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Silica-Sulfuric Acid: Novel, Simple, Efficient and Reusable Catalyst for Hydration of Nitrile to Amide

https://doi.org/10.14233/ajchem.2016.19907
eep Ch
1Institute for Stem Cell Biology and Regenerative Medicine, NCBS, TIFR, GKVK, Bellary Road, Bangalore-560 065, India 2Department of Biotechnology and Food Technology, Durban University of Technology, Durban 4001, South Africa 3Department of Public Health Medicine, University of KwaZulu-Natal, Howard College Campus, Durban 4001, South Africa *Corresponding author: E-mail: katharigattav@dut.ac.za; venugopalakn@gmail.com
Katharigatta N. Venugopala2
1Institute for Stem Cell Biology and Regenerative Medicine, NCBS, TIFR, GKVK, Bellary Road, Bangalore-560 065, India 2Department of Biotechnology and Food Technology, Durban University of Technology, Durban 4001, South Africa 3Department of Public Health Medicine, University of KwaZulu-Natal, Howard College Campus, Durban 4001, South Africa *Corresponding author: E-mail: katharigattav@dut.ac.za; venugopalakn@gmail.com
Rashmi Venugopala3
1Institute for Stem Cell Biology and Regenerative Medicine, NCBS, TIFR, GKVK, Bellary Road, Bangalore-560 065, India 2Department of Biotechnology and Food Technology, Durban University of Technology, Durban 4001, South Africa 3Department of Public Health Medicine, University of KwaZulu-Natal, Howard College Campus, Durban 4001, South Africa *Corresponding author: E-mail: katharigattav@dut.ac.za; venugopalakn@gmail.com
Bharti Odhav2
1Institute for Stem Cell Biology and Regenerative Medicine, NCBS, TIFR, GKVK, Bellary Road, Bangalore-560 065, India 2Department of Biotechnology and Food Technology, Durban University of Technology, Durban 4001, South Africa 3Department of Public Health Medicine, University of KwaZulu-Natal, Howard College Campus, Durban 4001, South Africa *Corresponding author: E-mail: katharigattav@dut.ac.za; venugopalakn@gmail.com

Asian Journal of Chemistry, Vol. 28 No. 10 (2016): Vol 28 Issue 10

Abstract

Silica-sulfuric acid efficiently catalyzes conversion of aliphatic, substituted aromatic and hetero aromatic nitriles to their corresponding amides in good to excellent yields under reflux condition. Products obtained were purified by column chromatography method and characterized by 1H NMR, 13C NMR and mass spectral analysis.

Keywords

Silica-sulfuric acid Nitriles Amides Hydration.
Ch, eep, N. Venugopala2, K., Venugopala3, R., & Odhav2, B. (2016). Silica-Sulfuric Acid: Novel, Simple, Efficient and Reusable Catalyst for Hydration of Nitrile to Amide. Asian Journal of Chemistry, 28(10), 2177–2180. https://doi.org/10.14233/ajchem.2016.19907
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