Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Comparative Sorption Studies for Amaranth Dye Removal from Water in Cost-Effective Way Using Guava Leaves and Potato Peels
Corresponding Author(s) : Rabia Rehman
Asian Journal of Chemistry,
Vol. 27 No. 6 (2015): Vol 27 Issue 6
Abstract
In this work, guava leaves and potato peels were used as adsorbents for removal of synthetic dye, i.e. Amaranth. Biosorbents were characterized by FT-IR and Boehm titration. The removal of dyes was confirmed by UV-visible spectroscopy. Isothermal modeling was done and maximum adsorption capacity qm for potato peels and guava leaves, respectively was found to be 1.709 and 1.028 mg g-1, while DG° values were -1.265 and 2.461 KJ/mol which indicates that adsorption process was exothermic and spontaneous with potato peels and vice versa is true for guava leaves. Similarly, pH, moisture content and elemental analysis of the adsorbents was also carried out. Results showed that potato peels were more effective for removal of Amaranth dye than guava leaves.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- H. Hosseinzadeh, J. Shayegan and M. Jalali, Desalination Water Treat., 51, 1 (2013); doi:10.1080/19443994.2012.749190.
- R. Rehman, T. Mahmud, J. Anwar and M. Salman, J. Chem. Soc. Pak., 34, 136 (2012).
- T. Calvete, E.C. Lima, N.F. Cardoso, S.L.P. Dias and E.S. Ribeiro, Clean–Soil Air Water, 38, 521 (2010); doi:10.1002/clen.201000027.
- A. Mittal, L. Kurup (Krishnan) and V.K. Gupta, J. Hazard. Mater., 117, 171 (2005); doi:10.1016/j.jhazmat.2004.09.016.
- M.M. Hashem, A.H. Atta, M.S. Arbid, S.A. Nada, S.M. Mouneir and G.F. Asaad, J. Pioneer. Med. Sci., 1, 43 (2011).
- M. Karkmaz, E. Puzenat, C. Guillard and J.M. Herrmann, Appl. Catal. B, 51, 183 (2004); doi:10.1016/j.apcatb.2004.02.009.
- R.W. Gaikwad and S.A.M. Kinldy, Korean J. Chem. Eng., 26, 102 (2009); doi:10.1007/s11814-009-0016-y.
- V.K. Gupta, R. Jain, A. Mittal, T.A. Saleh, A. Nayak, S. Agarwal and S. Sikarwar, Mater. Sci. Eng. C, 32, 12 (2012); doi:10.1016/j.msec.2011.08.018.
- V. Ponnusami, R. Madhuram, V. Krithika and S.N. Srivastava, Chem. Eng. J., 140, 609 (2008); doi:10.1016/j.cej.2007.11.003.
- Ch.D. Prasad, P.S.P. Krishna and Ch. Srinivas, J. Chem. Pharm. Res., 4, 1868 (2012).
- K.K. Anupama and J. Abraham, Res. Chem. Intermed., 39, 4067 (2013); doi:10.1007/s11164-012-0923-0.
- J. Kumar and A. Bansal, Int. J. Environ. Sci. Technol., 9, 479 (2012); doi:10.1007/s13762-012-0064-4.
- R. Jain and S. Sikarwar, Desalination Water Treat., 28, 120 (2011); doi:10.5004/dwt.2011.1190.
- R. Ahmad and R. Kumar, Clean–Soil, Air Water, 39, 74 (2011); doi:10.1002/clen.201000125.
- B. Zargar, H. Parham and A. Hatamie, Chemosphere, 76, 554 (2009); doi:10.1016/j.chemosphere.2009.02.065.
- R. Gong, Y. Ding, M. Li, C. Yang, H. Liu and Y. Sun, Dyes Pigments, 64, 187 (2005); doi:10.1016/j.dyepig.2004.05.005.
- S.R. Shirsath, A.P. Patil, R. Patil, J.B. Naik, P.R. Gogate and S.H. Sonawane, Ultrason. Sonochem., 20, 914 (2013); doi:10.1016/j.ultsonch.2012.11.010.
- R. Kumar and M.A. Barakat, Chem. Eng. J., 226, 377 (2013); doi:10.1016/j.cej.2013.04.063.
- M. Saif Ur Rehman, M. Munir, M. Ashfaq, N. Rashid, M.F. Nazar, M. Danish and J.-I. Han, Chem. Eng. J., 228, 54 (2013); doi:10.1016/j.cej.2013.04.094.
- V.S. Mane and P.V.V. Babu, Desalination, 273, 321 (2011); doi:10.1016/j.desal.2011.01.049.
- M. Ghaedi, S. Hajati, B. Barazesh, F. Karimi and G. Ghezelbash, J. Ind. Eng. Chem., 19, 227 (2013); doi:10.1016/j.jiec.2012.08.006.
- V. Ponnusami, S. Vikram and S.N. Srivastava, J. Hazard. Mater., 152, 276 (2008); doi:10.1016/j.jhazmat.2007.06.107.
- N. Amri, R. Alrozi, M.S. Osman and N. Nasuha, J. Mater. Chem. Eng., 1, 32 (2013).
- R. Gill, A. Mahmood and R. Nazir, J. Mater. Cycles. Waste Manage., 15, 115 (2013); doi:10.1007/s10163-012-0079-4.
- M.A.M. Salleh, D.K. Mahmoud, W. Azlina, W.A. Karim and A. Idris, Desalination, 280, 1 (2011); doi:10.1016/j.desal.2011.07.019.
- O.A. Ekpete and M. Horsfall JNR, Res. J. Chem. Sci., 1, 10 (2011).
- R. Ahmad and P.K. Mondal, Sep. Sci. Technol., 44, 1638 (2009); doi:10.1080/01496390902775836.
- S. Kamsonlian, S. Suresh, C.B. Majumder and S. Chand, Bioremediat. J., 16, 97 (2012); doi:10.1080/10889868.2012.665962.
- A.G. Deviparasad and M. Abdul Salam Abdullah, J. Appl. Sci. Environ. Sanit., 4, 273 (2008).
- J. Limsong, E. Benjavongkulchai and J. Kuvatanasuchati, J. Ethnopharmacol., 92, 281 (2004); doi:10.1016/j.jep.2004.03.008.
- S. Kartohardjono, M.A. Lukman, C.F. Utami and G.P. Manik, Global J. Environ. Res., 3, 149 (2009).
- M.M. Al-Subu, R. Salim, I. Abu-Shqair and K.M. Swaileh, Rev. Int. Contam. Ambient., 17, 91 (2001).
References
H. Hosseinzadeh, J. Shayegan and M. Jalali, Desalination Water Treat., 51, 1 (2013); doi:10.1080/19443994.2012.749190.
R. Rehman, T. Mahmud, J. Anwar and M. Salman, J. Chem. Soc. Pak., 34, 136 (2012).
T. Calvete, E.C. Lima, N.F. Cardoso, S.L.P. Dias and E.S. Ribeiro, Clean–Soil Air Water, 38, 521 (2010); doi:10.1002/clen.201000027.
A. Mittal, L. Kurup (Krishnan) and V.K. Gupta, J. Hazard. Mater., 117, 171 (2005); doi:10.1016/j.jhazmat.2004.09.016.
M.M. Hashem, A.H. Atta, M.S. Arbid, S.A. Nada, S.M. Mouneir and G.F. Asaad, J. Pioneer. Med. Sci., 1, 43 (2011).
M. Karkmaz, E. Puzenat, C. Guillard and J.M. Herrmann, Appl. Catal. B, 51, 183 (2004); doi:10.1016/j.apcatb.2004.02.009.
R.W. Gaikwad and S.A.M. Kinldy, Korean J. Chem. Eng., 26, 102 (2009); doi:10.1007/s11814-009-0016-y.
V.K. Gupta, R. Jain, A. Mittal, T.A. Saleh, A. Nayak, S. Agarwal and S. Sikarwar, Mater. Sci. Eng. C, 32, 12 (2012); doi:10.1016/j.msec.2011.08.018.
V. Ponnusami, R. Madhuram, V. Krithika and S.N. Srivastava, Chem. Eng. J., 140, 609 (2008); doi:10.1016/j.cej.2007.11.003.
Ch.D. Prasad, P.S.P. Krishna and Ch. Srinivas, J. Chem. Pharm. Res., 4, 1868 (2012).
K.K. Anupama and J. Abraham, Res. Chem. Intermed., 39, 4067 (2013); doi:10.1007/s11164-012-0923-0.
J. Kumar and A. Bansal, Int. J. Environ. Sci. Technol., 9, 479 (2012); doi:10.1007/s13762-012-0064-4.
R. Jain and S. Sikarwar, Desalination Water Treat., 28, 120 (2011); doi:10.5004/dwt.2011.1190.
R. Ahmad and R. Kumar, Clean–Soil, Air Water, 39, 74 (2011); doi:10.1002/clen.201000125.
B. Zargar, H. Parham and A. Hatamie, Chemosphere, 76, 554 (2009); doi:10.1016/j.chemosphere.2009.02.065.
R. Gong, Y. Ding, M. Li, C. Yang, H. Liu and Y. Sun, Dyes Pigments, 64, 187 (2005); doi:10.1016/j.dyepig.2004.05.005.
S.R. Shirsath, A.P. Patil, R. Patil, J.B. Naik, P.R. Gogate and S.H. Sonawane, Ultrason. Sonochem., 20, 914 (2013); doi:10.1016/j.ultsonch.2012.11.010.
R. Kumar and M.A. Barakat, Chem. Eng. J., 226, 377 (2013); doi:10.1016/j.cej.2013.04.063.
M. Saif Ur Rehman, M. Munir, M. Ashfaq, N. Rashid, M.F. Nazar, M. Danish and J.-I. Han, Chem. Eng. J., 228, 54 (2013); doi:10.1016/j.cej.2013.04.094.
V.S. Mane and P.V.V. Babu, Desalination, 273, 321 (2011); doi:10.1016/j.desal.2011.01.049.
M. Ghaedi, S. Hajati, B. Barazesh, F. Karimi and G. Ghezelbash, J. Ind. Eng. Chem., 19, 227 (2013); doi:10.1016/j.jiec.2012.08.006.
V. Ponnusami, S. Vikram and S.N. Srivastava, J. Hazard. Mater., 152, 276 (2008); doi:10.1016/j.jhazmat.2007.06.107.
N. Amri, R. Alrozi, M.S. Osman and N. Nasuha, J. Mater. Chem. Eng., 1, 32 (2013).
R. Gill, A. Mahmood and R. Nazir, J. Mater. Cycles. Waste Manage., 15, 115 (2013); doi:10.1007/s10163-012-0079-4.
M.A.M. Salleh, D.K. Mahmoud, W. Azlina, W.A. Karim and A. Idris, Desalination, 280, 1 (2011); doi:10.1016/j.desal.2011.07.019.
O.A. Ekpete and M. Horsfall JNR, Res. J. Chem. Sci., 1, 10 (2011).
R. Ahmad and P.K. Mondal, Sep. Sci. Technol., 44, 1638 (2009); doi:10.1080/01496390902775836.
S. Kamsonlian, S. Suresh, C.B. Majumder and S. Chand, Bioremediat. J., 16, 97 (2012); doi:10.1080/10889868.2012.665962.
A.G. Deviparasad and M. Abdul Salam Abdullah, J. Appl. Sci. Environ. Sanit., 4, 273 (2008).
J. Limsong, E. Benjavongkulchai and J. Kuvatanasuchati, J. Ethnopharmacol., 92, 281 (2004); doi:10.1016/j.jep.2004.03.008.
S. Kartohardjono, M.A. Lukman, C.F. Utami and G.P. Manik, Global J. Environ. Res., 3, 149 (2009).
M.M. Al-Subu, R. Salim, I. Abu-Shqair and K.M. Swaileh, Rev. Int. Contam. Ambient., 17, 91 (2001).