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Vol. 27 No. 9 (2015): Vol 27 Issue 9

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Synthesis and Crystal Structure of Trinuclear Copper(I/II) Complex[Cu(pa)2][Cu(pht)2]2

https://doi.org/10.14233/ajchem.2015.18849
Xi-Lan Hu
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China; Jiangsu Deveronmentresearch Insititute of Marine Resources, Huaihai Institute of Technology, Lianyungang 222005, P.R. China
Fu-Jun Yin
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China; Jiangsu Deveronmentresearch Insititute of Marine Resources, Huaihai Institute of Technology, Lianyungang 222005, P.R. China
Peng-Fei Shi
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China; Jiangsu Deveronmentresearch Insititute of Marine Resources, Huaihai Institute of Technology, Lianyungang 222005, P.R. China
Da-Qi Wang
College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P.R. China
Xu-Rui Bo
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China

Corresponding Author(s) : Fu-Jun Yin

yinfujun2008@126.com

Asian Journal of Chemistry, Vol. 27 No. 9 (2015): Vol 27 Issue 9

Abstract

A novel trinuclear copper(I/II) complex [Cu(pa)2][Cu(pht)2]2 (pa =1,3-propylenediamine, Hpht = 5,5-diphenylhydantoin, i.e. phenytoin) has been synthesized under hydrothermal condition and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The tricnuclear Cu(I/II) complex is triclinic, space group Pi, with a = 8.6506(12), b = 11.8844(16), c = 15.367(2) Å, a = 98.5940(10), b = 92.2810(10), g = 104.188(2)°, Z =1, Dc = 1.478 g/cm3, μ = 1.115 mm-1, the final R = 0.0812 and wR = 0.2029. The complex consists of an interesting trinuclear copper(I/II) unit. In the crystal structure, each Cu(I) ion is linearly coordinated by N2 and N4 from two different 5,5-diphenylhydantoin, respectively and the six coordinated Cu(II) ion adopted a distorted octahedral geomety.

Keywords

Copper(I/II) Complex Phenytoin
Hu, X.-L., Yin, F.-J., Shi, P.-F., Wang, D.-Q., & Bo, X.-R. (2015). Synthesis and Crystal Structure of Trinuclear Copper(I/II) Complex[Cu(pa)2][Cu(pht)2]2. Asian Journal of Chemistry, 27(9), 3401–3403. https://doi.org/10.14233/ajchem.2015.18849
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