Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Copyright (c) 2015 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Structure, and Properties of Binuclear Nickel(II) Complex with Hydrogen Bond and π···π Interaction

https://doi.org/10.14233/ajchem.2015.17671
Rong-Fang Li
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, Henan Province, P.R. China
Xiao-Yu Zhang
Food and Bioengineering Department, Henan University of Science and Technology, Luoyang 471003, Henan Province, P.R. China
Tian Zhang
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, Henan Province, P.R. China
Xun Feng
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, Henan Province, P.R. China
Xin-Fang Liu
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, Henan Province, P.R. China

Corresponding Author(s) : Xin-Fang Liu

2002sooner@163.com

Asian Journal of Chemistry, Vol. 27 No. 6 (2015): Vol 27 Issue 6

Abstract

A binuclear nickel complex {[Ni2(H3bptc)2(bpmp)(H2O)4]·2H2O} (1) [H4bptc = biphenyl-2,3,3',5'-tetracarboxylic acid, bpmp = 1,4-bis(2-pyridylmethyl)pipyrazine] was obtained by hydrothermal reaction. Single crystal X-ray diffraction analysis shows that complex 1 crystallizes in triclinic space group P-1 with cell parameters a = 10.4630(11) Å, b = 10.9057(12) Å, c =13.3948(15) Å, a = 73.8070(10)°, b = 72.0600(10) °, g = 67.7310(10)°, V = 1322.6(2) Å3, Mr = 593.18, Z = 2, R1 = 0.0418, and wR2 = 0.1056. In complex 1, both Ni ions are six-coordinated to form slightly distorted octahedral coordination geometry. The binuclear symmetric nickel(II) unit containing main ligand H3bptc– and auxiliary ligand bpmp is further extended via hydrogen bonds and p···p interactions (d = 3.8454 Å) into a 3D supramolecular structure. In addition, complex 1 is also characterized by elemental analyses, IR spectra and thermogravimetric analyses.

Keywords

Dinuclear Ni(II) complex Hydrogen bond Crystal structure
Li, R.-F., Zhang, X.-Y., Zhang, T., Feng, X., & Liu, X.-F. (2015). Synthesis, Structure, and Properties of Binuclear Nickel(II) Complex with Hydrogen Bond and π···π Interaction. Asian Journal of Chemistry, 27(6), 2033–2035. https://doi.org/10.14233/ajchem.2015.17671
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. T.T. Jia, S.R. Zhu, M. Shao, Y.M. Zhao and M.X. Li, Inorg. Chem. Commun., 11, 1221 (2008); doi:10.1016/j.inoche.2008.07.014.
  2. Y.L. Gai, F.L. Jiang, L. Chen, Y. Bu, K.Z. Su, S.A. Al-Thabaiti and M.C. Hong, Inorg. Chem., 52, 7658 (2013); doi:10.1021/ic400777c.
  3. B.M. Ji, D.S. Deng, X. He, B. Liu, S.B. Miao, N. Ma, W.Z. Wang, L.G. Ji, P. Liu and X.F. Li, Inorg. Chem., 51, 2170 (2012); doi:10.1021/ic202063h.
  4. L.B. Sun, Y. Li, Z.Q. Liang, J.H. Yu and R.R. Xu, Dalton Trans., 41, 12790 (2012); doi:10.1039/c2dt31717f.
  5. Z.R. Pan, J.A. Xu, X.Q. Yao, Y.Z. Li, Z.J. Guo and H.G. Zheng, CrystEngComm, 13, 1617 (2011); doi:10.1039/c0ce00490a.
  6. S.Q. Su, W. Chen, C. Qin, S.Y. Song, Z.Y. Guo, G.H. Li, X.Z. Song, M. Zhu, S. Wang, Z.M. Hao and H.J. Zhang, Cryst. Growth Des., 12, 1808 (2012); doi:10.1021/cg201283a.
  7. N.R. Kelly, S.Goetz, S.R.Batten and P.E.Kruger, CrystEngComm, 10, 1018 (2008); doi:10.1039/b801985a.
  8. B. Li, S.Q. Zang, C. Ji, H.W. Hou and T.C.W. Mak, Cryst. Growth Des., 12, 1443 (2012); doi:10.1021/cg2015447.
  9. X.L. Wang, C. Qin and E.B. Wang, Cryst. Growth Des., 6, 439 (2006); doi:10.1021/cg050376u.
  10. S.Q. Zang, Y. Su, Y.Z. Li, J.G. Lin, X.Y. Duan, Q.J. Meng and S. Gao, CrystEngComm, 11, 122 (2009); doi:10.1039/b806899b.
  11. R.P. Feazell, C.E. Carson and K.K. Klausmeyer, Inorg. Chem., 45, 2627 (2006); doi:10.1021/ic0512835.
  12. L. Cheng, J.Q. Wang and S.H. Gou, Inorg. Chem. Commun., 14, 261 (2011); doi:10.1016/j.inoche.2010.11.009.
  13. S.Q. Guo, D. Tian, X. Zheng and H. Zhang, Inorg. Chem. Commun., 14, 1876 (2011); doi:10.1016/j.inoche.2011.08.027.
  14. S.Q. Guo, D. Tian, Y.H. Luo and H. Zhang, J. Coord. Chem., 65, 308 (2012); doi:10.1080/00958972.2011.652099.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0