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Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

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Green Synthesis and Characterization of Nickel Oxide Nanoparticle for Rhodamine-B Adsorption using Phyllanthus emblica Fruit Extract

https://doi.org/10.14233/ajchem.2023.27715
P.S. Geetha Malini
Department of Chemistry, Quaid-E-Millath Government College for Women, Chennai-600002, India Department of Chemistry, Sri Chandrasekharendra Saraswathi Viswa Mahavidyalaya, Enathur, Kanchipuram-631561, India
https://orcid.org/0000-0001-8768-334X
S. Rani
PG & Research Department of Chemistry, Arignar Anna Government Arts College, Cheyyar-604407, India
https://orcid.org/0000-0003-0074-8441
J. Manonmani
Department of Chemistry, Quaid-E-Millath Government College for Women, Chennai-600002, India
https://orcid.org/0000-0002-0469-1510
R. Jayaprakash
Department of Chemistry, School of Arts and Science, AV Campus, Vinayaka Mission’s Research Foundation (Deemed to be University), Chennai-603104, India
https://orcid.org/0000-0002-4323-4910

Corresponding Author(s) : S. Rani

raniselvaraj1970@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

Abstract

In this work, the nanoadsorbent efficiency of nickel oxide nanoparticles (NiONPs) for the degradation of rhodamine B (RhA-B) dye was examined. The NiONPs were synthesized by green technique using NiCl2·H2O and Phyllanthus emblica fruit extract. The NiO nanoparticles were characterized using UV, FTIR, FESEM, HRTEM and TGA/DTA analysis to study the decomposition pattern, functional groups, crystalline size and elemental composition of nanoparticles. TEM analysis showed that the nanoparticles were spherical, highly crystalline, highly agglomerated and appeared as clusters of nanoparticles in the size range converted into tubular shape. The prepaed NiONPs were used for batch experiments to evaluate the adsorption capacities of the dye. The influence of various key parameters, i.e. adsorbent dosage and initial dye concentration were investigated. The extent of adsorption of RhA-B was found to be 88% at pH 6. Langmuir isotherm showed maximum monolayer adsorption with qm values from 328-465 mg/L. The kinetic investigation of RhA-B degradation followed a pseudo-second-order rate kinetics with a rate constant of 2.0495 × 10-2 mg-1 min-1. ΔGº = − 79.00 kJ/mol indicates that the adsorption is chemisorption and spontaneous.

Keywords

NiO Phyllanthus emblica Nanoparticles Rhodamine B dye Adsorption
Malini, P. G., Rani, S., Manonmani, J., & Jayaprakash, R. (2023). Green Synthesis and Characterization of Nickel Oxide Nanoparticle for Rhodamine-B Adsorption using Phyllanthus emblica Fruit Extract. Asian Journal of Chemistry, 35(4), 961–968. https://doi.org/10.14233/ajchem.2023.27715
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