Synthesis, Characterization and Properties of Amphiphilic Fluorine-Containing Copolymer

Zhenquan Li; Xulong Cao; Caiyu Song; Xiaojin Wang; Yebang Tan

doi:10.14233/ajchem.2015.18611

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Issue Published : May 26, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Characterization and Properties of Amphiphilic Fluorine-Containing Copolymer

https://doi.org/10.14233/ajchem.2015.18611

Zhenquan Li

Research Institute of Geology, Shengli Oilfield Company, SINOPEC, Dongying 257015, Shandong, P.R. China

Xulong Cao

Research Institute of Geology, Shengli Oilfield Company, SINOPEC, Dongying 257015, Shandong, P.R. China

Caiyu Song

School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P.R. China

Xiaojin Wang

School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P.R. China

Yebang Tan

School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P.R. China

Corresponding Author(s) : Yebang Tan

ybtan@sdu.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 9 (2015): Vol 27 Issue 9
Article Published : May 26, 2015

Abstract

A series of amphiphilic fluorine-containing copolymers PAMDF were synthesized from varying amounts of acrylamide (AM) and diallylamine derivatives (DF) with a fluorinated side chain via solution copolymerization. The diallylamine derivatives monomer was synthesized by reacting perfluorohexyl ethyl acrylate (PFHEA) with diallylamine to introduce fluorinated side-chains and rigid plane structure with strong fluorescence property into the copolymers. The amphiphilic fluorine-containing copolymers were characterized by ¹H NMR, ¹⁹F NMR, Elemental analyze and static light scattering measurements. The basic physico-chemical properties of the copolymers in an aqueous medium were investigated by means of surface tension, dynamic laser light scattering and resonance light scattering. The surface tension measurement indicated that the surface activity of the copolymers in aqueous solution increased with increasing the diallylamine derivatives content of amphiphilic copolymers. Dynamic laser light scattering measurement revealed the hydrophobic association behaviour of copolymers in aqueous solutions depended on the copolymer concentration, the content of hydrophobic diallylamine derivatives side chains and the addition of salt. The resonance light scattering results demonstrated the critical aggregation concentration of the copolymers was 0.01-0.05 mg mL^-1 in aqueous solutions.

Keywords

Water soluble polymer Hydrophobic association Fluorocarbon structure Aggregation behaviour

Li, Z., Cao, X., Song, C., Wang, X., & Tan, Y. (2015). Synthesis, Characterization and Properties of Amphiphilic Fluorine-Containing Copolymer. Asian Journal of Chemistry, 27(9), 3315–3320. https://doi.org/10.14233/ajchem.2015.18611

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References

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J.C. Ravey and M. Stébé, Colloids Surf. A, 84, 11 (1994); doi:10.1016/0927-7757(93)02731-S.

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J.C. Salamone, Polymeric Materials Encyclopedia, CRC Press: Boca Raton, FL, USA, vol. 4 (1996).

G. Hougham, Fluoropolymers; Kluwer Academic, New York, USA (1999).

S. Ebnesajjad, Fluoroplastics; Plastic Design Library, New York, USA (2002).

S.T. Iacono, S.M. Budy, J. Jin and D.W. Smith Jr., J. Polym. Sci. A Polym. Chem., 45, 5705 (2007); doi:10.1002/pola.22390.

R. Bongiovanni, G. Malucelli, A. Pollicino, C. Tonelli, G. Simeone and A. Priola, Macromol. Chem. Phys., 199, 1099 (1998); doi:10.1002/(SICI)1521-3935(19980601)199:6<1099::AID-MACP1099>3.0.CO;2-Q.

D. Valade, F. Boschet and B. Ameduri, Polym. Sci. Part A: Polym. Chem., 49, 4668 (2011); doi:10.1002/pola.24913.

J. Sha and C.K. Ober, Polym. Int., 58, 302 (2009); doi:10.1002/pi.2533.

G. Liu, W. Fan, L.J. Li, P.K. Chu, K.W.K. Yeung, S. Wu and Z. Xu, Fluor. Chem., 141, 21 (2012); doi:10.1016/j.jfluchem.2012.05.021.

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G.B. Butler and F.L. Ingley, J. Am. Chem. Soc., 73, 1512 (1951); doi:10.1021/ja01148a030.

N.S. Tüzün and V.J. Aviyente, Phys. Chem., 106, 8184 (2002); doi:10.1021/jp025950g.

H. Shao, L. Jiang, W.-D. Meng and F.-L. Qing, Fluor. Chem., 124, 89 (2003); doi:10.1016/S0022-1139(03)00193-3.

J.L. He, P.H. Ni and C.C.J. Liu, Polym. Sci. Part A: Polym. Chem., 46, 3029 (2008); doi:10.1002/pola.22641.

M. Li, M. Jiang, Y.-X. Zhang and Q. Fang, Macromolecules, 30, 470 (1997); doi:10.1021/ma960966o.

C.C. Liu, J.L. He, Q. Zhao, M. Zhang and P. Ni, J. Polym. Sci. A Polym. Chem., 47, 2702 (2009); doi:10.1002/pola.23355.

Y.C. Wang and M.A. Winnik, Langmuir, 6, 1437 (1990); doi:10.1021/la00099a001.

Y.J. Che, Y.B. Tan, J. Cao, H.P. Xin and G.Y. Xu, Polym. Bull., 66, 17 (2011); doi:10.1007/s00289-010-0255-4.

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Synthesis, Characterization and Properties of Amphiphilic Fluorine-Containing Copolymer

Corresponding Author(s) : Yebang Tan

Abstract

Keywords

Full Article

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