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Synthesis of sec-Butyl Disulfide by Phase Transfer Catalysis
Corresponding Author(s) : Guoqin Hu
Asian Journal of Chemistry,
Vol. 27 No. 9 (2015): Vol 27 Issue 9
Abstract
sec-Butyl disulfide was synthesized from sulfur, sodium hydroxide and sec-butyl chloride using tetrabutyl ammonium bromide as the phase transfer catalyst. The optimal experiment condition obtained by orthogonal design and the average product yield was 84.95 %. The samples synthesized under optical conditions were characterized by infrared spectrometry, gas chromatography-mass spectrometer.
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- Y.N. Yan, Res. Progr. Synth. Sym. Disulfide, 24, 28 (2005).
- V.I. Cohen, Helv. Chim. Acta, 59, 840 (1976); doi:10.1002/hlca.19760590313.
- S.U. Sonavane, M. Chidambaram, J. Almog and Y. Sasson, Tetrahedron Lett., 48, 6048 (2007); doi:10.1016/j.tetlet.2007.06.074.
- P. Metzner and A. Thuillier, Sulfur Reagents in Organic Chemistry, Academic Press (1994).
- N. Iranpoor, H. Firouzabadi and A.R. Pourali, Phosphorus Sulfur Silicon Rel. Elem., 181, 473 (2006); doi:10.1080/10426500500263656.
- M. Arisawa, C. Sugata and M. Yamaguchi, Tetrahedron Lett., 46, 6097 (2005); doi:10.1016/j.tetlet.2005.06.169.
- K.-T. Liu and Y.-C. Tong, Synthesis, 669 (1978); doi:10.1055/s-1978-24844.
- G.Q. Hu, X.-J. Wang, W. Li, H. Li and Y.D. Zhang, Chemical Reagents, 32, 941 (2010).
- X.Q. Liu, B.-H. Xie, W. Li and G.-Q. Hu, Fine Chemicals, 29, 813 (2012).
- M.E. Niyazymbetov, L.D. Konyushkin, Z.I. Niyazymbetova, V.P. Litvinov and V.A. Petrosyan, Synth. Commun., 23, 1659 (1993); doi:10.1080/00397919308011263.
References
Y.N. Yan, Res. Progr. Synth. Sym. Disulfide, 24, 28 (2005).
V.I. Cohen, Helv. Chim. Acta, 59, 840 (1976); doi:10.1002/hlca.19760590313.
S.U. Sonavane, M. Chidambaram, J. Almog and Y. Sasson, Tetrahedron Lett., 48, 6048 (2007); doi:10.1016/j.tetlet.2007.06.074.
P. Metzner and A. Thuillier, Sulfur Reagents in Organic Chemistry, Academic Press (1994).
N. Iranpoor, H. Firouzabadi and A.R. Pourali, Phosphorus Sulfur Silicon Rel. Elem., 181, 473 (2006); doi:10.1080/10426500500263656.
M. Arisawa, C. Sugata and M. Yamaguchi, Tetrahedron Lett., 46, 6097 (2005); doi:10.1016/j.tetlet.2005.06.169.
K.-T. Liu and Y.-C. Tong, Synthesis, 669 (1978); doi:10.1055/s-1978-24844.
G.Q. Hu, X.-J. Wang, W. Li, H. Li and Y.D. Zhang, Chemical Reagents, 32, 941 (2010).
X.Q. Liu, B.-H. Xie, W. Li and G.-Q. Hu, Fine Chemicals, 29, 813 (2012).
M.E. Niyazymbetov, L.D. Konyushkin, Z.I. Niyazymbetova, V.P. Litvinov and V.A. Petrosyan, Synth. Commun., 23, 1659 (1993); doi:10.1080/00397919308011263.