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Vol. 28 No. 10 (2016): Vol 28 Issue 10

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Adsorption of Aqueous Mercury by Amide-Functionalized Ordered Mesoporous Carbon

https://doi.org/10.14233/ajchem.2016.19961
Jianzhong Zhu1
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P.R. China 2Department of Civil and Environmental Engineering, University of Missouri, Columbia, MO 65211, USA 3Center of Environmental Sciences, Lincoln University of Missouri, Jefferson City, MO 65102, USA *Corresponding author: E-mail: zhuhhai2010@hhu.edu.cn
Dongliang Ji1
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P.R. China 2Department of Civil and Environmental Engineering, University of Missouri, Columbia, MO 65211, USA 3Center of Environmental Sciences, Lincoln University of Missouri, Jefferson City, MO 65102, USA *Corresponding author: E-mail: zhuhhai2010@hhu.edu.cn
Baolin Deng2
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P.R. China 2Department of Civil and Environmental Engineering, University of Missouri, Columbia, MO 65211, USA 3Center of Environmental Sciences, Lincoln University of Missouri, Jefferson City, MO 65102, USA *Corresponding author: E-mail: zhuhhai2010@hhu.edu.cn
John Yang3
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P.R. China 2Department of Civil and Environmental Engineering, University of Missouri, Columbia, MO 65211, USA 3Center of Environmental Sciences, Lincoln University of Missouri, Jefferson City, MO 65102, USA *Corresponding author: E-mail: zhuhhai2010@hhu.edu.cn
Ying Ding1
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P.R. China 2Department of Civil and Environmental Engineering, University of Missouri, Columbia, MO 65211, USA 3Center of Environmental Sciences, Lincoln University of Missouri, Jefferson City, MO 65102, USA *Corresponding author: E-mail: zhuhhai2010@hhu.edu.cn
Ya Su1
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P.R. China 2Department of Civil and Environmental Engineering, University of Missouri, Columbia, MO 65211, USA 3Center of Environmental Sciences, Lincoln University of Missouri, Jefferson City, MO 65102, USA *Corresponding author: E-mail: zhuhhai2010@hhu.edu.cn

Asian Journal of Chemistry, Vol. 28 No. 10 (2016): Vol 28 Issue 10

Abstract

Amide-functionalized ordered mesoporous carbon was developed for removal of mercury (Hg2+) from aqueous phase. Ordered mesoporous carbon was synthesized using a mesoporous silica template, SBA-15, followed by in situ polymerization of acrylic acid, carbonization and template removal. Ordered mesoporous carbon was subsequently functionalized with ethylenediamine through a combined treatment of nitric acid and thionyl chloride. Physio-chemical properties of the carbons were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Fourier transform IR spectroscopy, potentiometry and N2-adsorption/desorption (BET). Adsorption kinetics and equilibrium of Hg was assessed in batch experimental systems. Results indicated that amide-functionalized carbon (FOMC) maintained the original ordered mesoporous structure and hexagonal framework with an averaged surface area of 607 m2 g-1, pore size of 4.1 nm and pore volume of 0.62 cm3 g-1. The functionalization process immobilized significant amounts of amide group on the carbon surface and enhanced surface negative charges and hydrophilicity. The adsorption of mercury(II) by functionalized ordered mesoporous carbon reached equilibrium within 480 min. The adsorption capacity was 1.5-time as large as for ordered mesoporous carbon, suggesting an enhanced affinity of surface amide groups for aqueous Hg binding. The adsorption also occurred in a wider pH range (about 5.0-7.0 vs. 5.5-6.5). The Freundlich adsorption model fitted the isotherms reasonably well. A surface complexation double layer model was developed to describe the Hg2+ adsorption, from which related H+ and Hg2+ binding constants on the surface were obtained.

Keywords

Ordered mesoporous carbon Surface modification Mercury adsorption Surface complexation model.
Zhu1, J., Ji1, D., Deng2, B., Yang3, J., Ding1, Y., & Su1, Y. (2016). Adsorption of Aqueous Mercury by Amide-Functionalized Ordered Mesoporous Carbon. Asian Journal of Chemistry, 28(10), 2246–2254. https://doi.org/10.14233/ajchem.2016.19961
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