Synthesis of Pt/Al2O3 Catalysts by Microemulsion Technique and Hydrogenation of p-Chloronitrobenzene

Feng Li; Rui Ma; Hua-Lin Song; Hua Song

doi:10.14233/ajchem.2015.17793

Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Issue Published : March 17, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis of Pt/Al2O3 Catalysts by Microemulsion Technique and Hydrogenation of p-Chloronitrobenzene

https://doi.org/10.14233/ajchem.2015.17793

Feng Li

Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, Heilongjiang Province, P.R. China

Rui Ma

Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, Heilongjiang Province, P.R. China

Hua-Lin Song

Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province, Mudanjiang Medical University, Mudanjiang 157011, Heilongjiang Province, P.R. China

Hua Song

Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, Heilongjiang Province, P.R. China

Corresponding Author(s) : Hua Song

songhua2004@sina.com

Asian Journal of Chemistry, Vol. 27 No. 6 (2015): Vol 27 Issue 6
Article Published : March 18, 2015

Abstract

A water-in-oil microemulsion method for preparing Pt nanoparticles supproted on Al₂O₃ catalysts based on cetyltrimethylammonium bromide/n-butanol/cyclohexane/H₂PtCl₆ solution were described. The effects of the microemulsion composition and reduction condition on hydrogenation properties over Pt/Al₂O₃ catalysts were investigated using the hydrogenation of p-chloronitrobenzene as model reactions. Compared with the impregnation-derived catalyst, the microemulsion-derived catalyst showed smaller (about 3 nm) and highly dispersed Pt nanoparticles with much higher p-chloronitrobenzene hydrogenation conversion of 76.8 %, which improved by 46.7 %. The result could be attributed to the small Pt nanoparticles with high dispersion on Al₂O₃ prepared by microemulsion method.

Keywords

Microemulsion Pt/Al2O3 Selective hydrogenation p-Chloronitrobenzene

Li, F., Ma, R., Song, H.-L., & Song, H. (2015). Synthesis of Pt/Al2O3 Catalysts by Microemulsion Technique and Hydrogenation of p-Chloronitrobenzene. Asian Journal of Chemistry, 27(6), 2125–2128. https://doi.org/10.14233/ajchem.2015.17793

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References

G. Konnecker, A. Boehncke and S. Schmidt, Fresenius Environ. Bull., 12, 589 (2003).

Y.B. Fang, X.H. Yan, J.Q. Sun, Z.Y. Xu and W.J. Wang, Chin. J. Catal., 26, 233 (2005).

Y.Y. Chen, C.A. Wang, H.Y. Liu, J.S. Qiu and X.H. Bao, Chem. Commun., 42, 5298 (2005); doi:10.1039/b509595f.

X. Yan, J. Sun, Y. Wang and J. Yang, J. Mol. Catal. Chem., 252, 17 (2006); doi:10.1016/j.molcata.2006.01.060.

X.X. Han, R.X. Zhou, G.H. Lai and X.M. Zheng, Catal. Today, 93-95, 433 (2004); doi:10.1016/j.cattod.2004.06.053.

L. Červený, I. Paseka, V. Stuchlý and V. Růžička, Collect. Czech. Chem. Commun., 47, 853 (1982); doi:10.1135/cccc19820853.

Z.K. Yu, S.J. Liao, Y. Xu, B. Yang and D.R. Yu, J. Mol. Catal. Chem., 120, 247 (1997); doi:10.1016/S1381-1169(96)00420-7.

X.X. Han, R.X. Zhou, X.M. Zheng and H. Jiang, J. Mol. Catal. Chem., 193, 103 (2003); doi:10.1016/S1381-1169(02)00178-4.

J. Wrzyszcz, M. Zawadzki, A.M. Trzeciak and J.J. Ziolkowski, J. Mol. Catal. Chem., 189, 203 (2002); doi:10.1016/S1381-1169(02)00073-0.

J.L. Zhang, Y. Wang, H. Ji, Y.G. Wei, N.Z. Wu, B.J. Zuo and Q.L. Wang, J. Catal., 229, 114 (2005); doi:10.1016/j.jcat.2004.09.029.

V. Kratky, M. Kralik, M. Mecarova, M. Stolcova, L. Zalibera and M. Hronec, Appl. Catal. A, 235, 225 (2002); doi:10.1016/S0926-860X(02)00274-0.

M. Boutonnet, S. Lögdberg and E. Elm Svensson, Curr. Opin. Colloid Interface Sci., 13, 270 (2008); doi:10.1016/j.cocis.2007.10.001.

S. Eriksson, Appl. Catal. A, 265, 207 (2004); doi:10.1016/j.apcata.2004.01.014.

J.H. Shen and Y.W. Chen, J. Mol. Catal. Chem., 273, 265 (2007); doi:10.1016/j.molcata.2007.04.015.

H.X. Li, Y.D. Wu, J. Zhang, W.L. Dai and M.H. Qiao, Appl. Catal. A, 275, 199 (2004); doi:10.1016/j.apcata.2004.07.034.

I. Lisiecki and M.P. Pileni, J. Am. Chem. Soc., 115, 3887 (1993); doi:10.1021/ja00063a006.

T.S. Ahmadi, Z.L. Wang, T.C. Green, A. Henglein and M.A. El-Sayed, Science, 272, 1924 (1996); doi:10.1126/science.272.5270.1924.

Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Synthesis of Pt/Al2O3 Catalysts by Microemulsion Technique and Hydrogenation of p-Chloronitrobenzene

Corresponding Author(s) : Hua Song

Abstract

Keywords

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