Issue

Vol. 35 No. 7 (2023): Vol 35 Issue 7 (2023)

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Alkali Metal Complexes of an Octamethyl Isomeric Macrocycle: Synthesis, Characterization and Antimicrobial Studies

https://doi.org/10.14233/ajchem.2023.27923
Avijit Chakraborty
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
https://orcid.org/0000-0002-7860-8273
Saswata Rabi
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh Department of Chemistry, Faculty of Engineering & Technology, Chittagong University of Engineering and Technology, Chattogram 4349, Bangladesh
https://orcid.org/0000-0001-5911-1184
Snehashis Roy
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
https://orcid.org/0009-0009-9897-3188
Debashis Palit
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
https://orcid.org/0000-0002-4253-0232
Zinnat Ara Begum
Institute of Environmental Radioactivity, Fukushima University, 1 Kanayagawa, Fukushima City, Fukushima 960-1296, Japan Department of Civil Engineering, Southern University Bangladesh, Arefin Nagar, Bayezid Bostami, Chattogram 4210, Bangladesh
https://orcid.org/0000-0003-3408-9616
Ismail M.M. Rahman
Institute of Environmental Radioactivity, Fukushima University, 1 Kanayagawa, Fukushima City, Fukushima 960-1296, Japan
https://orcid.org/0000-0001-8084-5190
Tapashi Ghosh Roy
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
https://orcid.org/0000-0002-2192-1584

Corresponding Author(s) : Tapashi Ghosh Roy

tapashir57@cu.ac.bd

Asian Journal of Chemistry, Vol. 35 No. 7 (2023): Vol 35 Issue 7 (2023)

Abstract

Fourteen membered octamethyl tetraazamacrocyclic ligand salt, Me8[14]diene·2HClO4 and three isomeric ligands (LA, LB and LC) of its saturated analog have been synthesized as per literature. Interaction between the isomeric ligand LB and KX (X = SCN, NO3, Cl, Br and I) afforded white-coloured five coordinated square pyramidal potassium complexes [KLBX]. Moreover, the reaction between RbCl and LB produced five coordinated [RbLBCl] having square pyramidal geometry. Then, the axial substitution reaction on [RbLBCl] furnished a substituted rubidium complex with the same geometry of the mother complex. All the alkali metal complexes have been characterized by using modern analytical techniques. Furthermore, antibacterial and antifungal activities of ligand LB and its alkali metal (K and Rb) complexes have been investigated against different bacteria and fungi.

Keywords

Alkali metals Tetraazamacrocyclic complexes Isomeric ligands Biological activities
Chakraborty, A., Rabi, S., Roy, S., Palit, D., Begum, Z. A., Rahman, I. M., & Roy, T. G. (2023). Alkali Metal Complexes of an Octamethyl Isomeric Macrocycle: Synthesis, Characterization and Antimicrobial Studies. Asian Journal of Chemistry, 35(7), 1697–1701. https://doi.org/10.14233/ajchem.2023.27923
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. I.M. Kolthoff, Anal. Chem., 51, 1 (1979); https://doi.org/10.1021/ac50041a001
  2. B.D. Nath, K. Takaishi and T. Ema, Catal. Sci. Technol., 10, 12 (2020); https://doi.org/10.1039/C9CY01894H
  3. J.A. Manskaya, K.V. Domasevitch, V.V. Ponomareva, J. Sieler and V.N. Kokozay, Z. Naturforsch. B. J. Chem. Sci., 53, 683 (1998); https://doi.org/10.1515/znb-1998-0706
  4. D.P. Singh, K. Kumar, S.S. Dhiman and J. Sharma, J. Enzyme Inhib. Med. Chem., 25, 21 (2010); https://doi.org/10.3109/14756360902932750
  5. Y. Liang, R. Fang and Q. Rao, Molecules, 27, 2837 (2022); https://doi.org/10.3390/molecules27092837
  6. P.M. de Carvalho, H. Weich and W.-R. Abraham, Curr. Med. Chem., 23, 23 (2015); https://doi.org/10.2174/0929867323666151117121521
  7. P.V. Bernhardt and P.C. Sharpe, Inorg. Chem., 39, 4123 (2000); https://doi.org/10.1021/ic000315f
  8. D. Asik, R. Smolinski, S.M. Abozeid, T.B. Mitchell, S.G. Turowski, J.A. Spernyak and J.R. Morrow, Molecules, 25, 2291 (2020); https://doi.org/10.3390/molecules25102291
  9. J. Dyke, W. Levason, M.E. Light, D. Pugh, H. Bhakhoa, P. Ramasami, G. Reid and L. Rhyman, Dalton Trans., 44, 13853 (2015); https://doi.org/10.1039/C5DT01865J
  10. M. Everett, A. Jolleys, W. Levason, D. Pugh and G. Reid, Chem. Commun., 50, 5843 (2014); https://doi.org/10.1039/c4cc01407c
  11. A.P. Marchand, K.A. Kumar, A.S. McKim, K. Mlinarié-Majerski and G. Kragol, Tetrahedron, 53, 3467 (1997); https://doi.org/10.1016/S0040-4020(97)00075-6
  12. M.N.S. Hill, J.C. Lockhart and D.P. Mousley, J. Chem. Soc., Dalton Trans., 1455 (1996); https://doi.org/10.1039/dt9960001455
  13. L. Dey, S. Rabi, Z.A. Begum, T. Takase, I.M.M. Rahman, E.R.T. Tiekink and T.G. Roy, Z. Krist.- New Cryst. Str., 236, 1147 (2021); https://doi.org/10.1515/ncrs-2021-0254
  14. R. Bembi, S. M. Sondhi, A. K. Singh, A. K. Jhanji, T. G. Roy, J.W. Lown and R.G. Ball, Bull. Chem. Soc. Jpn., 62, 3701 (1989); https://doi.org/10.1246/bcsj.62.3701
  15. L. Dey, S. Rabi, D. Palit, S.K.S. Hazari, Z.A. Begum, I.M.M. Rahman and T.G. Roy, J. Mol. Struct., 1240, 130579 (2021); https://doi.org/10.1016/j.molstruc.2021.130579
  16. M.E. Farago and J.M. James, Inorg. Chem., 4, 1706 (1965); https://doi.org/10.1021/ic50034a007
  17. A. Sabatini and I. Bertini, Inorg. Chem., 4, 959 (1965); https://doi.org/10.1021/ic50029a007
  18. N.F. Curtis and Y.M. Curtis, Inorg. Chem., 4, 804 (1965); https://doi.org/10.1021/ic50028a007
  19. S. Anga, I. Banerjee, H.P. Nayek and T.K. Panda, RSC Adv., 6, 80916 (2016); https://doi.org/10.1039/C6RA13437H
  20. W.J. Geary, Coord. Chem. Rev., 7, 81 (1971); https://doi.org/10.1016/S0010-8545(00)80009-0
  21. F.B. Biswas, T.G. Roy, M.A. Rahman and T.B. Emran, Asian Pac. J. Trop. Med., 7, S534 (2014); https://doi.org/10.1016/S1995-7645(14)60286-8
Read More
Author biographies is not available.
Download
AJC-35-7-21
Statistic
Read Counter : 1 Download : 1