A One-Dimensional Compound [HgCl2(2,2'-bipy)]n (bipy = bipyridine): Synthesis and Crystal Structure

Hua-Long Chen; Wen-Tong Chen; Qiu-Yan Luo; Ya-Ping Xu

doi:10.14233/ajchem.2015.17641

Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

Issue Published : March 17, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

A One-Dimensional Compound [HgCl2(2,2'-bipy)]n (bipy = bipyridine): Synthesis and Crystal Structure

https://doi.org/10.14233/ajchem.2015.17641

Hua-Long Chen

Institute of Applied Chemistry, School of Chemistry and Chemical Engineering,Jinggangshan University, Ji'an 343009, Jiangxi, P.R. China

Wen-Tong Chen

Institute of Applied Chemistry, School of Chemistry and Chemical Engineering,Jinggangshan University, Ji'an 343009, Jiangxi, P.R. China; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, P.R. China

Qiu-Yan Luo

Institute of Applied Chemistry, School of Chemistry and Chemical Engineering,Jinggangshan University, Ji'an 343009, Jiangxi, P.R. China

Ya-Ping Xu

Institute of Applied Chemistry, School of Chemistry and Chemical Engineering,Jinggangshan University, Ji'an 343009, Jiangxi, P.R. China

Corresponding Author(s) : Wen-Tong Chen

cwtqq@aliyun.com

Asian Journal of Chemistry, Vol. 27 No. 6 (2015): Vol 27 Issue 6
Article Published : March 18, 2015

Abstract

A mercury chloride bipyridine compound [HgCl₂(2,2'-bipy)]_n (1) (bipy = bipyridine) has been synthesized through hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The title compound features a one-dimensional (1-D) infinite chain-like structure with the mercury ion showing a slightly distorted octahedral geometry. The 1-D chains pile up together through van der Waals interaction to complete three-dimensional (3-D) packing motif.

Keywords

Bipyridine Chloride Crystal structure Hydrothermal Mercury

Chen, H.-L., Chen, W.-T., Luo, Q.-Y., & Xu, Y.-P. (2015). A One-Dimensional Compound [HgCl2(2,2’-bipy)]n (bipy = bipyridine): Synthesis and Crystal Structure. Asian Journal of Chemistry, 27(6), 2005–2007. https://doi.org/10.14233/ajchem.2015.17641

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References

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References

S. Fukuzumi, H. Imahori, H. Yamada, M.E. El-Khouly, M. Fujitsuka, O. Ito and D.M. Guldi, J. Am. Chem. Soc., 123, 2571 (2001); doi:10.1021/ja002052u.

V. Balzani and A. Juris, Coord. Chem. Rev., 211, 97 (2001); doi:10.1016/S0010-8545(00)00274-5.

F.G. Gao and A.J. Bard, J. Am. Chem. Soc., 122, 7426 (2000); doi:10.1021/ja000666t.

M.E. Kosal, J.H. Chou, S.R. Wilson and K.S. Suslick, Nat. Mater., 1, 118 (2002); doi:10.1038/nmat730.

S.S. Sun and A.J. Lees, Organometallics, 21, 39 (2002); doi:10.1021/om0106027.

Y. Xie, Y.H. Xing, Z. Wang, H.Y. Zhao, X.Q. Zeng, M.F. Ge and S.Y. Niu, Inorg. Chim. Acta, 363, 918 (2010); doi:10.1016/j.ica.2009.12.037.

F.P. Huang, J.L. Tian, D.D. Li, G.J. Chen, W. Gu, S.P. Yan, X. Liu, D.Z. Liao and P. Cheng, CrystEngComm, 12, 395 (2010); doi:10.1039/b911950g.

Y. Yao, Y. Che and J. Zheng, Cryst. Growth Des., 8, 2299 (2008); doi:10.1021/cg7010106.

W.T. Chen and Z.G. Luo, Asian J. Chem, 25, 4077 (2013); doi:10.14233/ajchem.2013.14124.

W.T. Chen, H.L. Chen and H.M. Kuang, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 44, 130 (2014); doi:10.1080/15533174.2013.768658.

W.T. Chen, R.H. Hu, Z.G. Luo, H.L. Chen, X. Zhang and J. Liu, Indian J. Chem., 53A, 294 (2014).

W.T. Chen, M.S. Wang, X. Liu, G.C. Guo and J.S. Huang, Cryst. Growth Des., 6, 2289 (2006); doi:10.1021/cg060146v.

W.T. Chen, Asian J. Chem, 25, 7274 (2013); doi:10.14233/ajchem.2013.14538.

W.T. Chen, Chinese J. Struct. Chem., 32, 926 (2013).

P. Vojtisek, J. Rohovec and I. Lukes, Collect. Czech. Chem. Commun., 62, 1710 (1997); doi:10.1135/cccc19971710.

C. Titze, W. Kaim and S. Zalis, Inorg. Chem., 36, 2505 (1997); doi:10.1021/ic960837o.

X.M. Liu, X.Y. Mu, H. Xia, L. Ye, W. Gao, H.Y. Wang and Y. Mu, Eur. J. Inorg. Chem., 21, 4317 (2006); doi:10.1002/ejic.200600262.

W.T. Chen, M.S. Wang, X. Liu, G.C. Guo and J.S. Huang, Cryst. Growth Des., 6, 2289 (2006); doi:10.1021/cg060146v.

Issue

Vol. 27 No. 6 (2015): Vol 27 Issue 6

A One-Dimensional Compound [HgCl2(2,2'-bipy)]n (bipy = bipyridine): Synthesis and Crystal Structure

Corresponding Author(s) : Wen-Tong Chen

Abstract

Keywords

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