Knoevenagel Condensation Reaction Using Ionic Liquid [ADPQ][CF3SO3] as Green and Reusable Catalyst

Xiaochong Gao; Can Gao; Ruichang Gao

doi:10.14233/ajchem.2015.17821

Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Issue Published : March 17, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Knoevenagel Condensation Reaction Using Ionic Liquid [ADPQ][CF3SO3] as Green and Reusable Catalyst

https://doi.org/10.14233/ajchem.2015.17821

Xiaochong Gao

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P.R. China

Can Gao

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P.R. China

Ruichang Gao

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P.R. China

Corresponding Author(s) : Ruichang Gao

pharmacy@tju.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 6 (2015): Vol 27 Issue 6
Article Published : March 18, 2015

Abstract

Knoevenagel condensation reaction of aromatic aldehydes with some active methylene compounds proceeded efficiently without solvent using ionic liquids as catalyst. The experimental results show that these ionic liquids have good catalytic activities to the Knoevenagel condensation with a wide range of reactant. The reactions are carried out in a few minutes with high yields. The ionic liquids can be recycled and reused for 4 times without noticeably decreasing the catalytic activity.

Keywords

Ionic liquids Knoevenagel condensation Aromatic aldehydes Active methylene compounds

Gao, X., Gao, C., & Gao, R. (2015). Knoevenagel Condensation Reaction Using Ionic Liquid [ADPQ][CF3SO3] as Green and Reusable Catalyst. Asian Journal of Chemistry, 27(6), 2145–2148. https://doi.org/10.14233/ajchem.2015.17821

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N. Tavakoli-Hoseini, M.M. Heravi and F.F. Bamoharram, Asian J. Chem., 22, 7208 (2010).

M.B. Deshmukh, S. Patil, S.D. Jadhav and P.B. Pawar, Synth. Commun., 42, 1177 (2012); doi:10.1080/00397911.2010.537423.

G. Bartoli, M. Bosco, A. Carlone, R. Dalpozzo, P. Galzerano, P. Melchiorre and L. Sambri, Tetrahedron Lett., 49, 2555 (2008); doi:10.1016/j.tetlet.2008.02.093.

M. Venkatanarayana and P.K. Dubey, Heteroatom Chem., 23, 41 (2012); doi:10.1002/hc.20750.

F. Su, M. Antonietti and X. Wang, Catal. Sci. Technol., 2, 1005 (2012); doi:10.1039/c2cy00012a.

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Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Knoevenagel Condensation Reaction Using Ionic Liquid [ADPQ][CF3SO3] as Green and Reusable Catalyst

Corresponding Author(s) : Ruichang Gao

Abstract

Keywords

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