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Vol. 35 No. 6 (2023): Vol 35 Issue 6, 2023

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Effects of Axial Ligands on the Redox Properties of Manganese(III) meso-tetrakis(p-Hydroxyphenyl) Porphyrin

https://doi.org/10.14233/ajchem.2023.27796
V. Thandiayyakone
Research and Development Centre, Bharathiar University, Coimbatore-641046, India
https://orcid.org/0000-0002-5402-8741
A. Murugan
Department of Chemistry, North Eastern Regional Institute of Science & Technology, Nirjuli, Itanagar-791109, India
https://orcid.org/0000-0002-8342-2553
C.R. Ravikumar
Department of Chemistry, East West Institute of Technology, Bangalore-560091, India
https://orcid.org/0000-0002-4692-444X
T. Rajkumar
Department of Chemistry, Rajah Serfoji Government College (Affiliated to Bharathidasan University), Thanjavur-613005, India
https://orcid.org/0000-0002-5815-3769
A. Kulandaisamy
Department of Chemistry, Government Arts and Science College, Sivakasi-626124, India
https://orcid.org/0000-0001-9386-8754
Ijaz Ullah Muzaddadi
Department of Chemistry, North Eastern Regional Institute of Science & Technology, Nirjuli, Itanagar-791109, India
https://orcid.org/0000-0001-9522-8507
A. Manohar
Department of Chemistry, Periyar Maniammai Institute of Science and Technology, Periyar Nagar, Vallam, Thanjavur-613403, India
https://orcid.org/0000-0003-4618-3220
P. Thillai Arasu
Department of Chemistry, College of Natural and Computational Science, Wollega University, Wollega, Ethiopia
https://orcid.org/0000-0001-5975-8658
Mithun Chakrabarty
Department of Chemistry, St. Anthony’s College, Shillong-793001, India
https://orcid.org/0000-0003-4150-1664

Corresponding Author(s) : A. Murugan

nspmmurugan@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 6 (2023): Vol 35 Issue 6, 2023

Abstract

In this work, meso-tetrakis(p-Hydroxyphenyl) porphyrin [T(p-OH)PP] and manganese(III) meso-tetrakis(p-hydroxyphenyl) porphyrin Mn[T(p-OH)PP] were synthesized and characterized. The UV-visible and cyclic voltammetry were used to evaluate the axial ligand and redox behaviour of Mn[T(p-OH)PP]. The addition of ethylamine, diethylamine and tertiary amines to Mn(III) meso-porphyrins distinguishes their axial ligand characteristics. The presence of ethylamine causes the octahedral geometry to transform into a square pyramidal structure. Cyclic voltammetry shows that Mn(III) converts to Mn(II) porphyrins. Additionally, the UV-visible spectrophotometry and cyclic voltammetry were also used to investigate the oxidation process.

Keywords

Manganese meso-Porphyrin Axial effect Electrochemical properties
Thandiayyakone, V., Murugan, A., Ravikumar, C., Rajkumar, T., Kulandaisamy, A., Muzaddadi, I. U., … Chakrabarty, M. (2023). Effects of Axial Ligands on the Redox Properties of Manganese(III) meso-tetrakis(p-Hydroxyphenyl) Porphyrin. Asian Journal of Chemistry, 35(6), 1341–1346. https://doi.org/10.14233/ajchem.2023.27796
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