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Paper Industry Waste Sludge: A Low-Cost Adsorbent for Removal of Malachite green Dye
Asian Journal of Chemistry,
Vol. 28 No. 10 (2016): Vol 28 Issue 10
Abstract
In the present work, paper industry waste sludge has been used as a low-cost adsorbent for the investigation of adsorption isotherms, kinetics and thermodynamic parameters of Malachite green dye adsorption from aqueous solution. Three kinetic models, pseudo-first-order, pseudo-second-order and intra-particle-diffusion model have been used to predict the adsorption rate constants. The kinetics of adsorption has been best described by pseudo-second-order model and is supported by intra-particle-diffusion model. The equilibrium adsorption capacity has been determined by subjecting the experimental data to Langmuir, Freundlich and Temkin isotherms. The thermodynamic parameters such as; change in free energy, enthalpy and entropy have been calculated.
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- Z.N. Garba, Z.U. Zango, A.A. Babando and G. Galadima, J. Chem. Pharm. Res., 7, 710 (2015).
- M. Santhi, P.E. Kumar and B. Murlidharan, J. Appl. Chem., 8, 33 (2015).
- S.A. Ahmed, A.A.A. Gaber and A.M.A. Rahim, Int. J. Adv. Res., 3, 621 (2015).
- E.S. Dragan and I.A. Dinu, Res. J. Chem. Environ., 12, 5 (2008).
- N. Nordin and S.F.M. Amir, Int. J. Electrochem. Soc., 8, 11403 (2013).
- J. Wu, M. Eiteman and S. Law, J. Environ. Eng., 124, 272 (1998); doi:10.1061/(ASCE)0733-9372(1998)124:3(272).
- M.K. Asl and F. Bahramin, Bull. Georg. Natl. Acad. Sci., 8, 260 (2014).
- P. Pandit and S. Basu, Ind. Eng. Chem. Res., 43, 7861 (2004); doi:10.1021/ie0402160.
- R. Katwal, H. Kaur, G. Sharma, M. Naushad and D. Pathania, J. Ind. Eng. Chem., 31, 173 (2015); doi:10.1016/j.jiec.2015.06.021.
- H. Kaur and A. Thakur, Chem. Sci. Rev. Lett., 3, 159 (2014).
- T.A. Khan, V.V. Singh and D. Kumar, J. Sci. Ind. Res. (India), 63, 355 (2004).
- H. Kaur and R. Kaur, J. Mater. Environ. Sci., 5, 1830 (2014).
- H.A. Al-Aoh, I.A.M. Mihaina, F.M. Alzuaibr, A.D. Althaqafy, M.J. Maah, R. Yahya, M.R.B. Abas, I. Tyagi, S. Agarwal and V.K. Gupta, Asian J. Chem., 28, 714 (2016); doi:10.14233/ajchem.2016.19373.
- J. Zhang, Y. Li, C. Zhang and Y. Jing, J. Hazard. Mater., 150, 774 (2008); doi:10.1016/j.jhazmat.2007.05.036.
- M. Makeswari and T. Santhi, J. Water Resource Prot., 5, 222 (2013); doi:10.4236/jwarp.2013.52023.
- Z.M. Abou-Gamra and M.A. Ahmed, Adv. Chem. Eng. Sci., 5, 373 (2015); doi:10.4236/aces.2015.53039.
- S.K. Ponnusamy and R. Subramaniam, Int. J. Ind. Chem, 4, 17 (2013); doi:10.1186/2228-5547-4-17.
- C.H. Supriya, J. Pharm. Res., 4, 307 (2015).
- H. Kaur, Swati and R. Kaur, Chem. Sci. Trans., 3, 1300 (2014); doi:10.7598/cst2014.922.
- H. Freundlich and W. Heller, J. Am. Chem. Soc., 61, 2228 (1939); doi:10.1021/ja01877a071.
- I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
- M.J. Temkin and V. Pyzhev, Acta Physiochim. U.R.S.S., 12, 217 (1940).
- S. Lagergren, Handlingar, 24, 01 (1898).
- Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999); doi:10.1016/S0032-9592(98)00112-5.
- W.H. Weber and J.C. Morris, J. Sanit. Eng. Div., 89, 31 (1963).
References
Z.N. Garba, Z.U. Zango, A.A. Babando and G. Galadima, J. Chem. Pharm. Res., 7, 710 (2015).
M. Santhi, P.E. Kumar and B. Murlidharan, J. Appl. Chem., 8, 33 (2015).
S.A. Ahmed, A.A.A. Gaber and A.M.A. Rahim, Int. J. Adv. Res., 3, 621 (2015).
E.S. Dragan and I.A. Dinu, Res. J. Chem. Environ., 12, 5 (2008).
N. Nordin and S.F.M. Amir, Int. J. Electrochem. Soc., 8, 11403 (2013).
J. Wu, M. Eiteman and S. Law, J. Environ. Eng., 124, 272 (1998); doi:10.1061/(ASCE)0733-9372(1998)124:3(272).
M.K. Asl and F. Bahramin, Bull. Georg. Natl. Acad. Sci., 8, 260 (2014).
P. Pandit and S. Basu, Ind. Eng. Chem. Res., 43, 7861 (2004); doi:10.1021/ie0402160.
R. Katwal, H. Kaur, G. Sharma, M. Naushad and D. Pathania, J. Ind. Eng. Chem., 31, 173 (2015); doi:10.1016/j.jiec.2015.06.021.
H. Kaur and A. Thakur, Chem. Sci. Rev. Lett., 3, 159 (2014).
T.A. Khan, V.V. Singh and D. Kumar, J. Sci. Ind. Res. (India), 63, 355 (2004).
H. Kaur and R. Kaur, J. Mater. Environ. Sci., 5, 1830 (2014).
H.A. Al-Aoh, I.A.M. Mihaina, F.M. Alzuaibr, A.D. Althaqafy, M.J. Maah, R. Yahya, M.R.B. Abas, I. Tyagi, S. Agarwal and V.K. Gupta, Asian J. Chem., 28, 714 (2016); doi:10.14233/ajchem.2016.19373.
J. Zhang, Y. Li, C. Zhang and Y. Jing, J. Hazard. Mater., 150, 774 (2008); doi:10.1016/j.jhazmat.2007.05.036.
M. Makeswari and T. Santhi, J. Water Resource Prot., 5, 222 (2013); doi:10.4236/jwarp.2013.52023.
Z.M. Abou-Gamra and M.A. Ahmed, Adv. Chem. Eng. Sci., 5, 373 (2015); doi:10.4236/aces.2015.53039.
S.K. Ponnusamy and R. Subramaniam, Int. J. Ind. Chem, 4, 17 (2013); doi:10.1186/2228-5547-4-17.
C.H. Supriya, J. Pharm. Res., 4, 307 (2015).
H. Kaur, Swati and R. Kaur, Chem. Sci. Trans., 3, 1300 (2014); doi:10.7598/cst2014.922.
H. Freundlich and W. Heller, J. Am. Chem. Soc., 61, 2228 (1939); doi:10.1021/ja01877a071.
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
M.J. Temkin and V. Pyzhev, Acta Physiochim. U.R.S.S., 12, 217 (1940).
S. Lagergren, Handlingar, 24, 01 (1898).
Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999); doi:10.1016/S0032-9592(98)00112-5.
W.H. Weber and J.C. Morris, J. Sanit. Eng. Div., 89, 31 (1963).