Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Fermentative Hydrogen Production in Batch Experiments Using Molasses, Potato Processing Industry Wastewater and Chocolate Waste: Influence of Acidic Hydrolyzation
Corresponding Author(s) : Nevim Genç
Asian Journal of Chemistry,
Vol. 27 No. 6 (2015): Vol 27 Issue 6
Abstract
In this study, the hydrogen production potential of molasses, wastewater from potato industry and chocolate waste as substrate was investigated. Results show that Rmax (2.2 mLH2/min) was obtained for molasses and chocolate. Hydrogen production rate was lower due to the complex structure of substrates. Therefore, we are interested in using hydrolyzate obtained from acid hydrolysis of substrates. In treated molasses and chocolate, Hmax of 3190 and 6712 mL was obtained, increasing by 171 and 282 % as compared with the result of the untreated substrate, respectively. The net energy gain was calculated as negative for all substrates.
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- J. Wang and W. Wan, Int. J. Hydrogen Energy, 34, 799 (2009); doi:10.1016/j.ijhydene.2008.11.015.
- K.R.J. Perera, B. Ketheesan, V. Gadhamshetty and N. Nirmalakhandan, Int. J. Hydrogen Energy, 35, 12224 (2010); doi:10.1016/j.ijhydene.2010.08.037.
- W.H. Chen, S.Y. Chen, S.K. Khanal and S. Sung, Int. J. Hydrogen Energy, 31, 2170 (2006); doi:10.1016/j.ijhydene.2006.02.020.
- C.H. Wang, W.B. Lu and J.S. Chang, Int. J. Hydrogen Energy, 32, 3849 (2007); doi:10.1016/j.ijhydene.2007.05.009.
- L. Guo, X.M. Li, X. Bo, Q. Yang, G.M. Zeng, D.X. Liao and J.J. Liu, Bioresour. Technol., 99, 3651 (2008); doi:10.1016/j.biortech.2007.07.026.
- H. Zhu, W. Parker, R. Basnar, A. Proracki, P. Falletta, M. Beland and P. Seto, Int. J. Hydrogen Energy, 33, 3651 (2008); doi:10.1016/j.ijhydene.2008.04.040.
- X. Gomez, A. Moran, M.J. Cuetos and M.E. Sanchez, J. Power Sources, 157, 727 (2006); doi:10.1016/j.jpowsour.2006.01.006.
- Y. Wang, H. Wang, X. Feng, X. Wang and J. Huang, Int. J. Hydrogen Energy, 35, 3092 (2010); doi:10.1016/j.ijhydene.2009.07.024.
- R. Datar, J. Huang, P.C. Maness, A. Mohagheghi, S. Czernik and E. Chornet, Int. J. Hydrogen Energy, 32, 932 (2007); doi:10.1016/j.ijhydene.2006.09.027.
- S. Pattra, S. Sangyoka, M. Boonmee and A. Reungsand, Int. J. Hydrogen Energy, 33, 5256 (2008); doi:10.1016/j.ijhydene.2008.05.008.
- I. Ntaikou, H.N. Gavala and G. Lyberatos, Int. J. Hydrogen Energy, 35, 3423 (2010); doi:10.1016/j.ijhydene.2010.01.118.
- G. Davila-Vazquez, F. Alatriste-Mondragon, A.D. Leon-Rodriguez and E. Razo-Flores, Int. J. Hydrogen Energy, 33, 4989 (2008); doi:10.1016/j.ijhydene.2008.06.065.
- L. Guo, X.M. Li, G.M. Zeng and Y. Zhou, Energy, 35, 3557 (2010); doi:10.1016/j.energy.2010.04.005.
- H. Argun, F. Kargi and I.K. Kapdan, Int. J. Hydrogen Energy, 34, 2195 (2009); doi:10.1016/j.ijhydene.2008.12.066.
- P. Chairattanamanokorn, P. Penthamkeerati, A. Reungsang, Y.C. Lo, W.B. Lu and J.S. Chang, Int. J. Hydrogen Energy, 34, 7612 (2009); doi:10.1016/j.ijhydene.2009.07.034.
- A.E. Mars, T. Veuskens, M.A.W. Budde, P.F.N.M.V. Doeveern, S.J. Lips, R.R. Bakker, T.D. Vrije and P.A.M. Classen, Int. J. Hydrogen Energy, 35, 7730 (2010); doi:10.1016/j.ijhydene.2010.05.063.
- C.H. Lay, J.H. Wu, C.L. Hsiao, J.J. Chang, C.C. Chen and C.Y. Lin, Int. J. Hydrogen Energy, 35, 13445 (2010); doi:10.1016/j.ijhydene.2009.11.128.
- Y. Xing, Z. Li, Y. Fan and H. Hou, Environ. Sci. Pollut. Res., 17, 392 (2010); doi:10.1007/s11356-009-0187-4.
- Y.C. Lo, S.D. Chen, C.Y. Chen, T.I. Huang, C.Y. Lin and J.S. Chang, Int. J. Hydrogen Energy, 33, 5224 (2008); doi:10.1016/j.ijhydene.2008.05.014.
- M. Cui, Z. Yuan and X. Zhi, L. Wei and J. Shen, Int. J. Hydrogen Energy, 35, 4041 (2010); doi:10.1016/j.ijhydene.2010.02.035.
- M. Al-Alawi, NATO Science for Peace and Security Series, p. 177 (2007).
- B. Sen and R.R. Suttar, Int. J. Hydrogen Energy, 37, 15588 (2012); doi:10.1016/j.ijhydene.2012.04.027.
- Y. Mu, G. Wang and H.-Q. Yu, Bioresour. Technol., 97, 1302 (2006); doi:10.1016/j.biortech.2005.05.014.
- V. Gadhamshetty, Y. Arudchelvam, N. Nirmalakhandan and D.C. Johnson, Int. J. Hydrogen Energy, 35, 479 (2010); doi:10.1016/j.ijhydene.2009.11.007.
- Y. Mu, H.Q. Yu and G. Wang, Water Res., 41, 1152 (2007); doi:10.1016/j.watres.2006.11.047.
- S.W.V.G. Ginkel, S.E. Oh and B.E. Logan, Int. J. Hydrogen Energy, 30, 1535 (2005); doi:10.1016/j.ijhydene.2004.09.017.
- C.-A. Aceves-Lara, E. Latrille, N. Bernet, P. Buffière and J.-P. Steyer, Water Res., 42, 2539 (2008); doi:10.1016/j.watres.2008.02.018.
- G. Antonopoulou, H.N. Gavala, I.V. Skiadas, K. Angelopoulos and G. Lyberatos, Bioresour. Technol., 99, 110 (2008); doi:10.1016/j.biortech.2006.11.048.
References
J. Wang and W. Wan, Int. J. Hydrogen Energy, 34, 799 (2009); doi:10.1016/j.ijhydene.2008.11.015.
K.R.J. Perera, B. Ketheesan, V. Gadhamshetty and N. Nirmalakhandan, Int. J. Hydrogen Energy, 35, 12224 (2010); doi:10.1016/j.ijhydene.2010.08.037.
W.H. Chen, S.Y. Chen, S.K. Khanal and S. Sung, Int. J. Hydrogen Energy, 31, 2170 (2006); doi:10.1016/j.ijhydene.2006.02.020.
C.H. Wang, W.B. Lu and J.S. Chang, Int. J. Hydrogen Energy, 32, 3849 (2007); doi:10.1016/j.ijhydene.2007.05.009.
L. Guo, X.M. Li, X. Bo, Q. Yang, G.M. Zeng, D.X. Liao and J.J. Liu, Bioresour. Technol., 99, 3651 (2008); doi:10.1016/j.biortech.2007.07.026.
H. Zhu, W. Parker, R. Basnar, A. Proracki, P. Falletta, M. Beland and P. Seto, Int. J. Hydrogen Energy, 33, 3651 (2008); doi:10.1016/j.ijhydene.2008.04.040.
X. Gomez, A. Moran, M.J. Cuetos and M.E. Sanchez, J. Power Sources, 157, 727 (2006); doi:10.1016/j.jpowsour.2006.01.006.
Y. Wang, H. Wang, X. Feng, X. Wang and J. Huang, Int. J. Hydrogen Energy, 35, 3092 (2010); doi:10.1016/j.ijhydene.2009.07.024.
R. Datar, J. Huang, P.C. Maness, A. Mohagheghi, S. Czernik and E. Chornet, Int. J. Hydrogen Energy, 32, 932 (2007); doi:10.1016/j.ijhydene.2006.09.027.
S. Pattra, S. Sangyoka, M. Boonmee and A. Reungsand, Int. J. Hydrogen Energy, 33, 5256 (2008); doi:10.1016/j.ijhydene.2008.05.008.
I. Ntaikou, H.N. Gavala and G. Lyberatos, Int. J. Hydrogen Energy, 35, 3423 (2010); doi:10.1016/j.ijhydene.2010.01.118.
G. Davila-Vazquez, F. Alatriste-Mondragon, A.D. Leon-Rodriguez and E. Razo-Flores, Int. J. Hydrogen Energy, 33, 4989 (2008); doi:10.1016/j.ijhydene.2008.06.065.
L. Guo, X.M. Li, G.M. Zeng and Y. Zhou, Energy, 35, 3557 (2010); doi:10.1016/j.energy.2010.04.005.
H. Argun, F. Kargi and I.K. Kapdan, Int. J. Hydrogen Energy, 34, 2195 (2009); doi:10.1016/j.ijhydene.2008.12.066.
P. Chairattanamanokorn, P. Penthamkeerati, A. Reungsang, Y.C. Lo, W.B. Lu and J.S. Chang, Int. J. Hydrogen Energy, 34, 7612 (2009); doi:10.1016/j.ijhydene.2009.07.034.
A.E. Mars, T. Veuskens, M.A.W. Budde, P.F.N.M.V. Doeveern, S.J. Lips, R.R. Bakker, T.D. Vrije and P.A.M. Classen, Int. J. Hydrogen Energy, 35, 7730 (2010); doi:10.1016/j.ijhydene.2010.05.063.
C.H. Lay, J.H. Wu, C.L. Hsiao, J.J. Chang, C.C. Chen and C.Y. Lin, Int. J. Hydrogen Energy, 35, 13445 (2010); doi:10.1016/j.ijhydene.2009.11.128.
Y. Xing, Z. Li, Y. Fan and H. Hou, Environ. Sci. Pollut. Res., 17, 392 (2010); doi:10.1007/s11356-009-0187-4.
Y.C. Lo, S.D. Chen, C.Y. Chen, T.I. Huang, C.Y. Lin and J.S. Chang, Int. J. Hydrogen Energy, 33, 5224 (2008); doi:10.1016/j.ijhydene.2008.05.014.
M. Cui, Z. Yuan and X. Zhi, L. Wei and J. Shen, Int. J. Hydrogen Energy, 35, 4041 (2010); doi:10.1016/j.ijhydene.2010.02.035.
M. Al-Alawi, NATO Science for Peace and Security Series, p. 177 (2007).
B. Sen and R.R. Suttar, Int. J. Hydrogen Energy, 37, 15588 (2012); doi:10.1016/j.ijhydene.2012.04.027.
Y. Mu, G. Wang and H.-Q. Yu, Bioresour. Technol., 97, 1302 (2006); doi:10.1016/j.biortech.2005.05.014.
V. Gadhamshetty, Y. Arudchelvam, N. Nirmalakhandan and D.C. Johnson, Int. J. Hydrogen Energy, 35, 479 (2010); doi:10.1016/j.ijhydene.2009.11.007.
Y. Mu, H.Q. Yu and G. Wang, Water Res., 41, 1152 (2007); doi:10.1016/j.watres.2006.11.047.
S.W.V.G. Ginkel, S.E. Oh and B.E. Logan, Int. J. Hydrogen Energy, 30, 1535 (2005); doi:10.1016/j.ijhydene.2004.09.017.
C.-A. Aceves-Lara, E. Latrille, N. Bernet, P. Buffière and J.-P. Steyer, Water Res., 42, 2539 (2008); doi:10.1016/j.watres.2008.02.018.
G. Antonopoulou, H.N. Gavala, I.V. Skiadas, K. Angelopoulos and G. Lyberatos, Bioresour. Technol., 99, 110 (2008); doi:10.1016/j.biortech.2006.11.048.