Synthesis and Characterization of Mononuclear Nickel Complexes with Dithiolate Ligands

Wei Gao; Bo Shi

doi:10.14233/ajchem.2015.18386

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Issue Published : May 26, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Mononuclear Nickel Complexes with Dithiolate Ligands

https://doi.org/10.14233/ajchem.2015.18386

Wei Gao

School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China

Bo Shi

School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China

Corresponding Author(s) : Wei Gao

weigao415@aliyun.com

Asian Journal of Chemistry, Vol. 27 No. 9 (2015): Vol 27 Issue 9
Article Published : May 26, 2015

Abstract

Treatment of the mononuclear nickel complex (dppf)NiCl₂ (1) [dppf = 1,1'-bis(diphenylphosphino)ferrocene] with HSCH₂CH₂SH or HSCHMeCHMeSH in the presence of Et₃N in CH₂Cl₂ afforded the corresponding nickel dithiolate complexes (dppf)Ni(SCH₂CH₂S) (2) and (dppf)Ni(SCHMeCHMeS) (3) in 44 and 59 % yields, respectively. The new complexes 2 and 3 were structurally characterized by ¹H NMR, ³¹P{¹H} NMR and ¹³C{¹H} NMR spectroscopy.

Keywords

Nickel complex Ethanedithiolate Synthesis dppf

Gao, W., & Shi, B. (2015). Synthesis and Characterization of Mononuclear Nickel Complexes with Dithiolate Ligands. Asian Journal of Chemistry, 27(9), 3513–3514. https://doi.org/10.14233/ajchem.2015.18386

Download Citation

References

(a) H.G. Cui, N.N. Wu, J.Y. Wang, M.Q. Hu, H.M. Wen and C.N. Chen, J. Organomet. Chem., 767, 46 (2014); doi:10.1016/j.jorganchem.2014.04.026; (b) C.A. Mebi, D.S. Karr and B.C. Noll, Polyhedron, 50, 164 (2013); doi:10.1016/j.poly.2012.11.001; (c) P.H. Zhao, Y.Q. Liu and X.A. Li, Asian J. Chem., 25, 5428 (2013); doi:10.14233/ajchem.2013.14537; (d) X.F. Liu, Inorg. Chim. Acta, 378, 338 (2011); doi:10.1016/j.ica.2011.09.012; (e) X.F. Liu, J. Organomet. Chem., 750, 117 (2014); doi:10.1016/j.jorganchem.2013.11.020.
(a) E.S. Donovan, G.S. Nichol and G.A.N. Felton, J. Organomet. Chem., 726, 9 (2013); doi:10.1016/j.jorganchem.2012.12.006; (b) Y.L. Li, B. Xie, L.K. Zou, X.L. Zhang and X. Lin, J. Organomet. Chem., 718, 74 (2012); doi:10.1016/j.jorganchem.2012.07.038; (c) W. Gao, J. Yuan and J. Yang, Asian J. Chem., 25, 9755 (2013); doi:10.14233/ajchem.2013.15310A; (d) X.F. Liu and H.Q. Gao, Polyhedron, 65, 1 (2013); doi:10.1016/j.poly.2013.08.023; (e) P.H. Zhao, X.H. Li, Y.F. Liu and Y.Q. Liu, J. Coord. Chem., 67, 766 (2014); doi:10.1080/00958972.2014.903329; (f) X.F. Liu, X.Y. Yu and H.Q. Gao, Mol. Cryst. Liq. Cryst., 592, 229 (2014); doi:10.1080/15421406.2013.858024.
(a) S. Ghosh, G. Hogarth, N. Hollingsworth, K.B. Holt, S.E. Kabir and B.E. Sanchez, Chem. Commun., 50, 945 (2013); doi:10.1039/c3cc46456c; (b) X.F. Liu, Polyhedron, 72, 66 (2014); doi:10.1016/j.poly.2014.01.034; (c) M. El-khateeb, M. Harb, Q. Abu-Salem, H. Görls and W. Weigand, Polyhedron, 61, 1 (2013); doi:10.1016/j.poly.2013.04.060; (d) P.H. Zhao, M. Zhang and G.Z. Zhao, Asian J. Chem., 25, 5068 (2013); doi:10.14233/ajchem.2013.14513; (e) X.F. Liu and B.S. Yin, J. Coord. Chem., 63, 4061 (2010); doi:10.1080/00958972.2010.531715.
(a) S. Ghosh, G. Hogarth, N. Hollingsworth, K.B. Holt, I. Richards, M.G. Richmond, B.E. Sanchez and D. Unwin, Dalton Trans., 42, 6775 (2013); doi:10.1039/c3dt50147g; (b) L.J. Luo, X.F. Liu and H.Q. Gao, J. Coord. Chem., 66, 1077 (2013); doi:10.1080/00958972.2013.775431; (c) P.H. Zhao, Y.Q. Liu and G.Z. Zhao, Polyhedron, 53, 144 (2013); doi:10.1016/j.poly.2013.01.048; (d) C.G. Li, Y.F. Li, J.Y. Shang and T.J. Lou, Transition Met. Chem., 39, 373 (2014); doi:10.1007/s11243-014-9810-4; (e) X.F. Liu, M.Y. Chen and H.Q. Gao, J. Coord. Chem., 67, 57 (2014); doi:10.1080/00958972.2013.879123; (f) W. Gao, J.Y. Zhang and J. Yang, Asian J. Chem., 26, 2089 (2014); doi:10.14233/ajchem.2014.16183B.
(a) N. Wang, M. Wang, L. Chen and L.C. Sun, Dalton Trans., 42, 12059 (2013); doi:10.1039/c3dt51371h; (b) P.H. Zhao, W.T. Wang, Y.F. Liu and Y.Q. Liu, Transition Met. Chem., 39, 501 (2014); doi:10.1007/s11243-014-9825-x; (c) X.F. Liu and H.Q. Gao, J. Cluster Sci., 25, 367 (2014); doi:10.1007/s10876-013-0615-y; (d) X.F. Liu and H.Q. Gao, J. Cluster Sci., 25, 495 (2014); doi:10.1007/s10876-013-0627-7; (e) W. Gao, L.Q. Tian and J. Yang, Asian J. Chem., 26, 2086 (2014); doi:10.14233/ajchem.2014.16183A.
(a) T.H. Yen, K.T. Chu, W.W. Chiu, Y.C. Chien, G.H. Lee and M.H. Chiang, Polyhedron, 64, 247 (2013); doi:10.1016/j.poly.2013.05.019; (b) X.F. Liu and X.W. Xiao, J. Organomet. Chem., 696, 2767 (2011); doi:10.1016/j.jorganchem.2011.05.007; (c) X.F. Liu, Z.Q. Jiang and Z.J. Jia, Polyhedron, 33, 166 (2012); doi:10.1016/j.poly.2011.11.032; (d) C.G. Li, Y. Zhu, X.X. Jiao and X.Q. Fu, Polyhedron, 67, 416 (2014); doi:10.1016/j.poly.2013.09.027; (e) Y.L. Li, B. Xie, L.K. Zou, X. Lin, Y. Yang, S.S. Zhu and T. Wang, Polyhedron, 67, 490 (2014); doi:10.1016/j.poly.2013.09.041; (f) P.H. Zhao, Y.F. Liu, K.K. Xiong and Y.Q. Liu, J. Clust. Sci., 25, 1061 (2014); doi:10.1007/s10876-014-0689-1; (g) P.H. Zhao, S.N. Liu, Y.F. Liu and Y.Q. Liu, J. Clust. Sci., 25, 1331 (2014); doi:10.1007/s10876-014-0711-7; (h) W. Gao, F.P. Guo and J. Yang, Asian J. Chem., 26, 2083 (2014); doi:10.14233/ajchem.2014.16183.
X.F. Liu, Inorg. Chim. Acta, 421, 10 (2014); doi:10.1016/j.ica.2014.05.022.
W. Gao, K. Li and X.L. Wang, Asian J. Chem., 25, 7876 (2013); doi:10.14233/ajchem.2013.14667.

References

(a) H.G. Cui, N.N. Wu, J.Y. Wang, M.Q. Hu, H.M. Wen and C.N. Chen, J. Organomet. Chem., 767, 46 (2014); doi:10.1016/j.jorganchem.2014.04.026; (b) C.A. Mebi, D.S. Karr and B.C. Noll, Polyhedron, 50, 164 (2013); doi:10.1016/j.poly.2012.11.001; (c) P.H. Zhao, Y.Q. Liu and X.A. Li, Asian J. Chem., 25, 5428 (2013); doi:10.14233/ajchem.2013.14537; (d) X.F. Liu, Inorg. Chim. Acta, 378, 338 (2011); doi:10.1016/j.ica.2011.09.012; (e) X.F. Liu, J. Organomet. Chem., 750, 117 (2014); doi:10.1016/j.jorganchem.2013.11.020.

(a) E.S. Donovan, G.S. Nichol and G.A.N. Felton, J. Organomet. Chem., 726, 9 (2013); doi:10.1016/j.jorganchem.2012.12.006; (b) Y.L. Li, B. Xie, L.K. Zou, X.L. Zhang and X. Lin, J. Organomet. Chem., 718, 74 (2012); doi:10.1016/j.jorganchem.2012.07.038; (c) W. Gao, J. Yuan and J. Yang, Asian J. Chem., 25, 9755 (2013); doi:10.14233/ajchem.2013.15310A; (d) X.F. Liu and H.Q. Gao, Polyhedron, 65, 1 (2013); doi:10.1016/j.poly.2013.08.023; (e) P.H. Zhao, X.H. Li, Y.F. Liu and Y.Q. Liu, J. Coord. Chem., 67, 766 (2014); doi:10.1080/00958972.2014.903329; (f) X.F. Liu, X.Y. Yu and H.Q. Gao, Mol. Cryst. Liq. Cryst., 592, 229 (2014); doi:10.1080/15421406.2013.858024.

(a) S. Ghosh, G. Hogarth, N. Hollingsworth, K.B. Holt, S.E. Kabir and B.E. Sanchez, Chem. Commun., 50, 945 (2013); doi:10.1039/c3cc46456c; (b) X.F. Liu, Polyhedron, 72, 66 (2014); doi:10.1016/j.poly.2014.01.034; (c) M. El-khateeb, M. Harb, Q. Abu-Salem, H. Görls and W. Weigand, Polyhedron, 61, 1 (2013); doi:10.1016/j.poly.2013.04.060; (d) P.H. Zhao, M. Zhang and G.Z. Zhao, Asian J. Chem., 25, 5068 (2013); doi:10.14233/ajchem.2013.14513; (e) X.F. Liu and B.S. Yin, J. Coord. Chem., 63, 4061 (2010); doi:10.1080/00958972.2010.531715.

(a) S. Ghosh, G. Hogarth, N. Hollingsworth, K.B. Holt, I. Richards, M.G. Richmond, B.E. Sanchez and D. Unwin, Dalton Trans., 42, 6775 (2013); doi:10.1039/c3dt50147g; (b) L.J. Luo, X.F. Liu and H.Q. Gao, J. Coord. Chem., 66, 1077 (2013); doi:10.1080/00958972.2013.775431; (c) P.H. Zhao, Y.Q. Liu and G.Z. Zhao, Polyhedron, 53, 144 (2013); doi:10.1016/j.poly.2013.01.048; (d) C.G. Li, Y.F. Li, J.Y. Shang and T.J. Lou, Transition Met. Chem., 39, 373 (2014); doi:10.1007/s11243-014-9810-4; (e) X.F. Liu, M.Y. Chen and H.Q. Gao, J. Coord. Chem., 67, 57 (2014); doi:10.1080/00958972.2013.879123; (f) W. Gao, J.Y. Zhang and J. Yang, Asian J. Chem., 26, 2089 (2014); doi:10.14233/ajchem.2014.16183B.

(a) N. Wang, M. Wang, L. Chen and L.C. Sun, Dalton Trans., 42, 12059 (2013); doi:10.1039/c3dt51371h; (b) P.H. Zhao, W.T. Wang, Y.F. Liu and Y.Q. Liu, Transition Met. Chem., 39, 501 (2014); doi:10.1007/s11243-014-9825-x; (c) X.F. Liu and H.Q. Gao, J. Cluster Sci., 25, 367 (2014); doi:10.1007/s10876-013-0615-y; (d) X.F. Liu and H.Q. Gao, J. Cluster Sci., 25, 495 (2014); doi:10.1007/s10876-013-0627-7; (e) W. Gao, L.Q. Tian and J. Yang, Asian J. Chem., 26, 2086 (2014); doi:10.14233/ajchem.2014.16183A.

(a) T.H. Yen, K.T. Chu, W.W. Chiu, Y.C. Chien, G.H. Lee and M.H. Chiang, Polyhedron, 64, 247 (2013); doi:10.1016/j.poly.2013.05.019; (b) X.F. Liu and X.W. Xiao, J. Organomet. Chem., 696, 2767 (2011); doi:10.1016/j.jorganchem.2011.05.007; (c) X.F. Liu, Z.Q. Jiang and Z.J. Jia, Polyhedron, 33, 166 (2012); doi:10.1016/j.poly.2011.11.032; (d) C.G. Li, Y. Zhu, X.X. Jiao and X.Q. Fu, Polyhedron, 67, 416 (2014); doi:10.1016/j.poly.2013.09.027; (e) Y.L. Li, B. Xie, L.K. Zou, X. Lin, Y. Yang, S.S. Zhu and T. Wang, Polyhedron, 67, 490 (2014); doi:10.1016/j.poly.2013.09.041; (f) P.H. Zhao, Y.F. Liu, K.K. Xiong and Y.Q. Liu, J. Clust. Sci., 25, 1061 (2014); doi:10.1007/s10876-014-0689-1; (g) P.H. Zhao, S.N. Liu, Y.F. Liu and Y.Q. Liu, J. Clust. Sci., 25, 1331 (2014); doi:10.1007/s10876-014-0711-7; (h) W. Gao, F.P. Guo and J. Yang, Asian J. Chem., 26, 2083 (2014); doi:10.14233/ajchem.2014.16183.

X.F. Liu, Inorg. Chim. Acta, 421, 10 (2014); doi:10.1016/j.ica.2014.05.022.

W. Gao, K. Li and X.L. Wang, Asian J. Chem., 25, 7876 (2013); doi:10.14233/ajchem.2013.14667.

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Synthesis and Characterization of Mononuclear Nickel Complexes with Dithiolate Ligands

Corresponding Author(s) : Wei Gao

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents