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Synthesis and Crystal Structures of Two Inorganic Compounds
Corresponding Author(s) : Yi Zhu
Asian Journal of Chemistry,
Vol. 27 No. 9 (2015): Vol 27 Issue 9
Abstract
Two novel compounds [Zn(H2O)6K2(SO4)2] and [Ni(H2O)6K2(SO4)2] were synthesized and characterized by single-crystal X-ray. The two crystals are isostructure with monoclinic, space group P21/c. The oxygen atoms of sulfate in two compounds not only chelate four metal ions but also are all involved in hydrogen bonding as the acceptor, while the coordination water molecules also act as hydrogen donors to form intermolecular hydrogen bonds.
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- M.J. Hannon and L.J. Childs, Supramol. Chem., 16, 7 (2004); doi:10.1080/10610270310001632386.
- M. Greenwald, D. Wessely, E. Katz, I. Willner and Y.J. Cohen, J. Org. Chem., 65, 1050 (2000); doi:10.1021/jo991469j.
- M. Greenwald, D. Wessely, I. Goldberg and Y. Cohen, New J. Chem., 23, 337 (1999); doi:10.1039/a808673g.
- C. Dietrich-Buchecker and J.-P. Sauvage, Chem. Commun., 615 (1999); doi:10.1039/a809885i.
- J.H. Bi, F.X. Xie, X.D. Zhao, Q. Chen and J.D. Xu, Asian J. Chem., 16, 137 (2004).
- J.H. Bi, J.M. Song, Z.X. Huang, Y.H. Wang and L.T. Kong, Asian J. Chem., 18, 2365 (2006).
- N.L. Hu, H.Z. Dong, Z.X. Huang and F.X. Xie, Asian J. Chem., 17, 1276 (2005).
- Siemens, SAINT Version 4 Software Reference Manual (Siemens Analytical X-ray Systems, Inc.), Madison: WI (1996).
- Siemens, SAINT Version 5 Reference Manual (Siemens Analytical X-ray Systems, Inc.), Madison: WI (1996).
References
M.J. Hannon and L.J. Childs, Supramol. Chem., 16, 7 (2004); doi:10.1080/10610270310001632386.
M. Greenwald, D. Wessely, E. Katz, I. Willner and Y.J. Cohen, J. Org. Chem., 65, 1050 (2000); doi:10.1021/jo991469j.
M. Greenwald, D. Wessely, I. Goldberg and Y. Cohen, New J. Chem., 23, 337 (1999); doi:10.1039/a808673g.
C. Dietrich-Buchecker and J.-P. Sauvage, Chem. Commun., 615 (1999); doi:10.1039/a809885i.
J.H. Bi, F.X. Xie, X.D. Zhao, Q. Chen and J.D. Xu, Asian J. Chem., 16, 137 (2004).
J.H. Bi, J.M. Song, Z.X. Huang, Y.H. Wang and L.T. Kong, Asian J. Chem., 18, 2365 (2006).
N.L. Hu, H.Z. Dong, Z.X. Huang and F.X. Xie, Asian J. Chem., 17, 1276 (2005).
Siemens, SAINT Version 4 Software Reference Manual (Siemens Analytical X-ray Systems, Inc.), Madison: WI (1996).
Siemens, SAINT Version 5 Reference Manual (Siemens Analytical X-ray Systems, Inc.), Madison: WI (1996).