Copyright (c) 2015 AJC
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Detection of Free Fatty Acid in Crude Palm Oil: A Review
Corresponding Author(s) : Nor Azah Yusof
Asian Journal of Chemistry,
Vol. 27 No. 5 (2015): Vol 27 Issue 5
Abstract
Palm oil quality and price is dependent on the free fatty acids (FFA) content in palm oil. High content of free fatty acids in palm oil affect the quality of palm oil and leads to various health and environmental issues. The maximum free fatty acids content set by the Palm Oil Refiners Association of Malaysia in crude palm oil is 5 % and < 0.1 % in refined bleached deodorized oil. Due to the high demand in palm oil industry market nowadays, various works has been done to improve the quality of palm oil including the determination and reduction of free fatty acids in palm oil. The traditional method for determination of free fatty acids in palm oil is through titration of the sample against potassium hydroxide in hot 2-propanol solutions by using phenolphthalein as indicator. Several other methods have also been reported on free fatty acids determination previously for example spectroscopic, chromatography and electrochemical technique. This paper reviews all methods reported for determination of free fatty acids in palm oil.
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- C.H. Tan, H.M. Ghazali, A. Kuntom, C.P. Tan and A.A. Ariffin, J. Food Chem., 113, 645 (2009); doi:10.1016/j.foodchem.2008.07.052.
- M.K. Lam, K.T. Tan, K.T. Lee and A.R. Mohamed, Renew. Sustain. Energy Rev., 13, 1456 (2009); doi:10.1016/j.rser.2008.09.009.
- Y. Basiron and K.W. Chan, J. Oil Palm Res., 16, 1 (2004).
- Palm Oil NKEA to Benefit 160,000 Smallholders. The Star. Wednesday, Sept 22, 2010. http://biz.thestar.com.my/news/story.asp?file=/2010/9/22/business/7079289&sec=business Accessed on 11 June 2013, 9:55pm.
- Palm Oil Statistics. Economics and Industry Development Division: Malaysian Palm Oil Board; http://bepi.mpob.gov.my/ Accessed on 15 June 2013, 1:24pm.
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- S.M.A. Tagoe, M.J. Dickinson and M.M. Apetorgbor, Int. Food Res. J., 19, 271 (2012).
- A. Kuntom and A.A. Ariffin, Flavors of Palm Oil, Handbook of Fruit and Vegetable Flavors, John Wiley & Sons, Inc, p. 1051-1069 (2010).
- J.A. Cornelius, J. Sci. Food Agric., 17, 57 (1966); doi:10.1002/jsfa.2740170201.
- Y.B. Che Man, M.H. Moh and F.R. Voort, J. Am. Oil Chem. Soc., 76, 485 (1999); doi:10.1007/s11746-999-0029-z.
- D.G. Atinafu and B. Bedemo, J. Cereals Oil Seeds, 2, 71 (2011).
- C.L. Chong and R. Sambanthamurthi, J. Int. Biodeter. Biodegrad., 31, 65 (1993); doi:10.1016/0964-8305(93)90015-T.
- J.W. Purseglove, Tropical Crops-Monocotyledons, Longman, London (1985).
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- J. Henderson and K.J. Osborne, Phytochemistry, 30, 1073 (1991); doi:10.1016/S0031-9422(00)95175-6.
- C. Mohankumar, C. Arumughan and R. Kaleysaraj, J. Am. Oil Chem. Soc., 67, 665 (1990); doi:10.1007/BF02540419.
- R.K. Dart, E.B. Dede and J.O. Offem, J. Food Chem., 23, 139 (1987); doi:10.1016/0308-8146(87)90007-0.
- R.K. Dart, E.B. Dede and J.O. Offem, J. Food Chem., 18, 113 (1985); doi:10.1016/0308-8146(85)90134-7.
- V.W. Ogundero, Mycopathologica, 77, 43 (1982); doi:10.1007/BF00588656.
- J.L. Kinderlerer and B. Kellard, Phytochemistry, 23, 2847 (1984); doi:10.1016/0031-9422(84)83027-7.
- D.A. Forss, Prog. Chem. Fats Other Lipids, 13, 177 (1973); doi:10.1016/0079-6832(73)90007-4.
- F.W. Forney and A.J. Markovets, J. Lipid Res., 12, 383 (1971).
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- A.N.A. Aryee, F.R. van de Voort and B.K. Simpson, Process Biochem., 44, 401 (2009); doi:10.1016/j.procbio.2008.12.004.
- J.K. Satyarthi, D. Srinivas and V. Ratnasamy, Energy Fuels, 23, 2273 (2009); doi:10.1021/ef801011v.
- B.T.Y. Ping and M. Yusof, Oil Palm Bull., 59, 5 (2009).
- Y. Opoku-Boahen, S. Azumah, S. Apanyin, B.D. Novick and D. Wubah, Afr. J. Food Sci. Technol., 3, 142 (2012).
- N.J. Best, C.J.A. Bradshaw, M.A. Hindell and P.D. Nichols, Comp. Biochem. Physiol. B Biochem. Mol. Biol., 134, 253 (2003); doi:10.1016/S1096-4959(02)00252-X.
- C. Newland, I.C. Field, P.D. Nichols, C.J.A. Bradshaw and M.A. Hindell, Mar. Ecol. Prog. Ser., 384, 303 (2009); doi:10.3354/meps08010.
- C.P. Prados, D.R. Rezende, L.R. Batista, M.I.R. Alves and N.R.A. Filho, Fuel, 96, 476 (2012); doi:10.1016/j.fuel.2011.11.060.
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- E. Ballesteros, M. Gallego and M. Valcárcel, Anal. Chim. Acta, 282, 581 (1993); doi:10.1016/0003-2670(93)80123-3.
- K.N. Kilcawley, in eds.: In, P.F. Fox and P.L.H. McSweeney, High Performance Liquid Chromatography and Gas Chromatographic Methods for Lipid Analysis, In: Advanced Dairy Chemistry, Springer, New York, pp. 779 (2006).
- T. Cserháti and E. Forgács, Theory and Practice of Chromatography: Chromatography in Food Science and Technology, Technomic Publishing Company, Lancaster, PA, pp. 1-10 (1999).
- W.W. Christie, Lipid Technol., 9, 124 (1997).
- M. Hein and H.D. Isengard, Lebens. Unters. Forsch. A, 204, 420 (1997); doi:10.1007/s002170050105.
- M.H. Moh, T.S. Tang and G.H. Tan, J. Food Lipids, 8, 179 (2001); doi:10.1111/j.1745-4522.2001.tb00194.x.
- Y.B. Che Man and G. Setiowaty, J. Food Chem., 66, 109 (1999); doi:10.1016/S0308-8146(98)00254-4.
- Y.B.C. Man and M.H. Moh, J. Am. Oil Chem. Soc., 75, 557 (1998); doi:10.1007/s11746-998-0065-0.
- L.P. Houmøller, D. Kristensen and H. Rosager, Talanta, 71, 868 (2007); doi:10.1016/j.talanta.2006.05.066.
- A. Makahleh and B. Saad, Anal. Chim. Acta, 694, 90 (2011); doi:10.1016/j.aca.2011.03.033.
References
C.H. Tan, H.M. Ghazali, A. Kuntom, C.P. Tan and A.A. Ariffin, J. Food Chem., 113, 645 (2009); doi:10.1016/j.foodchem.2008.07.052.
M.K. Lam, K.T. Tan, K.T. Lee and A.R. Mohamed, Renew. Sustain. Energy Rev., 13, 1456 (2009); doi:10.1016/j.rser.2008.09.009.
Y. Basiron and K.W. Chan, J. Oil Palm Res., 16, 1 (2004).
Palm Oil NKEA to Benefit 160,000 Smallholders. The Star. Wednesday, Sept 22, 2010. http://biz.thestar.com.my/news/story.asp?file=/2010/9/22/business/7079289&sec=business Accessed on 11 June 2013, 9:55pm.
Palm Oil Statistics. Economics and Industry Development Division: Malaysian Palm Oil Board; http://bepi.mpob.gov.my/ Accessed on 15 June 2013, 1:24pm.
I.I. Junior, M.C. Flores, F.K. Sutili, S.G.F. Leite, L.S. de M. e Miranda, I.C.R. Leal and R.O.M.A. de Souza, J. Mol. Catal. B, 77, 53 (2012); doi:10.1016/j.molcatb.2012.01.008.
R.H.V. Corley and P.B. Tinker, The Oil Palm, Blackwell, USA, pp. 450-471 (2003).
B. Saad, C.W. Ling, M.S. Jab, B.P. Lim, A.S. Mohamad Ali, W.T. Wai and M.I. Saleh, J. Food Chem., 102, 1407 (2007); doi:10.1016/j.foodchem.2006.05.051.
S.M.A. Tagoe, M.J. Dickinson and M.M. Apetorgbor, Int. Food Res. J., 19, 271 (2012).
A. Kuntom and A.A. Ariffin, Flavors of Palm Oil, Handbook of Fruit and Vegetable Flavors, John Wiley & Sons, Inc, p. 1051-1069 (2010).
J.A. Cornelius, J. Sci. Food Agric., 17, 57 (1966); doi:10.1002/jsfa.2740170201.
Y.B. Che Man, M.H. Moh and F.R. Voort, J. Am. Oil Chem. Soc., 76, 485 (1999); doi:10.1007/s11746-999-0029-z.
D.G. Atinafu and B. Bedemo, J. Cereals Oil Seeds, 2, 71 (2011).
C.L. Chong and R. Sambanthamurthi, J. Int. Biodeter. Biodegrad., 31, 65 (1993); doi:10.1016/0964-8305(93)90015-T.
J.W. Purseglove, Tropical Crops-Monocotyledons, Longman, London (1985).
G. Arzamendi, E. Arguiñarena, I. Campo and L.M. Gandía, Chem. Eng. J., 122, 31 (2006); doi:10.1016/j.cej.2006.05.009.
M. Raita, T. Laothanachareon, V. Champreda and N. Laosiripojana, J. Mol. Catal., B Enzym., 73, 74 (2011); doi:10.1016/j.molcatb.2011.07.020.
J. Henderson and K.J. Osborne, Phytochemistry, 30, 1073 (1991); doi:10.1016/S0031-9422(00)95175-6.
C. Mohankumar, C. Arumughan and R. Kaleysaraj, J. Am. Oil Chem. Soc., 67, 665 (1990); doi:10.1007/BF02540419.
R.K. Dart, E.B. Dede and J.O. Offem, J. Food Chem., 23, 139 (1987); doi:10.1016/0308-8146(87)90007-0.
R.K. Dart, E.B. Dede and J.O. Offem, J. Food Chem., 18, 113 (1985); doi:10.1016/0308-8146(85)90134-7.
V.W. Ogundero, Mycopathologica, 77, 43 (1982); doi:10.1007/BF00588656.
J.L. Kinderlerer and B. Kellard, Phytochemistry, 23, 2847 (1984); doi:10.1016/0031-9422(84)83027-7.
D.A. Forss, Prog. Chem. Fats Other Lipids, 13, 177 (1973); doi:10.1016/0079-6832(73)90007-4.
F.W. Forney and A.J. Markovets, J. Lipid Res., 12, 383 (1971).
P.O.R.I.M. Test Methods,Palm Oil Research Institute of Malaysia (PORIM), Kuala Lumpur, Malaysia (1995).
R. Roldan-Assad and P. Gareil, J. Chromatogr. A, 708, 339 (1995); doi:10.1016/0021-9673(95)00390-9.
I.S.M. Zaidul, N.A. NikNorulaini, A.K. Mohd Omar and R.L. Smith Jr, J. Food Eng., 79, 1007 (2007); doi:10.1016/j.jfoodeng.2006.03.021.
C. Skiera, P. Steliopoulos, T. Kuballa, U. Holzgrabe and B. Diehl, J. Lipid Technol., 24, 279 (2012); doi:10.1002/lite.201200241.
E. da Silva Figueiredo, E. de Castro Vieira, E.H. de SiqueiraCavalcanti and E. D’Elia, J. Electroanal., 25, 750 (2013); doi:10.1002/elan.201200513.
D.T. Raspe and C. da Silva, J. Energy, 2013, 1 (2013); doi:10.1155/2013/301647.
A.F.C. Pereira, M.J.C. Pontes, F.F.G. Neto, S.R.B. Santos, R.K.H. Galvão and M.C.U. Araújo, Food Res. Int., 41, 341 (2008); doi:10.1016/j.foodres.2007.12.013.
A.N.A. Aryee, F.R. van de Voort and B.K. Simpson, Process Biochem., 44, 401 (2009); doi:10.1016/j.procbio.2008.12.004.
J.K. Satyarthi, D. Srinivas and V. Ratnasamy, Energy Fuels, 23, 2273 (2009); doi:10.1021/ef801011v.
B.T.Y. Ping and M. Yusof, Oil Palm Bull., 59, 5 (2009).
Y. Opoku-Boahen, S. Azumah, S. Apanyin, B.D. Novick and D. Wubah, Afr. J. Food Sci. Technol., 3, 142 (2012).
N.J. Best, C.J.A. Bradshaw, M.A. Hindell and P.D. Nichols, Comp. Biochem. Physiol. B Biochem. Mol. Biol., 134, 253 (2003); doi:10.1016/S1096-4959(02)00252-X.
C. Newland, I.C. Field, P.D. Nichols, C.J.A. Bradshaw and M.A. Hindell, Mar. Ecol. Prog. Ser., 384, 303 (2009); doi:10.3354/meps08010.
C.P. Prados, D.R. Rezende, L.R. Batista, M.I.R. Alves and N.R.A. Filho, Fuel, 96, 476 (2012); doi:10.1016/j.fuel.2011.11.060.
J. Eras, F. Montañes, J. Ferran and R. Canela, J. Chromatogr. A, 918, 227 (2001); doi:10.1016/S0021-9673(01)00754-3.
E. Ballesteros, M. Gallego and M. Valcárcel, Anal. Chim. Acta, 282, 581 (1993); doi:10.1016/0003-2670(93)80123-3.
K.N. Kilcawley, in eds.: In, P.F. Fox and P.L.H. McSweeney, High Performance Liquid Chromatography and Gas Chromatographic Methods for Lipid Analysis, In: Advanced Dairy Chemistry, Springer, New York, pp. 779 (2006).
T. Cserháti and E. Forgács, Theory and Practice of Chromatography: Chromatography in Food Science and Technology, Technomic Publishing Company, Lancaster, PA, pp. 1-10 (1999).
W.W. Christie, Lipid Technol., 9, 124 (1997).
M. Hein and H.D. Isengard, Lebens. Unters. Forsch. A, 204, 420 (1997); doi:10.1007/s002170050105.
M.H. Moh, T.S. Tang and G.H. Tan, J. Food Lipids, 8, 179 (2001); doi:10.1111/j.1745-4522.2001.tb00194.x.
Y.B. Che Man and G. Setiowaty, J. Food Chem., 66, 109 (1999); doi:10.1016/S0308-8146(98)00254-4.
Y.B.C. Man and M.H. Moh, J. Am. Oil Chem. Soc., 75, 557 (1998); doi:10.1007/s11746-998-0065-0.
L.P. Houmøller, D. Kristensen and H. Rosager, Talanta, 71, 868 (2007); doi:10.1016/j.talanta.2006.05.066.
A. Makahleh and B. Saad, Anal. Chim. Acta, 694, 90 (2011); doi:10.1016/j.aca.2011.03.033.