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Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Copyright (c) 2023 ANKIT SHARMA, Deepa Meena, Kiran Parashar, Deepti Goyal, Sakshi Kabra Malpani, Ashu Rani

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Extraction of Silica from Different Solid Wastes and Its Application as Catalyst Support for Vapour Phase Oxidation of Aromatic Hydrocarbon

https://doi.org/10.14233/ajchem.2023.28170
ANKIT SHARMA
UNIVERSITY OF KOTA,RAJASTHAN
https://orcid.org/0000-0002-6156-2379
Deepa Meena
UNIVERSITY OF KOTA,RAJASTHAN
https://orcid.org/0009-0003-6174-4214
Kiran Parashar
UNIVERSITY OF KOTA,RAJASTHAN
https://orcid.org/0009-0008-3635-2653
Deepti Goyal
Department of Applied Chemistry, University School of Vocational Studies & Applied Sciences, Gautam Buddha University, Greater Noida, UP, India
https://orcid.org/0000-0002-5377-9340
Sakshi Kabra Malpani
Save the WaterTM, 8723 NW 11 Street, Plantation, FL 33322, USA
https://orcid.org/0000-0002-6835-0504
Ashu Rani
UNIVERSITY OF KOTA,RAJASTHAN
https://orcid.org/0000-0002-2894-6098

Corresponding Author(s) : ANKIT SHARMA

ankit@uok.ac.in

Asian Journal of Chemistry, Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Abstract

In present study, the research work has been divided into two sections viz. Firstly, amorphous silica was extracted from different silica rich agricultural and industrial waste materials (fly ash, perlite and rice husk ash) via sol-gel method. The extracted silica (RHA-Si, Perlite-Si, FA-Si) was characterized using BET surface area, FESEM, EDS, XRD, NMR and FTIR techniques. The surface area and particle size of extracted silica was found to be 23.06-255.5 m2/g and 61-267 nm. Secondly, fly ash silica was used as catalyst support and modified desirably by loading different molybdenum weight percentages via acid impregnation method. The presence of MoO3 on the surface of extracted silica were confirmed by different characterization techniques. The kinetic studies of the FASi/Mo-15 catalyst for the vapour phase oxidation of benzene was also investigated by employing the Mars Van Krevelen model to analyze the reaction mechanism and rate of the process. The vapour phase oxidation reaction follows zero order kinetics, with faster benzene conversion occurring at lower intake concentrations and higher reaction temperatures.

Keywords

Fly ash Fly ash Rice husk ash Rice husk ash Perlite Perlite Extracted silica Extracted silica vapor phase vapor phase kinetics kinetics
SHARMA, A., Meena, D., Parashar, K., Goyal, D., Kabra Malpani, S., & Rani, A. (2023). Extraction of Silica from Different Solid Wastes and Its Application as Catalyst Support for Vapour Phase Oxidation of Aromatic Hydrocarbon. Asian Journal of Chemistry, 35(10), 2451–2460. https://doi.org/10.14233/ajchem.2023.28170
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