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Corrosion Inhibition Potential of Cymbopogon citratus (Lemongrass) Leaves Extract on Mild Steel in 0.1 M Sulphuric Acid Medium at Different Temperatures
Corresponding Author(s) : Gita Rani
Asian Journal of Chemistry,
Vol. 35 No. 8 (2023): Vol 35 Issue 8, 2023
Abstract
The role of the phytochemicals in Cymbopogon citratus (Lemongrass) plant is significant in preventing the corrosion. The current study investigated the effectiveness of lemongrass leaves extract (at concentrations ranging from 1-6%) in inhibiting the corrosion of mild steel (low carbon) in a corrosive medium of 0.1 M sulphuric acid. The extract was used as a green rust inhibitor at different temperatures (25, 35 and 45 ºC). Electrochemical impedance spectroscopy (EIS) and linear polarization studies were conducted to analyze the electrochemical behaviour and understand the corrosion inhibition mechanism. Additionally, weight loss studies were carried out. At 6% concentration and 25 ºC, lemongrass extract showed 92.01% corrosion inhibition efficiency. The surface analysis of mild steel samples was performed using both metallurgical research micrographs (MRM) and SEM techniques. Based on the results, the study concludes that the lemongrass leaves extract is an excellent green corrosion inhibitor.
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- B. Dong, W. Liu, L. Chen, T. Zhang, Y. Fan, Y. Zhao, S. Li, W. Yang and W. Banthukul, Cement Concr. Compos., 125, 104317 (2022); https://doi.org/10.1016/j.cemconcomp.2021.104317
- R. Ganjoo, S. Sharma, A. Thakur, H. Assad, P. Kumar Sharma, O. Dagdag, A. Berisha, M. Seydou, E.E. Ebenso and A. Kumar, J. Mol. Liq., 364, 119988 (2022); https://doi.org/10.1016/j.molliq.2022.119988
- H. Kumar and T. Dhanda, Chem. Data Coll., 33, 100721 (2021); https://doi.org/10.1016/j.cdc.2021.100721
- A.M. Guruprasad and H.P. Sachin, Chem. Data Coll., 34, 100734 (2021); https://doi.org/10.1016/j.cdc.2021.100734
- H.S.H. Munawaroh, Y. Sunarya, B. Anwar, E. Priatna, H. Risa, A.K. Koyande and P.L. Show, Sustainability, 14, 3622 (2022); https://doi.org/10.3390/su14063622
- S. Kumar, V. Kalia, M. Goyal, G. Jhaa, S. Kumar, H. Vashisht, H. Dahiya, M.A. Quraishi and C. Verma, J. Mol. Liq., 357, 119077 (2022); https://doi.org/10.1016/j.molliq.2022.119077
- R.A. Anaee, A.A. Abdulkarim, M.T. Mathew and H.M. Jedy, J. Bio Tribocorros., 7, 1 (2021); https://doi.org/10.1007/s40735-020-00440-0
- T. Chen, Z. Chen, M. Chen and C. Fu, J. Mol. Liq., 338, 116638 (2021); https://doi.org/10.1016/j.molliq.2021.116638
- B.R. Fazal, T. Becker, B. Kinsella and K. Lepkova, NPJ Mater. Degrad., 6, 5 (2022); https://doi.org/10.1038/s41529-021-00201-5
- A. Zakeri, E. Bahmani and A.S.R. Aghdam, Corros. Commun., 5, 25 (2022); https://doi.org/10.1016/j.corcom.2022.03.002
- N. Hossain, M.A. Chowdhury and M. Kchaou, J. Adhes. Sci. Technol., 35, 673 (2021); https://doi.org/10.1080/01694243.2020.1816793
- D.S. Chauhan, M.A. Quraishi and A. Qurashi, J. Mol. Liq., 326, 115117 (2021); https://doi.org/10.1016/j.molliq.2020.115117
- A. Singh, Y. Lin, E.E. Ebenso, W. Liu, J. Pan and B. Huang, J. Ind. Eng. Chem., 24, 219 (2015); https://doi.org/10.1016/j.jiec.2014.09.034
- B. Nematian, S.A. Ahmad Ramazani, M. Mahdavian, G. Bahlakeh and S.A. Haddadi, Colloids Surf. A Physicochem. Eng. Asp., 601, 125042 (2020); https://doi.org/10.1016/j.colsurfa.2020.125042
- N. Rajamohan, F.S. Zahir Said Al Shibli, M. Rajasimman and Y. Vasseghian, Chemosphere, 291, 132756 (2022); https://doi.org/10.1016/j.chemosphere.2021.132756
- F. Kaya, R. Solmaz and I. Halil Geçibesler, J. Ind. Eng. Chem., 122, 102 (2023); https://doi.org/10.1016/j.jiec.2023.02.013
- A. Chakravarty, I. Ahmad, P. Singh, M. Ud Din Sheikh, G. Aalam, S. Sagadevan and S. Ikram, Chem. Phys. Lett., 795, 139493 (2022); https://doi.org/10.1016/j.cplett.2022.139493
- M. Wifek, A. Saeed, R. Rehman and S. Nisar, Int. J. Chem. Biochem. Sci., 9, 79 (2016). https://www.researchgate.net/publication/336134806
- Z.A.A. Naqqash and H.K. Al-Bazaz, Res. J. Pharm. Technol., 12, 67 (2019); https://doi.org/10.5958/0974-360X.2019.00013.1.
- T.R. Arruda, P.C. Bernardes, A.R.F. Moraes and N.D.F.F. Soares, Food Res. Int., 111160 (2022); https://doi.org/10.1016/j.foodres.2022.111160
- J. Sharifi-Rad, A. Sureda, G.C. Tenore, M. Daglia, M. Sharifi-Rad, M. Valussi, R. Tundis, M. Sharifi-Rad, M. Loizzo, A. Ademiluyi, R. Sharifi-Rad, S. Ayatollahi and M. Iriti, Molecules, 22, 70 (2017); https://doi.org/10.3390/molecules22010070
- N. Zhen, X. Wang, X. Li, J. Xue, Y. Zhao, M. Wu, D. Zhou, J. Liu, J. Guo and H. Zhang, Microb. Biotechnol., 15, 1324 (2022); https://doi.org/10.1111/1751-7915.13918.
- S.A. Umoren, M.M. Solomon, I.B. Obot and R.K. Suleiman, J. Ind. Eng. Chem., 76, 91 (2019); https://doi.org/10.1016/j.jiec.2019.03.057
- A. Bala and G. Rani, Microsc. Res. Techn., (2023); https://doi.org/10.1002/jemt.24310
- A. Bala, G. Rani and R. Ahlawat, Spectrosc. Lett., 55, 618 (2022); https://doi.org/10.1080/00387010.2022.2137200
- T. Niaz, S. Shabbir, T. Noor, R. Abbasi and M. Imran, Int. J. Biol. Macromol., 156, 1366 (2020); https://doi.org/10.1016/j.ijbiomac.2019.11.177
- E. Machnikova, K.H. Whitmire and N. Hackerman, Electrochim. Acta, 53, 6024 (2008); https://doi.org/10.1016/j.electacta.2008.03.021
- K. Raviprabha and R.S. Bhat, Egypt. J. Petrol., 32, 1 (2023); https://doi.org/10.1016/j.ejpe.2023.03.002
References
B. Dong, W. Liu, L. Chen, T. Zhang, Y. Fan, Y. Zhao, S. Li, W. Yang and W. Banthukul, Cement Concr. Compos., 125, 104317 (2022); https://doi.org/10.1016/j.cemconcomp.2021.104317
R. Ganjoo, S. Sharma, A. Thakur, H. Assad, P. Kumar Sharma, O. Dagdag, A. Berisha, M. Seydou, E.E. Ebenso and A. Kumar, J. Mol. Liq., 364, 119988 (2022); https://doi.org/10.1016/j.molliq.2022.119988
H. Kumar and T. Dhanda, Chem. Data Coll., 33, 100721 (2021); https://doi.org/10.1016/j.cdc.2021.100721
A.M. Guruprasad and H.P. Sachin, Chem. Data Coll., 34, 100734 (2021); https://doi.org/10.1016/j.cdc.2021.100734
H.S.H. Munawaroh, Y. Sunarya, B. Anwar, E. Priatna, H. Risa, A.K. Koyande and P.L. Show, Sustainability, 14, 3622 (2022); https://doi.org/10.3390/su14063622
S. Kumar, V. Kalia, M. Goyal, G. Jhaa, S. Kumar, H. Vashisht, H. Dahiya, M.A. Quraishi and C. Verma, J. Mol. Liq., 357, 119077 (2022); https://doi.org/10.1016/j.molliq.2022.119077
R.A. Anaee, A.A. Abdulkarim, M.T. Mathew and H.M. Jedy, J. Bio Tribocorros., 7, 1 (2021); https://doi.org/10.1007/s40735-020-00440-0
T. Chen, Z. Chen, M. Chen and C. Fu, J. Mol. Liq., 338, 116638 (2021); https://doi.org/10.1016/j.molliq.2021.116638
B.R. Fazal, T. Becker, B. Kinsella and K. Lepkova, NPJ Mater. Degrad., 6, 5 (2022); https://doi.org/10.1038/s41529-021-00201-5
A. Zakeri, E. Bahmani and A.S.R. Aghdam, Corros. Commun., 5, 25 (2022); https://doi.org/10.1016/j.corcom.2022.03.002
N. Hossain, M.A. Chowdhury and M. Kchaou, J. Adhes. Sci. Technol., 35, 673 (2021); https://doi.org/10.1080/01694243.2020.1816793
D.S. Chauhan, M.A. Quraishi and A. Qurashi, J. Mol. Liq., 326, 115117 (2021); https://doi.org/10.1016/j.molliq.2020.115117
A. Singh, Y. Lin, E.E. Ebenso, W. Liu, J. Pan and B. Huang, J. Ind. Eng. Chem., 24, 219 (2015); https://doi.org/10.1016/j.jiec.2014.09.034
B. Nematian, S.A. Ahmad Ramazani, M. Mahdavian, G. Bahlakeh and S.A. Haddadi, Colloids Surf. A Physicochem. Eng. Asp., 601, 125042 (2020); https://doi.org/10.1016/j.colsurfa.2020.125042
N. Rajamohan, F.S. Zahir Said Al Shibli, M. Rajasimman and Y. Vasseghian, Chemosphere, 291, 132756 (2022); https://doi.org/10.1016/j.chemosphere.2021.132756
F. Kaya, R. Solmaz and I. Halil Geçibesler, J. Ind. Eng. Chem., 122, 102 (2023); https://doi.org/10.1016/j.jiec.2023.02.013
A. Chakravarty, I. Ahmad, P. Singh, M. Ud Din Sheikh, G. Aalam, S. Sagadevan and S. Ikram, Chem. Phys. Lett., 795, 139493 (2022); https://doi.org/10.1016/j.cplett.2022.139493
M. Wifek, A. Saeed, R. Rehman and S. Nisar, Int. J. Chem. Biochem. Sci., 9, 79 (2016). https://www.researchgate.net/publication/336134806
Z.A.A. Naqqash and H.K. Al-Bazaz, Res. J. Pharm. Technol., 12, 67 (2019); https://doi.org/10.5958/0974-360X.2019.00013.1.
T.R. Arruda, P.C. Bernardes, A.R.F. Moraes and N.D.F.F. Soares, Food Res. Int., 111160 (2022); https://doi.org/10.1016/j.foodres.2022.111160
J. Sharifi-Rad, A. Sureda, G.C. Tenore, M. Daglia, M. Sharifi-Rad, M. Valussi, R. Tundis, M. Sharifi-Rad, M. Loizzo, A. Ademiluyi, R. Sharifi-Rad, S. Ayatollahi and M. Iriti, Molecules, 22, 70 (2017); https://doi.org/10.3390/molecules22010070
N. Zhen, X. Wang, X. Li, J. Xue, Y. Zhao, M. Wu, D. Zhou, J. Liu, J. Guo and H. Zhang, Microb. Biotechnol., 15, 1324 (2022); https://doi.org/10.1111/1751-7915.13918.
S.A. Umoren, M.M. Solomon, I.B. Obot and R.K. Suleiman, J. Ind. Eng. Chem., 76, 91 (2019); https://doi.org/10.1016/j.jiec.2019.03.057
A. Bala and G. Rani, Microsc. Res. Techn., (2023); https://doi.org/10.1002/jemt.24310
A. Bala, G. Rani and R. Ahlawat, Spectrosc. Lett., 55, 618 (2022); https://doi.org/10.1080/00387010.2022.2137200
T. Niaz, S. Shabbir, T. Noor, R. Abbasi and M. Imran, Int. J. Biol. Macromol., 156, 1366 (2020); https://doi.org/10.1016/j.ijbiomac.2019.11.177
E. Machnikova, K.H. Whitmire and N. Hackerman, Electrochim. Acta, 53, 6024 (2008); https://doi.org/10.1016/j.electacta.2008.03.021
K. Raviprabha and R.S. Bhat, Egypt. J. Petrol., 32, 1 (2023); https://doi.org/10.1016/j.ejpe.2023.03.002