100701344602.
- Z. Begum, P.B. Sandhya Sri, D.B. Karuna Kumar and C. Rambabu, J. Mol. Liq., 178, 99 (2013); doi:10.1016/j.molliq.2012.11.016.
- A. Gupta and R.K. Bamezai, J. Indian Chem. Soc., 88, 521 (2011).
- W.L. Weng, J. Chem. Eng. Data, 44, 63 (1999); doi:10.1021/je980104d.
- O. Redlich and A.T. Kister, Ind. Eng. Chem., 40, 345 (1948); doi:10.1021/ie50458a036.
- G. Manukonda, V. Ponneri, S. Kasibhatta and S. Sakamuri, Korean J. Chem. Eng., 30, 1131 (2013); doi:10.1007/s11814-013-0014-y.
- M.V. Rathnam, R.T. Sayed, K.R. Bhanushali and M.S.S. Kumar, J. Mol. Liq., 166, 9 (2012); doi:10.1016/j.molliq.2011.10.020.
References
B. Saini, A. Gupta, R. Sharma and R.K. Bamezai, Phys. Chem. Liq., 52, 262 (2014); doi:10.1080/00319104.2013.812020.
B. Saini, B. Rani and R.K. Bamezai, Russ. J. Phys. Chem., 88, 47 (2014); doi:10.1134/S0036024414010270.
B. Saini, R. Sharma, R.C. Thakur and R.K. Bamezai, Asian J. Chem., 28, 1599 (2016); doi:10.14233/ajchem.2016.19767.
R.C. Thakur, R. Sharma, A. Kumar, S. Kumar and M.L. Parmar, Orient. J. Chem., 30, 2037 (2014); doi:10.13005/ojc/300469.
R.C. Thakur, R. Sharma, M. Meenakshi and A. Kumar, Orient. J. Chem., 31, 363 (2015); doi:10.13005/ojc/310143.
J.N. Nayak, M.I. Aralaguppi and T.M. Aminabhavi, J. Chem. Eng. Data, 48, 628 (2003); doi:10.1021/je0201828.
B. Ranjith Kumar, P.M. Krishna, S.A. Banu, K.A. Jyothi, T. Savitha Jyostna and N. Satyanarayana, Phys. Chem. Liq., 48, 79 (2010); doi:10.1080/00319100802688030.
B. Sinha, Phys. Chem. Liq., 48, 183 (2010); doi:10.1080/00319100802706691.
K. Patwari, R.K. Bachu, S. Boodida and S. Nallani, J. Chem. Eng. Data, 54, 1069 (2009); doi:10.1021/je800653d.
N.G. Tsierkezos and M.M. Palaiologou, Phys. Chem. Liq., 47, 447 (2009); doi:10.1080/00319100802104855.
G.P. Dubey and M. Sharma, Phys. Chem. Liq., 46, 610 (2008); doi:10.1080/00319100701344602.
Z. Begum, P.B. Sandhya Sri, D.B. Karuna Kumar and C. Rambabu, J. Mol. Liq., 178, 99 (2013); doi:10.1016/j.molliq.2012.11.016.
A. Gupta and R.K. Bamezai, J. Indian Chem. Soc., 88, 521 (2011).
W.L. Weng, J. Chem. Eng. Data, 44, 63 (1999); doi:10.1021/je980104d.
O. Redlich and A.T. Kister, Ind. Eng. Chem., 40, 345 (1948); doi:10.1021/ie50458a036.
G. Manukonda, V. Ponneri, S. Kasibhatta and S. Sakamuri, Korean J. Chem. Eng., 30, 1131 (2013); doi:10.1007/s11814-013-0014-y.
M.V. Rathnam, R.T. Sayed, K.R. Bhanushali and M.S.S. Kumar, J. Mol. Liq., 166, 9 (2012); doi:10.1016/j.molliq.2011.10.020.