Synthesis, Crystal and Supramolecular Structures of New Mononuclear Cu(II) Complex [Cu(pic)2(py)2]

P. Wang; J.-C. Ma; L. Zhao

doi:10.14233/ajchem.2015.18365

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Issue Published : February 20, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal and Supramolecular Structures of New Mononuclear Cu(II) Complex [Cu(pic)2(py)2]

https://doi.org/10.14233/ajchem.2015.18365

P. Wang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

J.-C. Ma

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

L. Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

Corresponding Author(s) : L. Zhao

zhaoli_72@163.com

Asian Journal of Chemistry, Vol. 27 No. 5 (2015): Vol 27 Issue 5
Article Published : February 20, 2015

Abstract

A new mononuclear Cu(II) complex, [Cu(pic)₂(py)₂] (where pic = picrate anion and py = pyridine), has been synthesized and characterized by single crystal X-ray crystallography. The crystal structure shows that Cu(II) ion has a distorted octahedral coordination geometry. The complex crystallizes in the orthorhombic crystal system with Pna 2(1), with a = 9.488(5) Å, b = 12.469(7) Å, c = 22.449(13) Å, and Z = 4. In the crystal, the short O···O contacts and hydrogen bonding interactions constitute a 2D supramolecular layer structure.

Keywords

Copper(II) complex Crystal structure

Wang, P., Ma, J.-C., & Zhao, L. (2015). Synthesis, Crystal and Supramolecular Structures of New Mononuclear Cu(II) Complex [Cu(pic)2(py)2]. Asian Journal of Chemistry, 27(5), 1868–1870. https://doi.org/10.14233/ajchem.2015.18365

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References

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References

O.M. Yaghi, H.L. Li, C. Davis, D. Richardson and T.L. Groy, Acc. Chem. Res., 31, 474 (1998); doi:10.1021/ar970151f.

B. Moulton and M.J. Zaworotko, Chem. Rev., 101, 1629 (2001); doi:10.1021/cr9900432.

L.J. Zhou, Y.Y. Wang, C.H. Zhou, C.J. Wang, Q.Z. Shi and S.M. Peng, Cryst. Growth Des., 7, 300 (2007); doi:10.1021/cg060369l.

S.H. Rahaman, H. Chowdhury, D. Bose, G. Mostafa, H.-K. Fun and B.K. Ghosh, Inorg. Chem. Commun., 8, 1041 (2005); doi:10.1016/j.inoche.2005.08.008.

J. Lang, K. Vagnerova, J. Czernek and P. Lhotak, Supramol. Chem., 18, 371 (2006); doi:10.1080/10610270600650790.

W.K. Dong, G. Li, Z.K. Wang and X.Y. Dong, Spectrochim. Acta A, 133, 340 (2014); doi:10.1016/j.saa.2014.04.190.

M.C. Etter, Acc. Chem. Res., 23, 120 (1990); doi:10.1021/ar00172a005.

J.P. Zhang and S. Kitagawa, J. Am. Chem. Soc., 130, 907 (2008); doi:10.1021/ja075408b.

A. Westcott, J. Fisher, L.P. Harding, P. Rizkallah and M.J. Hardie, J. Am. Chem. Soc., 130, 2950 (2008); doi:10.1021/ja8002149.

N.W. Solomons, J. Am. Coll. Nutr., 4, 83 (1985); doi:10.1080/07315724.1985.10720069.

P.-F. Larsson, A. Correa, M. Carril, P.-O. Norrby and C. Bolm, Angew. Chem. Int. Ed., 48, 5691 (2009); doi:10.1002/anie.200902236.

B. Wu, X.-J. Yang, C. Janiak and P. Gerhard Lassahn, Chem. Commun., 902 (2003); doi:10.1039/b211616b.

J.R.J. Sorenson, Chem. Br., 25, 169 (1989).

R.P. Sharma, A. Saini, D. Monga, P. Venugopalan, J. Jezierska, A. Ozarowski and V. Ferretti, New J. Chem., 38, 437 (2013); doi:10.1039/c3nj00736g.

M.L. Liu, M. Jiang, K. Zheng, Y.T. Li, Z.Y. Wu and C.W. Yan, J. Coord. Chem., 67, 630 (2014); doi:10.1080/00958972.2014.884218.

W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.

L.G. Armstrong and L.F. Lindoy, Inorg. Chem., 14, 1322 (1975); doi:10.1021/ic50148a024.

Issue

Vol. 27 No. 5 (2015): Vol 27 Issue 5

Synthesis, Crystal and Supramolecular Structures of New Mononuclear Cu(II) Complex [Cu(pic)2(py)2]

Corresponding Author(s) : L. Zhao

Abstract

Keywords

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