Copyright (c) 2015 AJC
![Creative Commons License](http://i.creativecommons.org/l/by/4.0/88x31.png)
This work is licensed under a Creative Commons Attribution 4.0 International License.
Effects of Precipitants on Fischer-Tropsch Synthesis Over Co-Ru-Al2O3 Catalysts
Corresponding Author(s) : Debao Li
Asian Journal of Chemistry,
Vol. 27 No. 8 (2015): Vol 27 Issue 8
Abstract
In this work, the effects of precipitants on the physicochemical properties of the precursors, alumina, catalysts and the corresponding catalytic performance for Fischer-Tropsch synthesis were investigated systematically. Furthermore, the relations between pores size distribution of alumina, cobalt particle sizes and catalytic performance for Fischer-Tropsch synthesis were studied thoroughly. It was found that Boehmite (g-AlOOH) could be prepared by using ammonia or ammonium bicarbonate as precipitants, respectively, while the ammonium aluminium carbonate hydroxide (AACH) could be prepared from precipitating ammonium carbonate. Different alumina were obtained by roasting the prepared g-AlOOH and AACH, respectively. The pores size distribution of alumina were tuned by different precipitants and thus the cobalt particle sizes and the reduction behaviours of catalysts supported on the corresponding alumina could be regulated simultaneously.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- W.P. Ma, G. Jacobs, R.A. Keogh, D.B. Bukur and B.H. Davis, Appl. Catal. A, 437-438, 1 (2012); doi:10.1016/j.apcata.2012.05.037.
- G.L. Bezemer, J.H. Bitter, H.P.C.E. Kuipers, H. Oosterbeek, J.E. Holewijn, X. Xu, F. Kapteijn, A.J. van Dillen and K.P. de Jong, J. Am. Chem. Soc., 128, 3956 (2006); doi:10.1021/ja058282w.
- A.S. Lermontov, J.B. Girardon, A. Griboval-Constant, S. Pietrzyk and A.Y. Khodakov, Catal. Lett., 101, 117 (2005); doi:10.1007/s10562-005-3759-z.
- O. Borg, P.D.C. Dietzel, A.I. Spjelkavik, E.Z. Tveten, J.C. Walmsley, S. Diplas, S. Eri, A. Holmen and E. Rytter, J. Catal., 259, 161 (2008); doi:10.1016/j.jcat.2008.08.017.
- M.R. Hemmati, M. Kazemeini, F. Khorasheh and J. Zarkesh, J. Taiwan Inst. Chem. Eng., 44, 205 (2013); doi:10.1016/j.jtice.2012.11.003.
- A.Y. Khodakov, A. Griboval-Constant, R. Bechara and V.L. Zholobenko, J. Catal., 206, 230 (2002); doi:10.1006/jcat.2001.3496.
- A.Y. Khodakov, J.S. Girardon, A. Griboval-Constant, A.S. Lermontov and P.A. Chernavskii, Stud. Surf. Sci. Catal., 147, 295 (2004); doi:10.1016/S0167-2991(04)80067-3.
- O. Borg, S. Eri, E. Blekkan, S. Storsater, H. Wigum, E. Rytter and A. Holmen, J. Catal., 248, 89 (2007); doi:10.1016/j.jcat.2007.03.008.
- P. Pansanga, J. Panpranot, O. Mekasuwandumrong, C. Satayaprasert, J.G. Goodwin and P. Praserthdam, Catal. Commun., 9, 207 (2008); doi:10.1016/j.catcom.2007.05.042.
- D.C. Shin, S.S. Park, J.H. Kim, S.S. Hong, J.M. Park, S.H. Lee, D.S. Kim and G.D. Lee, J. Ind. Eng. Chem., 20, 1269 (2014); doi:10.1016/j.jiec.2013.07.003.
- Z. Tang, J.L. Liang, X.H. Li, J.F. Li, H.L. Guo, Y.Q. Liu and C.G. Liu, J. Solid State Chem., 202, 305 (2013); doi:10.1016/j.jssc.2013.03.049.
- X.F. Hu, Y.Q. Liu, Z. Tang, G.C. Li, R.Y. Zhao and C.G. Liu, Mater. Res. Bull., 47, 4271 (2012); doi:10.1016/j.materresbull.2012.09.019.
- J. Kong, B.X. Chao, T. Wang and Y.L. Yan, Powder Technol., 229, 7 (2012); doi:10.1016/j.powtec.2012.05.024.
- H. Liu, H.J. Sun, J.Q. Li, X.M. He and Z.F. Zhu, Adv. Powder Technol., 23, 164 (2012); doi:10.1016/j.apt.2011.01.008.
- Z.S. Wu, Y.D. Shen, Y. Dong and J.Q. Jiang, J. Alloys Comp., 467, 600 (2009); doi:10.1016/j.jallcom.2007.12.092.
- M. Abdullah, M. Mehmood and J. Ahmad, Ceram. Int., 38, 3741 (2012); doi:10.1016/j.ceramint.2012.01.019.
- X.L. Du, Y.Q. Wang, X.H. Su and J.G. Li, Powder Technol., 192, 40 (2009); doi:10.1016/j.powtec.2008.11.008.
- K.M. Parida, A.C. Pradhan, J. Das and N. Sahu, Mater. Chem. Phys., 113, 244 (2009); doi:10.1016/j.matchemphys.2008.07.076.
- H.K. Varma, T.V. Mani, A.D. Damodaran, K.G. Warrier and U. Balachandran, J. Am. Chem. Soc., 77, 1597 (1994).
- G.J. Ji, M.M. Li, G.H. Li, G.M. Gao, H.F. Zou, S.C. Gan and X.H. Xu, Powder Technol., 215-216, 54 (2012); doi:10.1016/j.powtec.2011.09.005.
- G.C. Li, Y.Q. Liu, L.L. Guan, X.F. Hu and C.G. Liu, Mater. Res. Bull., 47, 1073 (2012); doi:10.1016/j.materresbull.2011.12.026.
- C.C. Ma, N. Yao, Q. Han and X.N. Li, Chem. Eng. J., 191, 534 (2012); doi:10.1016/j.cej.2012.03.024.
- T.L. Hong, H.T. Liu, C.T. Yeh, S.H. Chen, F.C. Sheu, L.J. Leu and C.I. Wang, Appl. Catal. A, 158, 257 (1997); doi:10.1016/S0926-860X(97)00002-1.
- A.M. Hilmen, D. Schanke, K.F. Hanssen and A. Holmen, Appl. Catal. A, 186, 169 (1999); doi:10.1016/S0926-860X(99)00171-4.
- H.F. Xiong, Y.H. Zhang, K.Y. Liew and J.L. Li, Fuel Process. Technol., 90, 237 (2009); doi:10.1016/j.fuproc.2008.08.014.
- A. Tavasoli, R.M. Malek Abbaslou and A.K. Dalai, Appl. Catal. A, 346, 58 (2008); doi:10.1016/j.apcata.2008.05.001.
- H.F. Xiong, Y.H. Zhang, S.G. Wang and J.L. Li, Catal. Commun., 6, 512 (2005); doi:10.1016/j.catcom.2005.04.018.
- J.L. Zhang, J.G. Chen, J. Ren and Y.H. Sun, Appl. Catal. A, 243, 121 (2003); doi:10.1016/S0926-860X(02)00541-0.
References
W.P. Ma, G. Jacobs, R.A. Keogh, D.B. Bukur and B.H. Davis, Appl. Catal. A, 437-438, 1 (2012); doi:10.1016/j.apcata.2012.05.037.
G.L. Bezemer, J.H. Bitter, H.P.C.E. Kuipers, H. Oosterbeek, J.E. Holewijn, X. Xu, F. Kapteijn, A.J. van Dillen and K.P. de Jong, J. Am. Chem. Soc., 128, 3956 (2006); doi:10.1021/ja058282w.
A.S. Lermontov, J.B. Girardon, A. Griboval-Constant, S. Pietrzyk and A.Y. Khodakov, Catal. Lett., 101, 117 (2005); doi:10.1007/s10562-005-3759-z.
O. Borg, P.D.C. Dietzel, A.I. Spjelkavik, E.Z. Tveten, J.C. Walmsley, S. Diplas, S. Eri, A. Holmen and E. Rytter, J. Catal., 259, 161 (2008); doi:10.1016/j.jcat.2008.08.017.
M.R. Hemmati, M. Kazemeini, F. Khorasheh and J. Zarkesh, J. Taiwan Inst. Chem. Eng., 44, 205 (2013); doi:10.1016/j.jtice.2012.11.003.
A.Y. Khodakov, A. Griboval-Constant, R. Bechara and V.L. Zholobenko, J. Catal., 206, 230 (2002); doi:10.1006/jcat.2001.3496.
A.Y. Khodakov, J.S. Girardon, A. Griboval-Constant, A.S. Lermontov and P.A. Chernavskii, Stud. Surf. Sci. Catal., 147, 295 (2004); doi:10.1016/S0167-2991(04)80067-3.
O. Borg, S. Eri, E. Blekkan, S. Storsater, H. Wigum, E. Rytter and A. Holmen, J. Catal., 248, 89 (2007); doi:10.1016/j.jcat.2007.03.008.
P. Pansanga, J. Panpranot, O. Mekasuwandumrong, C. Satayaprasert, J.G. Goodwin and P. Praserthdam, Catal. Commun., 9, 207 (2008); doi:10.1016/j.catcom.2007.05.042.
D.C. Shin, S.S. Park, J.H. Kim, S.S. Hong, J.M. Park, S.H. Lee, D.S. Kim and G.D. Lee, J. Ind. Eng. Chem., 20, 1269 (2014); doi:10.1016/j.jiec.2013.07.003.
Z. Tang, J.L. Liang, X.H. Li, J.F. Li, H.L. Guo, Y.Q. Liu and C.G. Liu, J. Solid State Chem., 202, 305 (2013); doi:10.1016/j.jssc.2013.03.049.
X.F. Hu, Y.Q. Liu, Z. Tang, G.C. Li, R.Y. Zhao and C.G. Liu, Mater. Res. Bull., 47, 4271 (2012); doi:10.1016/j.materresbull.2012.09.019.
J. Kong, B.X. Chao, T. Wang and Y.L. Yan, Powder Technol., 229, 7 (2012); doi:10.1016/j.powtec.2012.05.024.
H. Liu, H.J. Sun, J.Q. Li, X.M. He and Z.F. Zhu, Adv. Powder Technol., 23, 164 (2012); doi:10.1016/j.apt.2011.01.008.
Z.S. Wu, Y.D. Shen, Y. Dong and J.Q. Jiang, J. Alloys Comp., 467, 600 (2009); doi:10.1016/j.jallcom.2007.12.092.
M. Abdullah, M. Mehmood and J. Ahmad, Ceram. Int., 38, 3741 (2012); doi:10.1016/j.ceramint.2012.01.019.
X.L. Du, Y.Q. Wang, X.H. Su and J.G. Li, Powder Technol., 192, 40 (2009); doi:10.1016/j.powtec.2008.11.008.
K.M. Parida, A.C. Pradhan, J. Das and N. Sahu, Mater. Chem. Phys., 113, 244 (2009); doi:10.1016/j.matchemphys.2008.07.076.
H.K. Varma, T.V. Mani, A.D. Damodaran, K.G. Warrier and U. Balachandran, J. Am. Chem. Soc., 77, 1597 (1994).
G.J. Ji, M.M. Li, G.H. Li, G.M. Gao, H.F. Zou, S.C. Gan and X.H. Xu, Powder Technol., 215-216, 54 (2012); doi:10.1016/j.powtec.2011.09.005.
G.C. Li, Y.Q. Liu, L.L. Guan, X.F. Hu and C.G. Liu, Mater. Res. Bull., 47, 1073 (2012); doi:10.1016/j.materresbull.2011.12.026.
C.C. Ma, N. Yao, Q. Han and X.N. Li, Chem. Eng. J., 191, 534 (2012); doi:10.1016/j.cej.2012.03.024.
T.L. Hong, H.T. Liu, C.T. Yeh, S.H. Chen, F.C. Sheu, L.J. Leu and C.I. Wang, Appl. Catal. A, 158, 257 (1997); doi:10.1016/S0926-860X(97)00002-1.
A.M. Hilmen, D. Schanke, K.F. Hanssen and A. Holmen, Appl. Catal. A, 186, 169 (1999); doi:10.1016/S0926-860X(99)00171-4.
H.F. Xiong, Y.H. Zhang, K.Y. Liew and J.L. Li, Fuel Process. Technol., 90, 237 (2009); doi:10.1016/j.fuproc.2008.08.014.
A. Tavasoli, R.M. Malek Abbaslou and A.K. Dalai, Appl. Catal. A, 346, 58 (2008); doi:10.1016/j.apcata.2008.05.001.
H.F. Xiong, Y.H. Zhang, S.G. Wang and J.L. Li, Catal. Commun., 6, 512 (2005); doi:10.1016/j.catcom.2005.04.018.
J.L. Zhang, J.G. Chen, J. Ren and Y.H. Sun, Appl. Catal. A, 243, 121 (2003); doi:10.1016/S0926-860X(02)00541-0.