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Vol. 27 No. 6 (2015): Vol 27 Issue 6

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A Simple Spectrophotometric Determination of Nickel(II) Using 1-Nitroso-2-naphthol in Anionic Micellar Solution

https://doi.org/10.14233/ajchem.2015.18779
Ghulam Abbas Shar
Department of Chemistry, Shah Abdul Latif University, Khairpur-66022, Sindh, Pakistan; Department of Chemistry, Virginia Commonwealth University, Richmond, Virginia-23284, USA
Gulafshan Soomro
Department of Crop Physiology, Sindh Agriculture University, Tandojam-70060, Pakistan

Corresponding Author(s) : Ghulam Abbas Shar

gabbas.shar@salu.edu.pk

Asian Journal of Chemistry, Vol. 27 No. 6 (2015): Vol 27 Issue 6

Abstract

A simple rapid new spectrophotometric method has been developed for the determination of nickel at trace level using 1-nitroso-2-naphthol as complexing reagent in presence of anionic aqueous micellar solution surfactant 1 % sodium dodecyl sulphate. 1-Nitroso-2-naphthol reacts with nickel(II) to form bis(1-nitroso-2-naphtholato) nickel complex. The use of micellar system replaces the previous solvent extraction steps while enhancing the sensitivity, selectivity and the molar absorptivity which reduces the cost and toxicity. The average molar absorption coefficient and Sandell's sensitivity was found to be 1.02 × 104 L mol-1 cm-1 and 5.7 ng cm-2 at lmax 471.6 nm. Linear calibration graph was obtained over the concentration range 0.25-4.0 μg mL-1, the stoichiometric composition of the chelate was 1:2 (Ni:[NNPh]2. The developed method was successfully applied for the determination of nickel from alloy and real samples.

Keywords

Spectrophotometric Nickel 1-Nitroso-2-naphthol Anionic micellar Sodium dodecyl sulphate
Abbas Shar, G., & Soomro, G. (2015). A Simple Spectrophotometric Determination of Nickel(II) Using 1-Nitroso-2-naphthol in Anionic Micellar Solution. Asian Journal of Chemistry, 27(6), 2307–2310. https://doi.org/10.14233/ajchem.2015.18779
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