Synthesis, Crystal and Supramolecular Structures of Dinuclear Cu(II) Complex Based on 2,3-Dihydroxybenzaldehyde and 3-Ethoxysalicyladehyde

P. Wang; L. Zhao

doi:10.14233/ajchem.2015.18352

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Issue Published : February 20, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal and Supramolecular Structures of Dinuclear Cu(II) Complex Based on 2,3-Dihydroxybenzaldehyde and 3-Ethoxysalicyladehyde

https://doi.org/10.14233/ajchem.2015.18352

P. Wang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

L. Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : L. Zhao

zhaoli_72@163.com

Asian Journal of Chemistry, Vol. 27 No. 5 (2015): Vol 27 Issue 5
Article Published : February 20, 2015

Abstract

A dinuclear copper(II) complex with a asymmetrical Salamo-type chelating ligand 3-ethoxysalicylaldehyde-O-(2-hydroxyethyl) oxime (H₂L²), has been synthesized by the reaction of copper(II) salts with a Salamo-type chelating ligand 6-ethoxy-6'-hydroxy-2,2'-[1,1'-(ethylenedioxy-dinitrilo) dimethylidyne]diphenol (H₃L¹). Obviously in the process of the reaction, there is a cleavage of N-O bond which give the ligand H₂L². The formula of Cu(II) complex may be suggested as [Cu₂(L²)₂].

Keywords

Asymmetrical Salamo-type compound Cu(II) complex Synthesis Structure

Wang, P., & Zhao, L. (2015). Synthesis, Crystal and Supramolecular Structures of Dinuclear Cu(II) Complex Based on 2,3-Dihydroxybenzaldehyde and 3-Ethoxysalicyladehyde. Asian Journal of Chemistry, 27(5), 1871–1874. https://doi.org/10.14233/ajchem.2015.18352

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References

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References

T. Katsuki, Coord. Chem. Rev., 140, 189 (1995); doi:10.1016/0010-8545(94)01124-T.

A. Bencini, C. Benelli, A. Caneschi, R.L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc., 107, 8128 (1985); doi:10.1021/ja00312a054.

A.D. Garnovskii, A.L. Nivorozhkin and V.I. Minkin, Coord. Chem. Rev., 126, 1 (1993); doi:10.1016/0010-8545(93)85032-Y.

W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009); doi:10.1016/j.ica.2008.05.028.

J.-C.G. Bünzli and C. Piguet, Chem. Rev., 102, 1897 (2002); doi:10.1021/cr010299j.

M.F. Summers, L.G. Marzilli, N. Bresciani-Pahor and L. Randaccio, J. Am. Chem. Soc., 106, 4478 (1984); doi:10.1021/ja00328a030.

P.G. Lacroix, Eur. J. Inorg. Chem., 2001, 339 (2001); doi:10.1002/1099-0682(200102)2001:2<339::AID-EJIC339>3.0.CO;2-Z.

S. Akine, T. Taniguchi and T. Nabeshima, Chem. Lett., 682 (2001); doi:10.1246/cl.2001.682.

S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002); doi:10.1002/anie.200290011.

R.H. Holm, P. Kennepohl and E.I. Solomon, Chem. Rev., 96, 2239 (1996); doi:10.1021/cr9500390.

W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009); doi:10.1016/j.ica.2008.03.128.

X.Q. Song, W.S. Liu, W. Dou, Y.W. Wang, J.R. Zheng and Z.P. Zang, Eur. J. Inorg. Chem., 2008, 1901 (2008); doi:10.1002/ejic.200701279.

T. Ghosh, B. Mondal, T. Ghosh, M. Sutradhar, G. Mukherjee and M.G.B. Drew, Inorg. Chim. Acta, 360, 1753 (2007); doi:10.1016/j.ica.2006.10.003.

H.E. Smith, Chem. Rev., 83, 359 (1983); doi:10.1021/cr00056a001.

K.K. Du and S.X. Liu, Chinese J. Struct. Chem., 27, 49 (2008).

W.K. Dong, G. Li, X. Li, C.J. Yang, M.M. Zhao and X.Y. Dong, Chinese J. Inorg. Chem., 30, 1911 (2014).

W.K. Dong, W. Du, X.Y. Zhang, G. Li and X.Y. Dong, Spectrochim. Acta A, 132, 588 (2014); doi:10.1016/j.saa.2014.04.168.

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Synthesis, Crystal and Supramolecular Structures of Dinuclear Cu(II) Complex Based on 2,3-Dihydroxybenzaldehyde and 3-Ethoxysalicyladehyde

Corresponding Author(s) : L. Zhao

Abstract

Keywords

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