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Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

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Synthesis, Characterization of Zirconia and Molybdenum Doped on Silica: Study their Catalytic Activity for Oxidation of Sulphides

https://doi.org/10.14233/ajchem.2023.27586
Amal A. Muftah
Faculty of Education, Bani Walid University, Bani Walid, Libya
Ramejabi Sayyad
Department of Chemistry, Yashwantrao Mohite College of Arts Science and Commerce, Bharati Vidyapeeth (Deemed To Be University), Pune-411030, India
Shobha Waghmode
Department of Chemistry, MES Abasaheb Garware College, (Affiliated to Savitribai Phule Pune University, Pune), Pune-411004, India
Supriya Shukla
Department of Chemistry, Yashwantrao Mohite College of Arts Science and Commerce, Bharati Vidyapeeth (Deemed To Be University), Pune-411030, India
Sharda Gadale
Department of Chemistry, Yashwantrao Mohite College of Arts Science and Commerce, Bharati Vidyapeeth (Deemed To Be University), Pune-411030, India

Corresponding Author(s) : Sharda Gadale

dagade@rediffmail.com

Asian Journal of Chemistry, Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

Abstract

To explore the structural, green methodology and thermal stability for synthesizing series of ternary mixed metal oxides were prepared by doping ZrO2 and MoO3 on SiO2 (ZMS) by sol-gel method. Catalysts were examined by XRD, FT-IR, XPS, Raman spectroscopy, temperature programmed desorption (TPD) and TEM techniques. Both oxides showed the high stability with nanocrystalline nature and the catalytic activity of synthesized ZMS catalyst were tested for oxidation of sulfides to sulfoxides at room temperature. Gas chromatography was used to analyze the products. A high selectivity obtained by nicely controlled a variation of catalyst amount as well as amounts of oxidant applied. Recycling experiments explained that the synthesized ZMS catalysts can be recycled many times without major loss of their activity. The catalytic system provided a number of advantages including clean, use of green solvent and easy handling strategy for the synthesis of sulfoxides at mild conditions.

Keywords

Ternary mixed oxide Catalytic activity Sol gel method Zirconia Molybdenum oxide Oxidation Sulfides Sulfoxides
Muftah, A. A., Sayyad, R., Waghmode, S., Shukla, S., & Gadale, S. (2023). Synthesis, Characterization of Zirconia and Molybdenum Doped on Silica: Study their Catalytic Activity for Oxidation of Sulphides. Asian Journal of Chemistry, 35(4), 999–1008. https://doi.org/10.14233/ajchem.2023.27586
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