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Synthesis and Crystal Structure of Nickel(II) Complex of Hydrazone Derived from Benzohydrazide and 4-Acetylpyridine and Tetramethylethylenediamine as Secondary Ligand
Asian Journal of Chemistry,
Vol. 28 No. 10 (2016): Vol 28 Issue 10
Abstract
A new nickel(II) complex of formula [Ni(L)2(tmed)] (1) (LH = 4-acetylpyridine benzoyl hydrazone, tmed = tetramethylethylenediamine) has been synthesized and characterized by single crystal X-ray diffraction method. The compound crystallizes in monoclinic space group P21/c with a = 10.4479 (6), b = 18.8907 (10), c = 16.5022 (9) Å, α = 90, β = 94.527(3), γ = 90° V = 3246.8 (3) Å3, Z = 4, F(000) = 1376.0, Dc = 1.333 Mg/m3, μ = 0.642 mm-1. Nickel(II) ion exhibited distorted octahedral geometry. The hydrazone acted as anionic ligand.
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- M.A.A. Radwan, E.A. Ragab, N.M. Sabry and S.M. El-Shenawy, Bioorg. Med. Chem., 15, 3832 (2007); doi:10.1016/j.bmc.2007.03.024.
- S.K. Sridhar, S.N. Pandeya, J.P. Stables and A. Ramesh, Eur. J. Pharm. Sci., 16, 129 (2002); doi:10.1016/S0928-0987(02)00077-5.
- D. Kaushik, S.A. Khan, G. Chawla and S. Kumar, Eur. J. Med. Chem., 45, 3943 (2010); doi:10.1016/j.ejmech.2010.05.049.
- A. Deeb, F. El-Mariah and M. Hosny, Bioorg. Med. Chem. Lett., 14, 5013 (2004); doi:10.1016/j.bmcl.2004.06.102.
- D. Kumar, N. Maruthi Kumar, S. Ghosh and K. Shah, Bioorg. Med. Chem. Lett., 22, 212 (2012); doi:10.1016/j.bmcl.2011.11.031.
- O.I. El-sabbagh, M.A. Shabaan, H.H. Kadry and E.S. Al-Din, Eur. J. Med. Chem., 45, 5390 (2010); doi:10.1016/j.ejmech.2010.08.064.
- J.C. Jeffery, P. Thornton and M.D. Ward, Inorg. Chem., 33, 3612 (1994); doi:10.1021/ic00094a029.
- L. Latheef, E.B. Seena and M.R. Prathapachandra Kurup, Inorg. Chim. Acta, 362, 2515 (2009); doi:10.1016/j.ica.2008.10.012.
- A.A.R. Despaigne, L.F. Vieira, I.C. Mendes, F.B. Costa, N.L. Speziali and H. Beraldo, J. Braz. Chem. Soc., 21, 1247 (2010); doi:10.1590/S0103-50532010000700012.
- G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
References
M.A.A. Radwan, E.A. Ragab, N.M. Sabry and S.M. El-Shenawy, Bioorg. Med. Chem., 15, 3832 (2007); doi:10.1016/j.bmc.2007.03.024.
S.K. Sridhar, S.N. Pandeya, J.P. Stables and A. Ramesh, Eur. J. Pharm. Sci., 16, 129 (2002); doi:10.1016/S0928-0987(02)00077-5.
D. Kaushik, S.A. Khan, G. Chawla and S. Kumar, Eur. J. Med. Chem., 45, 3943 (2010); doi:10.1016/j.ejmech.2010.05.049.
A. Deeb, F. El-Mariah and M. Hosny, Bioorg. Med. Chem. Lett., 14, 5013 (2004); doi:10.1016/j.bmcl.2004.06.102.
D. Kumar, N. Maruthi Kumar, S. Ghosh and K. Shah, Bioorg. Med. Chem. Lett., 22, 212 (2012); doi:10.1016/j.bmcl.2011.11.031.
O.I. El-sabbagh, M.A. Shabaan, H.H. Kadry and E.S. Al-Din, Eur. J. Med. Chem., 45, 5390 (2010); doi:10.1016/j.ejmech.2010.08.064.
J.C. Jeffery, P. Thornton and M.D. Ward, Inorg. Chem., 33, 3612 (1994); doi:10.1021/ic00094a029.
L. Latheef, E.B. Seena and M.R. Prathapachandra Kurup, Inorg. Chim. Acta, 362, 2515 (2009); doi:10.1016/j.ica.2008.10.012.
A.A.R. Despaigne, L.F. Vieira, I.C. Mendes, F.B. Costa, N.L. Speziali and H. Beraldo, J. Braz. Chem. Soc., 21, 1247 (2010); doi:10.1590/S0103-50532010000700012.
G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.