Microwave-Assisted Hydroxylation of Benzene to Phenol Over V(V)/MCM-41 Catalysts at Room Temperature

Tong Liu; Sujuan Fan; Jinhui Hou

doi:10.14233/ajchem.2015.18379

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Issue Published : May 26, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Microwave-Assisted Hydroxylation of Benzene to Phenol Over V(V)/MCM-41 Catalysts at Room Temperature

https://doi.org/10.14233/ajchem.2015.18379

Tong Liu

School of Chemistry and Chemical Engineering, Xuzhou Institute of Technology, Xuzhou 221111, Jiangsu Province, P.R. China

Sujuan Fan

Xuzhou Central Hospital, Xuzhou 221009, Jiangsu Province, P.R. China

Jinhui Hou

School of Food (Biology) Engineering, Xuzhou Institute of Technology, Xuzhou 221111, Jiangsu Province, P.R. China

Corresponding Author(s) : Tong Liu

liutongcumt@126.com

Asian Journal of Chemistry, Vol. 27 No. 9 (2015): Vol 27 Issue 9
Article Published : May 26, 2015

Abstract

Direct hydroxylation of benzene to phenol with hydrogen peroxide over catalysts prepared by the metal species e.g., V(V), Cu(II), Co(II) impregnated on MCM-41 was examined at room temperature under microwave irradiation. This paper investigated the catalytic performances of MCM-41 supports prepared by various calcined temperature and time. The results manifested that the V(V)/MCM-41 catalyst gave the highest activity than Cu(II), Co(II)/MCM-41 at same experimental conditions. The influence of various reaction parameters, such as reaction time, amount of catalyst and hydrogen peroxide, on the conversion of benzene was investigated under microwave irradiation. Coupled conventionally heated method gives phenol yield of 5.8 %, the V(V)/MCM-41 gives higher phenol yield of 18.7 % and selectivity of 100 % under microwave irradiation.

Keywords

Hydroxylation Benzene Phenol Hydrogen peroxide V(V)/MCM-41

Liu, T., Fan, S., & Hou, J. (2015). Microwave-Assisted Hydroxylation of Benzene to Phenol Over V(V)/MCM-41 Catalysts at Room Temperature. Asian Journal of Chemistry, 27(9), 3201–3204. https://doi.org/10.14233/ajchem.2015.18379

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References

T. Sakamoto, T. Takagaki, A. Sakakura, Y. Obora, S. Sakaguchi and Y. Ishii, J. Mol. Catal. Chem., 288, 19 (2008); doi:10.1016/j.molcata.2008.04.002.
K. Lemke, H. Ehrich, U. Lohse, H. Berndt and K. Jähnisch, Appl. Catal. A., 243, 41 (2003); doi:10.1016/S0926-860X(02)00535-5.
M. Tani, T. Sakamoto, S. Mita, S. Sakaguchi and Y. Ishii, Angew. Chem. Int. Ed., 44, 2586 (2005); doi:10.1002/anie.200462769.
G. Tanarungsun, W. Kiatkittipong, P. Praserthdam, H. Yamada, T. Tagawa and S. Assabumrungrat, Catal. Commun., 9, 1886 (2008); doi:10.1016/j.catcom.2008.03.008.
J.K. Joseph, S. Singhal, S.L. Jain, R. Sivakumaran, B. Kumar and B. Sain, Catal. Today, 141, 211 (2009); doi:10.1016/j.cattod.2008.05.037.
A.N. Kharat, S. Moosavikia, B.T. Jahromi and A. Badiei, J. Mol. Catal. Chem., 348, 14 (2011); doi:10.1016/j.molcata.2011.07.014.
V.S. Chemyavsky, L.V. Pirutko, A.K. Uriarte, A.S. Kharitonov and G.I. Panov, J. Catal., 245, 466 (2007); doi:10.1016/j.jcat.2006.10.023.
E.J.M. Hensen, Q. Zhu and R.A. Van Santen, J. Catal., 233, 136 (2005); doi:10.1016/j.jcat.2005.04.008.
T. Liu, Y.X. Wang and J.H. Hou, Asian J. Chem., 26, 745 (2014); doi:10.14233/ajchem.2014.15514.
T. Liu and J.H. Hou, Asian J. Chem., 26, 2683 (2014); doi:10.14233/ajchem.2014.15799.
K. Nomiya, H. Yanagibayashi, C. Nozaki, K. Kondoh, E. Hiramatsu and Y. Shimizu, J. Mol. Catal. Chem., 114, 181 (1996); doi:10.1016/S1381-1169(96)00316-0.
G. Bond, R.B. Moyes and D.A. Whan, Catal. Today, 17, 427 (1993); doi:10.1016/0920-5861(93)80046-4.
P. Lidström, J. Tierney, B. Wathey and J. Westman, Tetrahedron, 57, 9225 (2001); doi:10.1016/S0040-4020(01)00906-1.

References

T. Sakamoto, T. Takagaki, A. Sakakura, Y. Obora, S. Sakaguchi and Y. Ishii, J. Mol. Catal. Chem., 288, 19 (2008); doi:10.1016/j.molcata.2008.04.002.

K. Lemke, H. Ehrich, U. Lohse, H. Berndt and K. Jähnisch, Appl. Catal. A., 243, 41 (2003); doi:10.1016/S0926-860X(02)00535-5.

M. Tani, T. Sakamoto, S. Mita, S. Sakaguchi and Y. Ishii, Angew. Chem. Int. Ed., 44, 2586 (2005); doi:10.1002/anie.200462769.

G. Tanarungsun, W. Kiatkittipong, P. Praserthdam, H. Yamada, T. Tagawa and S. Assabumrungrat, Catal. Commun., 9, 1886 (2008); doi:10.1016/j.catcom.2008.03.008.

J.K. Joseph, S. Singhal, S.L. Jain, R. Sivakumaran, B. Kumar and B. Sain, Catal. Today, 141, 211 (2009); doi:10.1016/j.cattod.2008.05.037.

A.N. Kharat, S. Moosavikia, B.T. Jahromi and A. Badiei, J. Mol. Catal. Chem., 348, 14 (2011); doi:10.1016/j.molcata.2011.07.014.

V.S. Chemyavsky, L.V. Pirutko, A.K. Uriarte, A.S. Kharitonov and G.I. Panov, J. Catal., 245, 466 (2007); doi:10.1016/j.jcat.2006.10.023.

E.J.M. Hensen, Q. Zhu and R.A. Van Santen, J. Catal., 233, 136 (2005); doi:10.1016/j.jcat.2005.04.008.

T. Liu, Y.X. Wang and J.H. Hou, Asian J. Chem., 26, 745 (2014); doi:10.14233/ajchem.2014.15514.

T. Liu and J.H. Hou, Asian J. Chem., 26, 2683 (2014); doi:10.14233/ajchem.2014.15799.

K. Nomiya, H. Yanagibayashi, C. Nozaki, K. Kondoh, E. Hiramatsu and Y. Shimizu, J. Mol. Catal. Chem., 114, 181 (1996); doi:10.1016/S1381-1169(96)00316-0.

G. Bond, R.B. Moyes and D.A. Whan, Catal. Today, 17, 427 (1993); doi:10.1016/0920-5861(93)80046-4.

P. Lidström, J. Tierney, B. Wathey and J. Westman, Tetrahedron, 57, 9225 (2001); doi:10.1016/S0040-4020(01)00906-1.

Issue

Vol. 27 No. 9 (2015): Vol 27 Issue 9

Microwave-Assisted Hydroxylation of Benzene to Phenol Over V(V)/MCM-41 Catalysts at Room Temperature

Corresponding Author(s) : Tong Liu

Abstract

Keywords

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